Greenly, Edward. 1919. The geology of Anglesey. London HMSO [For Geological Survey] Two volumes
Chapter 4 The petrology of the Mona Complex
Introductory
The petrological descriptions of the rocks will be arranged in the groups mentioned on p. 38, the contents of each group, sedimentary, volcanic, and the like, being described under the group-heading. But the descriptions of metamorphic state cannot often be divorced from those of original material, as in many cases the rocks are only known in that state, which is therefore diagnostic. The rocks known are: Quartzites, black quartzites, grits of several types, and conglomerates, with slates and phyllites. These give rise to quartzite-schist, grit-schists of several kinds, and a variety of mica-schists, ranging from slightly altered chlorite-sericite-schist to highly crystalline muscovite-schist, and a muscovite-schist with green biotite. With these are limestones, dolomites, and manganous-dolomites, some of which pass into highly crystalline mica-cipolini, and associated with them are graphitic phyllite and graphite-schist. There are spilitic lavas, albite-diabases, keratophyres, and felsites; with spilitic tuffs, rhyolitic tuffs, and mixed tuffs; and important ashy grits. The basic rocks give rise to a suite of chlorite-epidote and chlorite-actinolite-schists. Jaspers and jaspery phyllites occur with the spilites, and pass into hsematitic schists in places. Green hornblende-schist and glaucophane-schist are developed on a large scale. There are serpentines, gabbros, and pyroxenites, with which occur talc-schist, tremolite-schist, tremolite-marble, ophicalcite, and epidositic hornfels. There are granites of several types, with four or five types of hornfels. Finally, there are hornblende gneisses, biotite gneisses, sillimanite gneisses, forsterite limestones, and granitoid gneisses.
The Holyhead Quartzite
This rock is perhaps the most conspicuous in Anglesey, for the summit of Holyhead Mountain is composed of it. The characters that strike the eye at once are its whiteness, its uniformity, and the extraordinary massiveness of its bedding. It hardly ever shows a blue core, and even appears, indeed, to become whiter the more deeply it is quarried. Over most of the hill no bedding can be made out at all, but it is occasionally visible on the great sea-cliffs of Gigorth and Rhoscolyn, and at one or two places there are thin beds of mica-schist. The whole mass (except along the foot of the southern escarpment) is traversed by a nearly vertical foliation
The clastic character of the rock can be seen by the naked eye on any hand specimen, and it is, for a quartzite, rather coarse, grains one-sixteenth of an inch in diameter being quite plentiful, though the great majority are smaller. The large ones are well rounded, the small ones usually sub-angular. Felspar is rare. The schistosity is determined by well-defined, though impersistent, films of white mica, along which the rock splits readily, though a cross fracture is also easy to obtain. These films are about a quarter of an inch apart, and between them the grains of quartz are often quite undeformed. The rock is, however, typically blastopsammitic, the matrix having been completely reconstructed as a granoblastic schist, with whose elements the clastic grains interlock, their original smooth outline being visible in ordinary light. Internally, their integrity is not much disturbed, and yet the edges of the foliation-micas often penetrate the quartz of a grain that is still a unit optically. Anhedral iron-ores, tourmaline, and zircon are not uncommon. Quartz-veining is abundant. Along the foot of the southern escarpment foliation disappears, and the quartzite is quite massive. This massive rock, especially the finer parts of it, is the only portion that resembles the Gwna quartzites. It is, however, blastopsammitic like the foliated variety, but the clastic grains are closely packed, and there is very little matrix. _Hence the massive structure, for in the ordinary quartzite it is the matrix alone that is really foliated. In the massive zone, south-west of Twr, the Quartzite is for a short distance pebbly, with fragments a third of an inch in length. Most of these are venous quartz, but there are some of scarlet Gwna jasper, and some from old granoblastic rocks and mica-schists.
The following analyses, by T. Blair, of Sheffield, were kindly furnished by the manager of the Holyhead Silica Works.
I. | II. | III. | |
SiO2 | 96.00 | 94.25 | Less than 87.00 |
Al2O3 | 1.98 | 2.24 | — |
Fe2O3 | .42 | .56 | — |
CaO | .38 | .67 | — |
MgO | .30 | .97 | — |
K2O+Na2O | .42 | (not stated) | — |
Loss on ignition | .50 | .65 | — |
100.00 | 99.34 | — | |
Spec. Grav | 2.656 | — | 2.653 |
All are from the Breakwater quarries. No. I is the most siliceous variety found there, but the massive rock of the southern escarpment (E10127)
The South Stack Series
The South Stack Series proper
This great series of rocks, which, from its wonderful folding and metamorphism, laid bare in the lofty sea-cliffs, presents some of the most striking geological sections in Great Britain, consists essentially of grits with partings of mica-schist.
These partings were once evidently felspathic shales, so that this group and the Holyhead Quartzite are the only major subdivisions of the Mona Complex that are composed entirely of mechanical sediment. It falls into two main subdivisions, a Llwyn (pronounced 'Hloo-yn') Group (named from the Llwyn-y-berth promontory), that has lithological affinities to the New Harbour Beds, and a South Stack Moor (or briefly 'Stack Moor', from the moor that extends from the South Stack sea-cliffs eastward for a mile) Group with affinities to the Quartzite. The difference is chiefly in the grits. Throughout both divisions these weather white, but in the Stack Moor part they are very massive, usually 10, and sometimes 30 feet in thickness, so that in shallow inland sections they may easily be mistaken for the Quartzite, while in the Llwyn part they are much thinner, usually about a foot, so that the general aspect here is banded or flaggy, not unlike that of the English Lias. In spite of the affinities just remarked; there is no difficulty in separating the series from the New Harbour Beds on the one hand and the Quartzite on the other. In the adjacent part of the New Harbour Beds the gritty matter is disseminated, and the whole rock is 'thin-seamed' or even laminated; but the moment we pass into the South Stack Series the grits become sharply individualised, weathering white, a foot or so in thickness, and the alternating type is quite pronounced. The massive Stack Moor. Beds, on the other hand, however white and quartzite-like they may be externally, are much more felspathic, and (unlike the Quartzite) pale blue internally, while they never fail to show bedding as soon as a deeper section is obtained. The thinner grits of the Llwyn portion, though often weathering as white as a quartzite, are also always green or blue in a fresh fracture. For so thick a succession of grits they are on the whole rather fine. The massive Stack Moor Beds have about the same texture as the Quartzite, but the Llwyn Grits are really very fine, even their larger grains, which have survived the metamorphism, being quite small. In both divisions, however, there are a few coarse beds, in which grains of as much as three-sixteenths of an inch may be found.
Throughout the deposition of the series a gradual change in the conditions of deposit was going on, from the hypopelitic New Harbour Beds, to the purely psammitic conditions of the Quartzite.
Besides quartz, felspars and white micas are frequent as original constituents, but only the massive upper beds could be called felspathic. The felspar is albite, with a good deal of albite-oligoclase, and a little microperthite. Zircon, tourmaline, rutile, and iron-ores are generally present as accessories. The coarse beds contain a good many composite fragments, most of which are fine grits, often schistose, with a foliation independent, in some cases, of that of the enclosing grit. One or two granitoid rocks have been seen. Some scarlet fragments can be identified with confidence as from the Gwna jaspers. Snell clastic grains as retain their original outlines are, in many cases, not very well rounded, but these are usually the larger ones. Blue opalescent quartz is abundant in one of the coarser grits on the South Stack. One fragment of mica-schist (E10131)
Metamorphism
In spite of the beautiful preservation of their bedding, all these rocks are in reality holocrystalline schists.
The coarser grits are now blastopsammitic, but the finer grits, as well as the matrix of the coarser ones, have been completely re-constructed and are purely granoblastic. A foliation is imparted by thin straight flakes of muscovite and of a green mineral (p. 47), which, except in the more massive beds, are to be found, sparingly, all through the rock, becoming the dominant minerals along the films of parting. Their ends often penetrate the clear quartz of the clastic grains, which nevertheless retains its optical integrity. The green mineral is a biotite, the same as that of the New Harbour Schists. Its optical characters are given on p. 47. Thin plates of muscovite are intergrown with it.
The same two minerals, however, occur also in crystalline lenticular growths, elongated parallel to the general foliation, but in which the basal cleavages and planes of intergrowth are almost -at right angles to that. A name for growths of this kind in crystalline schists will be found convenient. Following the lines of Grubenmann's terminology (see footnote to p. 143), they may be called Encarsioblastic, from έγκάρσιος = transverse (πλάγιος having, in mineralogy, been used in contradistinction to όρθός, is unsuitable, as these growths may be at an angle of 90° to the foliation).
Another interesting feature is that some of the larger blastopsammitic felspars with turbid cores have peripheries of clear albite, the whole grain, twinning-planes and all, being optically undisturbed. Weathered felspar has therefore been rejuvenated, so that permeation by sodium solutions must have accompanied the dynamic metamorphism.
The fine partings, which may be as much as three or four inches thick, often show the colour-banding of the original shale, and sometimes also contain thin seams of fine white quartz-schist. The pelitic matter itself has been completely reconstructed, and is now a perfect lustrous lepidoblastic mica-schist with a pale sea-green tinge, which consists almost entirely of white mica, with a varying proportion of green biotite, and with many minute granules of epidote, zoisite, haematite, and other iron-ores. The micas may be half a millimetre in length. Encarsioblasts are an even more striking feature of these beds than of the grits, and in some case development has been carried so far that the dominant foliation has become reduced to a series of mere films between them, so as to resemble a strain-slip foliation. Specimens of such rocks (E10158)
Lenticular seams of coarse venous quartz, which may be several inches thick, occur throughout the series; and usually contain chlorite, in irregular aggregates that may be an inch thick, and several inches long, composed of little well-formed plates that sparkle under the lens. In a few cases it is foliated, but. the quartz is not. These seams are much more frequently found in the pelitic schists than in the grits, conforming in a general way to the bedding, but transgressing it at a low angle. Thin ones may fold sharply with the beds, and may then cut the foliation at right angles, causing slight deflections of it. They are evidently the last product of the metamorphism, introduced, apparently, when the shearing stresses had nearly but not wholly spent themselves.
Chemical composition
The following analysis of a 'schist from the South Stack, near the Lighthouse', is given by Messrs. Mellard Reade and Holland in Proc. Lpl. Geol. Soc., 1900, p. 472 and table. It is described as a foliated rock, with a silky texture, and folded laminations, but with no trace of slaty cleavage, composed of minute quartz, with mica in subordinate quantity and some chlorite. Evidently it is neither one of the massive grits nor one of the micaceous partings.
The description corresponds to a fine grit such as (E10599)
SiO2 | 76.77 |
TiO2 | 0.74 |
Al2O3 | 11.15 |
Fe2O3 | 1.71 |
FeO | 2.32 |
MnO | 0.12 |
CaO | 0.09 |
BaO | 0.03 |
MgO | 1.06 |
K2O | 2.85 |
Na2O | 1.05 |
P2O5 | 0.11 |
C | traces |
Combined Water | 2.41 |
100.41 |
As the felspar is albite, it is evident from the percentage of potassium that the white mica must be a muscovite.
The Coeden Beds
These are regarded as a slightly differing facies of the Liwyn part of the South Stack Series. They are finely developed in the rugged tract known as The Mynydd Mechell, after which they have been called by several authors, but the word Coeden 'may be found to run more trippingly on the tongue'. Like that with which it is correlated [such as (E9313)
But they are now blastopsammitic schists, the matrix being a granoblastic but fine mosaic. Foliation is imparted to it by white mica and chlorite, but the flakes are neither as long, as broad, or as well-formed as in Holy Isle, and encarsioblasts are rare. Iron-ores are usually present. Epidote is an important constituent, its granules often being rounded porphyroblasts. Seams of pistacio-green epidosite are a conspicuous feature of the group. They may be half an inch or more in thickness, but never extend for many feet. The clastic texture still survives in them, but the matrix is crowded with granular epidote. Some are slightly transgressive, showing their secondary date. Zoisite is also present.
The fissile partings are composed almost wholly of white mica, in very thin flakes, closely felted, and with some chlorite intergrown, and granules of iron-ore. Thin seams of quartz-schist are interbanded with it. It is often full of venous quartz in sills', containing reddened felspar, some of which is albite, some apparently decomposing orthoclase.
The group has undergone more crystalline reconstruction than has the country to its north, as has been pointed out by Dr. Callaway. But less than that of the rocks of Holy Isle. Yet the survival power of the clastic grains, and the texture of the mosaic of the matrix are much the same in the two areas. Here, it is true, undulose extinction is much more often seen, which, were it a feature of the metamorphism, would indicate a lower grade. But the Coeden beds are riding upon the Carmel Head thrust-plane, which, being here at a very low angle, cannot be far beneath them anywhere; and some of the dykes by which they are traversed are deformed. Their undulose extinction may, therefore, be referred to movements of a later date.
The New Harbour Group
This is named from its fine development about the New Harbour at Holyhead. The term 'New Harbour Beds' will be used in an inclusive sense for the formation as it is found in Holy Isle, in the Western Region, and in the Northern Inters; the term Amlwch Series in a similar sense for the facies found in the Northern Region; the terms 'Green-mica-schist' and 'Amlwch Beds' for the dominant sedimentary member in each case. The group thus includes the following members:
Green-mica-schist
Amlwch Beds
Jaspery Phyllites
Bedded Jaspers
Spilitic Lavas and Basic Schists
The jaspery phyllites, jaspers, and spilites present the same characters in the Amlwch Series as in the New Harbour Beds.
The Green-mica-schists
These are flaggy or laminated schists of medium grain, with a persistent green colour, and sparkling with little flakes of mica. They are cleanly crystallised, and their green hue is clear, different in quality from the dull muddy green so characteristic of the Gwna Beds. Two elements are present. The greater part of the rock is hard and slabby, saccharoid on cross-fracture, and rather like the Moine Schists of the Scottish Highlands. The other element is a fissile schist with gleaming foliation planes, which occurs as thin partings. The hard bands, however, are seldom as much as a foot, are usually only an inch or so, in thickness, often indeed mere seams, of which eight or more may be counted in an inch. Not only so, but they are thoroughly foliated throughout their whole body. Even the most massive beds that have been seen, a yard or more in thickness, are foliated through and through. So that the granular and the fissile elements are closely bound together in this formation. The fissile beds may reach three or four inches in rare cases, but are generally not much more than a small fraction of an inch, or even mere films.
The rocks are without doubt sedimentary in origin, and their flaggy bands were grits. Where these are tolerably massive, some clastic grains are usually to be seen under the hand-lens, but they are not conspicuous. Most of them are quartz; but there is a good deal of felspar, nearly all of which is albite, with a few grains like microcline. The albite is often untwinned, and full of minute inclusions, most of which are micas. The only surviving original accessory is tourmaline, some of which has a beautiful dichroism from lark blue to rose-pink, and is sub-hedral. In a few places there are coarser grits, one of which, on the shore below the Coastguard Station at Holyhead, contains fragments a seventh of an inch in diameter, of fine white quartzite of Gwna type. One fragment of a granitoid rock was found in the massive beds at Porth-y-felin.
The rocks are typically blastopsammitic, and have undergone a high degree of alteration
The grass-green mineral which imparts the colour to the rock has been investigated by Dr. H. H. Thomas and the writer, from the specimen (E10151)
Epidote is everywhere abundant, some seams being crowded with its granules, which attain to a diameter of .5 mm., and are porphyroblastic. Most of it is yellow and pleochroic, with high bi-refringence, but there are pale varieties with low bi-refringence, which give sometimes the characteristic polarization-blues of zoisite.
A large proportion, however, of the granules conspicuous by strong relief, are sphene. There is a good scattering of iron-ores, most of which are ilmenite, often elongated along the foliation; and occasionally apatite in some abundance. In the slide (E10151)
Quartz-sheets. Venous quartz in sheets or sills, always with nests of chlorite, of precisely the same kind as those in the South Stack Series, are developed on a great scale in this group. A felspar is often intercrystallised with the quartz, so that these segregations are not mere quartz-veins, but approach in character to pegmatites. The felspar is albite, much of it untwinned. In rare cases the quartz has a rude, and the chlorite a strong foliation, so that though the latest products of the metamorphism, movement had not ceased when some at any rate of them had separated. They are present everywhere, often in such abundance as to be a conspicuous feature on the rugged bosses. There are also seams that are foliated and finely granoblastic; some parallel to the general foliation and graduating laterally into the green schist, others truncating it at a low angle. Separation of quartz must therefore have taken place during three intervals at least of the metamorphism, and it was progressively incorporated. For the granoblastic is a modification of the venous quartz, cores of which survive in it. Quartz being always in excess over chlorite, it is evident that the beds in their original condition must have been more siliceous, considered as a whole, than they are to-day.
These rocks also, therefore, are holocrystalline schists, even more thoroughly foliated than the South Stack Series. Next to the Gneisses and the Penmynydd Schists, they are the most reconstructed rocks in the Island. This character is maintained throughout Holy Isle, but a crystalline degeneration seems to set in upon the main Island, increasing eastwards. To some extent this is really the case. But the appearance is chiefly due to a platy foliation that is there developed, which is later (pp. 196–8) than the foliation-planes of Holy Isle, and on which there is a feebler development of mica, so that the planes of easy splitting are less lustrous.
Subdivisions. Two subdivisions can be recognised. In the first of these the flaggy, alternating, type is pronounced; psammitic matter is dominant; clastic grains are often visible; and the coarser grits are not uncommon. The group may be called the Soldier's Point Beds.
The other is much more pelitic, and clastic grains are rarely seen, while the lepidoblistic seams are far more intimately interfelted with the granoblastic, so that the alternation of the two is far less conspicuous. Here, also, the sheets of venous quartz with albite are most abundant. This group may be called the Mynydd-celyn (or briefly, the Celyn-pronounced 'Kelyn') Beds. The Celyn beds lie next to the South Stack Series, the Soldier's Point beds adjoin the Skerries Group.
Chemical composition.
The following analyses have been made, some others being annexed for comparison.
I. | II. | III | IV | V. | VI | VII | VIII | |
SiO2 | 72.32 | 48.52 | 53.67 | 78.66 | 84.86 | 55.43 | 60.15 | 58.38 |
TiO2 | 2.53 | 2.73 | — | 0.25 | 0.41 | 0.46 | 0.76 | 0.65 |
Al2O3 | 10.23 | 23.25 | — | 4.78 | 5.96 | 13.84 | 16.45 | 15.47 |
Fe2O3 | 2.31 | 4.17 | — | 1.08 | 1.39 | 4.00 | 4.04 | 4.03 |
FeO | 2.62 | 5.67 | — | 0.30 | 0.84 | 114 | 2.90 | 2.46 |
MnO | 0.21 | 0.15 | — | trace | trace | trace | trace | trace |
CaO | 2.67 | 1.48 | — | 5.57 | 1.06 | 6.02 | 1.45 | 31.7 |
MgO | 1.30 | 3.29 | — | 1.17 | 0.52 | 2.67 | 2.32 | 2.45 |
K2O | 0.80 | 5:94 | 4.41 | 1.32 | 1.16 | 2.67 | 3.60 | 3.25 |
Na2O | 3.08 | 0.95 | 2.57 | 0.45 | 016 | 1.80 | 1.01 | 1.31 |
H2O (at 110°) | 0.09 | 0.12 | — | 0.31 | 0.27 | 2.11 | 0.89 | 1.34 |
H2O (above 110°) | 1.67 | 3.81 | — | 1.33 | 1.47 | 3.45 | 3.82 | 3.68 |
CO2, &c | — | — | — | 5.19 | 1.16 | 6.29 | 3.07 | 4.27 |
99.83 | 100.08 | — | 100.4 | 99.86 | 100.48 | 100.46 | 100.46 | |
Spec. Grav. | 2.763 | 2.746 |
The specific gravities are given by Mallet, and are not from the same specimens.
I. Typical hard, gritty schist from just north-west of Bryntirion (six-inch map), Holyhead, i.e., 300 yards north-west by west from the new church ('ch'. of one-inch map). No slice, but same type as (E10282)
II. Fissile band from same locality (E10151)
III. Mica-schist of intermediate character, Cromlech Farm, Rhoscolyn (E10162)
IV. A composite analysis of 253 sandstones; and
V. of 371 building-sandstones, from different parts of the United States.
VI. A composite analysis of 27 Mesozoic and Cainozoic Shales; and 7, of 51 Palaeozoic Shales.
VIII. The average of VI and VII 'weighted' as three to five.
These composite analyses are from Bull. U.S.G.S., quoted in Sir A. Geikie's 'Text-book of Geology', Ed. 4 (1903), pp. 165. 'CaO', here, includes BaO, and 'CO2, &c'. includes P2O5, SO3, and organic C.
The proportion of titanium in both the Holyhead rocks is remarkable, and shows what a large proportion of the minute granules of high refractive index must be sphene. But, considering the ab'undance of that mineral, and of epidote, the percentage of lime is small, and more magnesia might have been expected from the chlorite. The alkalies are high, and the reversal of proportions between them in the granular and fissile types indicates that the alkali-mineral of the one is albite, of the other, muscovite. Comparing them with the composite analyses, however, it is evident that the granular component of the group is not a normal grit, nor their fissile component a normal shale. In both types the silica (though allowance must be made for the siliceous segregations) is relatively low, the alkalies and the magnesium high, the iron (especially the ferrous iron) very high, and the titanium quite exceptional. The granular component is far more aluminous than a normal grit, and is rich in sodium, evidently contained in its albite.
Now, in the field, the persistent green tinge of these rocks undoubtedly suggests to the mind that volcanic matter must enter into their composition. Previous observers (p. 11) have noted this, and Dr. Teall, who walked over them with me near Holyhead, received the same impression. Their mineral and chemical composition leaves no doubt that such must be the case. Yet no bands that could be regarded as tuffs have been found except at the top and bottom of the group. If, however, we suppose that the basin of deposit was, throughout the whole time of their formation, within reach of showers of fine volcanic dust produced by the explosion of a basic magma, these characters receive an explanation. Can that magma be identified? We have seen that a singular character of both the psammitic and the pelitic elements is their high percentage of titanium, which is nearly the same in both in spite of all their other differences. Now there are some lavas in the group, and they are spilitic. Such lavas are apt to contain a high percentage of titania, rising to a maximum of 2.95.<ref>Dewey and Flett, Geol. Mag., 1911, p. 207, and Geol. Surv. Mem, Lizard and Meneage, p. 185.</ref> And the spilite of the New Harbour Beds themselves (p. 55) contains 2.21 per cent. of titania, the average of that of the two components of the Green-mica-schists being 2.63. Why titaniferous particles were disseminated so much more widely than other ones may perhaps be explained in more than one way. However that may be, little doubt can remain that the volcanic element of these beds is the dust of a spilitic lava.
The Amlwch Beds
The Alternating Beds are thin-bedded schistose grits with partings of fine phyllitic mica-schist, the grits not often exceeding three or four inches in thickness. One or two inches is a common thickness, and towards Llaneilian they have become so thin that it is easy to obtain hand-specimens containing five or six grits that are from a quarter to even an eighth of an inch in thickness. All the beds are green, the phyllites pale grey-green, the grits rather darker green internally. There are two distinct types of grit, one which is rather fissile and relatively soft, the other very hard and jointed, weathering out in rectangularly-edged ribs that are sharply marked out from the phyllitic partings. These are the beds that impart such a conspicuously alternating' aspect to the series, for they weather to a light cream colour. In the fissile grits there is much more matrix. The fragments are chiefly quartz, but there is much felspar in fair condition. It is albite, sometimes untwinned, often with beautiful polysynthetic twinning. The grains tend to be sub-angular. For the most part these grits are rather fine, and usually there is a good deal of matrix. It has been completely reconstructed, and is now a fine granoblastic schist with chlorite and white mica. Epidote is usually present, and in some slides is abundant. The matrix of the fissile green grits is more full of chlorite than that of the hard bands. In these rocks also the amount of green material points to the presence of basic volcanic dust, probably derived from the spilitic lavas, as in the case of the New Harbour Beds of Holy Isle.
In a few places there are coarser grits, and at Amlwch is a true conglomerate with well-rolled pebbles up to two inches in length. Some of these are derived from Gwna quartzite, some from grits, others from granitoid rocks arid albite-quartz-felsites of the same types as those of the Skerries Conglomerates (p. 60), a few are old mica-schists. Boulders, also, as much as four inches or more in diameter (pp. 303–4), are occasionally to be seen in quite fine flaggy beds. They have probably been brought by floating vegetation, as has been suggested in somewhat similar cases that are known in coal seams and in chalk.
These pebbles are in some cases much deformed, especially the igneous, ones. Many of the clastic grains in the grits have suffered like manner, and have begun to enter into sutural relations with the matrix. The fine partings are often a little gritty, but all, except these few grains, have been completely reconstructed; and they are now fine chloritic mica-schists or phyllites. Some of the quartz veins that cut the foliation are traversed by a rude schistosity parallel to that foliation. Bands of epidosite like those in the Coeden beds are rare in this group.
Subdivisions — Here also there are two divisions. The alternating, psammitic division may be called the Lynas beds; from which can be distinguished a pelitic division that may be called the Bodelwyn Beds. Metamorphism increases in them southwards, but they never reach the crystalline condition of the Celyn beds of Holy Isle: their micas being a fine felt in which the individual flakes are small.
The following are analyses of the, grey-green phyllites.
I. | II. | III. | IV. | V. | |
SiO2 | 57.23 | 70.58 | 70.74 | — | 80.59 |
TiO2 | 0.89 | 0.62 | 0.41 | — | 0.34 |
Al2O3 | 20.43 | 13.23 | 12.79 | — | 6.45 |
Fe2O3 | 1.33 | 4.23 | 4.76 | — | 4.77 |
FeO | 5.64 | 1.24 | 1.26 | — | 0.73 |
MnO | 0.05 | 0.35 | 0.38 | — | 0.81 |
CaO | 1.54 | — | trace | — | 3.64 |
BaO | 0.02 | — | — | — | — |
MgO | 2.09 | 1.83 | 2.97 | — | 0.82 |
K2O | 2.39 | 1.92 | 1.90 | 3.61 | 0.24 |
Na2O | 3.97 | 3.52 | 2.35 | 2.92 | 0.73 |
H2O (combined) | 3.94 | 2.18 | 2.61 | — | 1.06 |
SO3 | 0.03 | — | — | — | — |
P2O5 | 0.54 | trace | — | — | — |
100.09 | 99.70 | 100.17 | — | 100.18 | |
Spec. Grav. | 2.72 | 2.65 |
I. 'Green slate from quarry between Cemlyn and Cemmaes, a finely cleaved glossy green slate'. Anal. Mellard Reade and Holland. Proc. Lpl. Geol. Soc., 1900, p. 466 and table.
II. 'Slate', 'Borth Bay', evidently Hen-borth, Mynachdy. Anal. E. Dickson. Proc. Lpl. Geol. Soc., 1890.
III. 'Unaltered Slate', Porth y Gwartheg, Cemlyn. Anal. E. Dickson, loc. cit.
IV. Fine parting. Amlwch, the bathing creek, just where the footpath that runs north-westward from the Coastguard Station reaches the sea (E10558)
V. 'Greenish-grey infiltrated rock penetrating slate as a sheet, Yr-hen-borth'. The description and locality correspond with those of the bands of epidosite a little to the west of Hen-borth, Mynachdy (E10385)
The Jaspery Phyllites
These are fine, fissile rocks, of a rather uniform purplish red colour, usually not very lustrous on the foliation planes. Transitional types connect them with the green ordinary phyllites, a few of which have a faint purplish tinge indicating the first approach to the purple beds. But the true jaspery phyllites are marked off quite sharply enough to be easily separable on the maps. They are composed chiefly of white mica hematite, fine quartz, and a little chlorite. The hematite is most of it thin scaly eisenglimmer. Some of the quartz and mica seem to be clastic, but the grains are very small. Rocks with the full red colour are known in Holy Isle only at one place, but in many places the Green-mica-schists contain thin beds that have a tinge of purple, and can be separated roughly on the maps. They are as lustrous as the fissile portions of the mica-schist, and differ only in the presence of abundant scales of eisenglimmer, which are interfelted with the mica, larger and better formed than in the north, but in less quantity, It is not unlikely that, in these highly crystalline schists, the red colour has been partly discharged by reduction of the ferric oxide (cf p. 88).
The Bedded Jaspers
Intimately related to the jaspery phyllites, these rocks cannot be separated from them on the maps; usually occurring as bands in them that are less than an inch in thickness, the bedding being well preserved, and the jaspers finely banded. They are not fissile, but are hard, compact, and brittle, with a cross-jointing like that often seen in bedded cherts. Their colour differs from that of the phyllites in being brick-red rather than purple; but they never show the bright scarlet of the nodular jaspers of the Gwna Beds. They are composed
In No. III. of the following analyses it was found impossible to exclude a proportion of the jaspery phyllite, owing to the rapidity of alternation. If it be compared with that of a pure jaspery phyllite (p. 89), no doubt will remain that the silica percentage of the pure jasper must be very high.
I. | II. | III. | |
SiO2 | 55.34 | 61.65 | 67.07 |
TiO2 | 1.94 | 0.70 | 0.69 |
Al2O3 | 20.87 | 16.82 | 14.79 |
Fe2O3 | 7.07 | 6.61 | 6.33 |
FeO | 1.19 | 1.39 | 0.81 |
MnO | 0.36 | 1.07 | 0.26 |
CaO | 0.78 | 0.15 | 1.14 |
BaO | 0.07 | 0.03 | not det. |
MgO | 1.58 | 2.02 | 2.23 |
K2O | 4.76 | 2.90 | 1.85 |
Na2O | 2.80 | 3.36 | 3.51 |
H2O | — | — | 0.07 |
H2O (combined) | 3.39 | 3.15 | 1.78 |
P2O5 | 0.13 | 0.08 | not det. |
SO3 | trace | not fd. | not det. |
CO2 | — | — | none |
100.28 | 99.93 | 100.53 |
I. Purple-grey 'slate'. Hen-borth, Mynachdy. Anal. Mellard Reade and Holland. Proc. Lpl. Geol. Soc. 1900, p. 469 and table.
II. Purple-grey 'slate' ('crinkled'). Llanrhwydrys. Anal. Mellard Reade and Holland, loc. cit., p. 467 and table.
III. Jasper. Amlwch. South side of creek, 80 yards north of where the path, running north-westward from the Coastguard Station, reaches the cliff (E10535)
The Spilitic Lavas
are massive, heavy rocks, normally of a pale sea-green colour, but mottled and shot throughout with the pistacio-green of epidote, some parts being thoroughly epidotised. They have not the dull fracture of the Gwna spilites<ref>The description of the unaltered Gwna spilites (pp. 71–74) should be read first.</ref>, but look saccharoid under the lens. In many parts they are full of sometimes white but usually yellow spots which range from an eighth to half an inch in diameter. The pillowy structure is well developed, for they are built up of ellipsoidal masses that range from six inches to two feet in length, and that push into each other
The rocks have been composed of felspar and ferro-magnesian minerals, iron-ores being usually present in but small quantity. Some porphyritic pseudomorphs have the form of olivine. The pyroxene has been completely converted into fine pale actinolitic hornblende, with a varying amount of chlorite. In some there is a little quartz, but epidote is generally present, often in great abundance, and beautifully crystallised in large grains with strong pleochroism. The spots are now entirely composed of it: they are often hollow spheres enclosing cores of the general body of the rock. This body consists of lath-felspars, with which are intergrown the needles of actinolite. Some of the felspars are of fair size (these are usually sericitised), but the great majority, which give nearly straight extinctions, are slender and delicate almost to fibrosity. In the best-preserved specimens they are arranged, throughout, in brushes and subradiate groups, so that the structure is thoroughly variolitic. The needles of actinolite share the same arrangement, so that it is to be supposed that the original pyroxene shared the variolitic disposition which is, as it were, first indicated in the Gwna spilites. Some fine varieties appear to have been glassy, the glass being now chloritised. The rocks are true variolitic spilites like those of the Gwna Beds.
Nor need any doubt be entertained of their having been true lavas. Their associates are too much reconstructed for pyroclastic structure to be recognised: but close to the epidotic variolite of the Cliperau shore some green chlorite-epidote schists, which nevertheless contain much quartz, are interbanded with the green-mica-schists, and can hardly represent anything but fine tuffs. A thin chlorite-epidote-albite schist that occurs just at the junction. of the New Harbour Beds and the South Stack Series in Holv Isle is almost certainly a tuff, for it graduates into the sediments above and below. Its chlorite seems to be after hornblende. And we have already seen that the peculiar composition of the New Harbour and the Amlwch Beds indicates that explosions of spilitic dust were taking place from time to time. These variolitic spilites must therefore be regarded as contemporaneous outflows.
The following analysis shows that, while the rock has in a general way the composition of a spilite, it has been modified by epidotisation,-as well as having been probably more basic originally.
I. | II. | |
SiO2 | 39.20 | 42.26 |
TiO2 | 2.21 | — |
Al2O3 | 18.80 | — |
Fe2O3 | 8.61 | — |
FeO | 4.99 | — |
MnO | none | — |
CaO | 9.69 | — |
MgO | 10.03 | — |
K2O | 016 | — |
Na2O | 1.88 | — |
H2O | 0.10 | — |
H2O (combined) | 4.52 | — |
CO2 | none | — |
100.19 | — |
I. Variolitic spilite, Amlwch, 100 yards north of the path's end on the cliff, north-west of the Coastguard Station (E10529)
II. Chlorite-epidote schist, probably a variolitic tuff, 100 yards north of the cottage on the east side of Borth-wen, Rhoscolyn, Holy Isle (E10165)
Metamorphism — Under the influence of the great shearing stresses of the Complex the tough ellipsoids of the lavas lend themselves readily to the production of large lenticular augen, about which winds the less obdurate material of the skins', now converted into a chloritic and actinolitic schist; and by further deformation the lenticular cores themselves become attenuated, and finally foliated. But even in the most advanced stages reached some trace of the pillowy structure can generally be detected.
If we now compare the lavas of this horizon with those of the Gwna Beds it would seem that they differed but little in their original condition. Both are spilites with a marked tendency to variolitic structure. The differences are in their dynamic metamorphism. No hornblende has been found in any undeformed Gwna spilite. It does not appear at all, nor does epidote in quantity, until foliation has developed. But in these rocks not merely epidote but actinolite appears in abundance without any breaking down of the delicate variolitic disposition of the felspars. And where foliation is developed there is no concurrent advance in the development of hornblende; the rock does not become a hornblende-schist. If we consider the state of the associated sediments we find that those of the Gwna Beds have suffered severe cataclastic deformation, while those of the New Harbour Beds have been rapidly folded and have acquired a much more crystalline foliation. There can be little doubt that the different condition of the two groups of spilite is in some way connected, first with their positions on the maximum primary folds, and next with the types of stress that were set up in the major secondary folds of the Mona Complex.
The Skerries Group
The formation included in this group are the Skerries Grits, the Church Bay Tuffs, and the Tyfry Beds.
The Church Bay Tuffs
Its generally unstratified character is the salient feature of this formation, and one that is unusual in deposits that are so fine of grain. At Clegyr-mawr alone can bedding be seen through a thickness of 180 feet, and even this disappears rapidly along the strike. Elsewhere, a thin bed or two coarser than the rest, may be quite sharply marked out, but none of these can be followed for more than about 50 yards; and a banding that is occasionally visible in the fine material dies away in a few feet. Where there is no deformation, the only structure visible is a plexus of irregular joints, and its aspect in the long lines of sea-cliff is that of a massive igneous rock. The typical material is a dull greenish-grey porcellanite, weathering to a cream tint, and almost invariably traversed by a multitude of thin, dark green, anastomosing veinlets, which impart a crackled ' appearance to the outer crust. On a fresh fracture, minute clastic grains are just perceptible under the hand lens. In thin section, the porcellanous matrix, which is turbid at first sight, resolves itself under a higher power into finely granular epidote and minute clots of sericite, but iron-ores are scanty. Plentifully strewn throughout it are small angular fragments, which often, indeed, have re-entering angles. A few are of quartz, but the great majority are of felspar, now almost entirely sericitised. The sericite, however, is often differently disposed in different lamellae, so that the twin-lamellation is itself pseudomorphed. The felspar was therefore triclinic. In a few cases it is fresh enough to show a positive optical figure, and extinction angles near to those of albite. In a coarse tuff at Porthmadog it is without doubt albite. The veinlets are partly of chlorite, partly of a honey-coloured pleochroic delessite.
The coarser bands resemble grits externally, but are essentially of the same nature as the porcellanite, their matrix being identical with that. The composite fragments may sometimes be seen to be of spilitic type, but there are also irregular chloritic bodies like lapilli of a basic glass. Fragments of a reddish felsite are also to be seen. In a few places there are thin, even, bands of purple phyllite and bedded jasper that resemble in every respect the similar beds in the New Harbour Group, some of them being composed of crypto-crystalline silica full of hmmatite dust and containing very minute clastic quartz and mica.
The green porcellanites are not often as homogeneous as at Clegyr-mawr: they commonly have a confusedly mottled aspect, and are full of yellowish matter. At a little cove south of Porth Trwyn a green gritty porcellanite is crowded with clots of pale, compact, epidosite, one-eighth of an inch or less in length, lying in beautifully parallel bands. But often a number of such clots will run together, so as to form a ragged-edged bed. This clot bed' is two to three feet thick, and its bedding is parallel to that of the adjacent rock. In other places, the same compact epidosite forms even-sided bands, which are sometimes very fine, but they are apt to be broken up into isolated fragments, and that in rock that shows no sign of deformation.
At Castell, Trefadog, is a sheared volcanic breccia with fragments of acid lavas, while north of Church Bay, fragments of keratophyre and mica-schist occur in a grit, and a massive gritty epidosite contains many pebbles about half an inch, and some of them two inches, in length, of acid igneous rocks, quartzites, and jaspers. They are of great stratigraphical importance, and are discussed on pp. 60.
A specimen of the typical porcellanite was analysed by Mr. J. O. Hughes.
SiO2 | 59.62 |
Al2O3 | 19.59 |
Fe2O3 | 2.66 |
FeO | 3.59 |
CaO | 2.82 |
MgO | 2.05 |
K2O | 3.56 |
Na2O | 3.51 |
H2O (at 110°) | 0.23 |
H2O (above 110°) | 2.52 |
100.15 | |
TiO2 with Al2O3, MnO with FeO |
(E9315)
It is therefore evident that the rock is a fine tuff of intermediate composition. Not only, however, are no lavas of andesitic type known in the Mona Complex, but it is difficult to suppose that it can have been produced simply by the explosion of such a magma. The proportions of most of the constituents, especially of its alkalies, are such as may often be found in andesitic lavas, but the calcium it contains is nearer to that of the dacites, for which it does not yield sufficient silica. The nature of the composite fragments of the coarser beds explains the anomaly, showing that the porcellanite must be a spilitic tuff with an admixture of rhyolitic debris.
Metamorphism
Deformation. There is perhaps a greater mass of undeformed material in this formation than in any other member of the Complex, which is probably due to its remarkable homogeneity, hardly any native planes being provided along which it might begin to give way. But eastward and southward it breaks down, and the process may be studied along the coast. Mylonisation sets in, confined at first to definite slips, but soon extending over zones of several inches. These become frequent, and then the whole rock acquires a rude fissility, along which the epidosite clots, and the veinlets, are drawn out into light and dark green lenticular streaks. In the midst of the massive porcellanitic tuff of Church Bay the process does not often get to this stage; but at one place a schist with a good long lenticular structure and a dull sheen has been produced for a few yards, which could not be distinguished from much of the material of the Gwna Beds. Near the junction with those beds, however, such material is found in abundance.
Silicification. The tuffs have been sporadically silicified, the final product being a fine white quartz-rock that graduates into the normal dull-green material. This, resisting the deforming stresses, has been cut up and sheared out into augen. The resulting rock simulates closely the Autoclastic Mélange of the Gwna Beds (pp. 65, 66), but its augen, instead of being blastopsammitic, are finely granoblastic. It is clear that the silicification is older than the great movements of the Mona Complex, and it may therefore be ascribed to a geyseritic episode that followed closely upon the eruptions of the tuffs themselves.
The Trwyn Bychan rocks of the north have (except that they are not, perhaps, quite so compact as a whole) the same peculiarities of composition and structure as those of Church Bay, and their extraordinary massiveness is finely displayed on cliffs more than 100 feet in height. In some places their epidosite clots appear to be genuine lapilli. But they have been far more deformed. Few parts have escaped, and considerable tracts have been transformed into a dull but fissile schist.
The Skerries Grits
The Skerries Grits are the 'Llanfechell' Grits of Dr. Callaway, but, as in the case of a similar group-name, that word scarcely runs 'trippingly' even off a native tongue; and as all the most interesting and important characters of the rocks are far more strikingly developed on The Skerries than at any other place, that name seems more appropriate as well as more euphonious. They are hard 'greywackes', generally rather coarse, and often pebbly; greenish grey inland, but green with subordinate grey mottling on The Skerries. The most remarkable thing about them is their unusual massiveness. On most of the sections no bedding whatever can be seen; and except at base and top it is rare throughout. They consist of quartz, felspar, and composite fragments, with abundant secondary epidote, chlorite, and sericite, and some iron-ores, most of which appear to be ihnenite. The felspars are chiefly albite, with some albite-oligoclase and micropegmatite. But the clastic grains are not closely crowded as in ordinary grits; they are visibly isolated by the matrix. This, which is of a low pistacio-green colour, plays an important part, and is identical in appearance with the green clots and mottlings of the Church Bay Tuffs. It looks turbid under a low power, but with a 4-inch objective is resolved into minute granules and prisms of epidote, clots and specks of sericite, and abundant chlorite.
This matrix is therefore the same as the fine epidosite of the Church Bay Tuffs, and as the composite fragments are for the most part volcanic, it is evident that much of the rock is of pyroclastic origin. At the Bull Bay section the proportion of matrix increases rapidly northwards; it then comes on in bands, and these in their turn increase until there is a complete passage by alternation into pure Church Bay Tuff. Further, we have called them 'grits', but there is reason to suspect that even their quartz is but partly epiclastic. Many of its grains have not the rounded or irregularly sub-angular outlines of ordinary sand; they tend to be quadrangular or triangular, sometimes with bays and re-entering angles. These are forms typical of the phenocrysts of the quartz-felsites. On the East Mouse, grains like them can be seen (p. 318) with still a little matrix adhering, and it is therefore likely that these detached grains are direct products of the explosion of an acid lava. The Skerries Grits, then, are far from being normal sedimentary rocks: the pyroclastic element in them preponderates, and, doubtless, to this is due their extraordinary massiveness.
The Conglomerates
Composite fragments are more plentiful as well as much larger than in any other member of the Mona Complex, and they are of great importance. Small ones, visible in thin section only, are extremely abundant, often exceeding in quantity the grains of quartz or felspar; and hand specimens usually show a good number that are about an eighth of an inch in diameter; but larger ones are rare upon the mainland, a few only having been found of half an inch or so in length. They are larger on the islets, there being a good many on the East Mouse that are an inch or two, and some even six inches across.
But by far the finest development is on The Skerries. There, and there alone, are true conglomerates in the Mona Complex. Bands occur at intervals all over the little archipelago, the pebbles being usually three or four inches across. But on Ynys Arw the conglomerate may be called a boulder-bed, being full of great oval blocks, most of which are six inches, many of them a foot, and some nearly two feet in diameter. They are well rounded, and being light in tint, stand out in strong contrast to the dark green matrix, so that the beds are very striking in appearance. But so tough and resistant is the matrix that the boulders do not always weather out, some even weathering into cavities. The grits contain many short bands, an inch or so in thickness, of a fine epidositic mudstone, with minute clastic quartz, which is of the same nature as the matrix. These bands may be finely bedded, but in the boulder-beds are broken up into long strips, and these into fragments, many of which are well rounded, so that contemporaneous erosion was at work.
All but a few of the larger pebbles in the Skerries Conglomerates are of acid igneous rocks, with a textural range from quartz-rhyolite to granite, and are very fresh and well preserved. The finest are compact, of a clear bluish purple tinge, and consist of a cryptocrystalline matrix that may once have been vitreous, in which are phenocrysts of quartz, often corroded, and felspar. At the other extremity of the suite are granites
Throughout the Skerries Grits, whether on the other islets or the mainland of Anglesey, the same acid igneous rocks contribute the majority of the larger pebbles, and they play the same role in the pebbly portions of the Church Bay Tuffs, as well as in the pebbly beds of the Amlwch alternating series, which are close to the junction of the groups, near the East Mouse. On the Middle Mouse is a variety composed entirely of micropegmatite with a few phenocrysts of albite. Not infrequent, but never in large fragments, are spilitic lavas of Gwna type.
Less in number, but of great stratigraphical importance, are pebbles of hard fine green grits, fine purple grits and hard purple mudstones, white quartzite, scarlet jasper, and schistose grit. Those of white quartzite (one of which was two inches in diameter) and of jasper were first found upon The Skerries. The jasper has all the characters of that which is known only in the spilitic lavas and limestones of the Gwna Beds, and the quartzite is not of Holyhead but of thorough Gwna type. The green grits are also very common in (though not confined to) that group. Many schistose fragments occur throughout the Skerries Grits, but in most cases their foliation is parallel to (though stronger than) that of the matrix of the grit, and might, perhaps, have been induced in situ. Some, however, can be found whose foliation is undoubtedly their own, for it is oblique, sometimes at a high angle, to thab of the enclosing rock. The largest of these that has been collected and preserved is shown in
It is certain, therefore, that a foliated complex exists within the region, whose metamorphism is older than that of the Mona Complex.
A few of the pebbles, in their turn, contain little fragments of yet older rocks. A purple ashy grit pebble from the Middle Mouse encloses pieces of the spilitic lavas: Those of quartzite from the Skerries Conglomerates contain fragments of tourmaline and of mica granulites. The formation from which these have been derived must be of extreme antiquity.<ref>As The Skerries are difficult of access, it may be well to mention that the same pebbles are well seen on the East Mouse, though not so numerous or so large, and usually deformed (p. 318). The East Mouse can be reached easily by a boat from Amlwch Port.</ref>
Deformation and foliation The Skerries Grits have been unequally deformed. In some parts the pebbles are smooth, oval, and uninjured internally even when quite small, and the secondary products have no definite orientation. Usually, however, the chlorite of the matrix is well foliated, and the sericitised fragments are drawn out into lenticular augen. The power of the deforming forces may be gauged by the fact that along certain zones that cross The Skerries large pebbles of rhyolite and granite are drawn out into thin lenticular strips
The Tyfry<ref>Pronounced 'Tyvry'.</ref> Beds
In the eastern parts of the Middle Region, and along the Malldraeth, where the metamorphism is of a low order, many strips of ashy grit and phyllite have been separated from the surrounding Gwna Beds. Most of them are green, but some are purplish. The contents of the ashy grits link them to the Church Bay Tuffs and Skerries Grits, with which they have accordingly been coloured. They are composed essentially of albite and quartz, with some large flakes of clastic mica, often much chloritic matter in the matrix, and iron-ores. Albite is usually in excess of quartz, and where the rocks are not much deformed the broken albites are sub-angular, often angular, sometimes with re-entering angles. Some are lath-shaped, but most are tolerably broad, and with polysynthetic twinning. The quartz is angular, sometimes tending to be square, as in the Skerries Grits.
Composite fragments are also plentiful. The most abundant are spilitic lavas, albite trachytes, and keratophyres, some of the trachytes containing porphyritic albites with the same broad habit as the isolated broken crystals. Fragments of a quartz-felsite are also present. Many of the spilites are. deeply hæmatised, and an albite grit on Llanddwyn, associated with jaspery phyllite, is luematised throughout. About Nantnewydd, Llangefni, and especially at Trefdraeth Church, are beds in which the matrix is a pale green epidosite of the same kind as that of the Church Bay Tuffs and Skerries Grits, and some of the finer bands are largely epidositic dust. These are true tuffs, and some of the ashy grits of Tyfry and other places are but slightly mixed with epiclastic sediment. Their volcanic materials were evidently drawn from the same sources as those of the pyroclastic rocks of the north and west, and they are therefore best placed with the Skerries Group. But their spilitic fragments, occasionally haamatised, and the hmmatisa-tion of some of the beds themselves, link them closely with the Gwna spilites, which are, in their vicinity, developed on a large scale.
Epiclastic fragments Besides these pyroclastic fragments the grits contain some epiclastic ones of great interest. These are of a true granoblastic mica-schist
Deformation At Tyfry the coarser grits are, for a short distance, free from cleavage, but this is exceptional. In all the other strips that are shown upon the map they are schistose, though usually less so than the surrounding Gwna Beds. About a mile beyond the Malldraeth Marsh, however, they are to be recognised only by their larger fragments, the finer parts having passed into a schist indistinguishable from the Gwna Green-schist. There is little doubt, indeed, that they are separable only in tracts of minimum deformation, and that their boundaries, as drawn, are not stratigraphical but arbitrary. It is impossible to distinguish the finer grits and phyllites with which they are associated (and which have been coloured with them on the maps) from those of the Gwna Beds themselves. No unconformity whatever can be found, and it must be admitted that considerable tracts of them have probably been included with the general schistose mélange which has been termed the Gwna Green-schist.
The Gwna Group
This group, which is found at intervals all over the Island, is here named after the vale of the little River Gwna, near Bodorgan Station, that being the only district in which every subdivision of the group is to be found.
The subdivisions in question are:
Alternating Green Grit and Phyllite (usually as Mélange)
Spilitic Lavas and Tuffs
Albite Diabases
Keratophyres
Quartzite (and black quartzite)
Limestone
Graphitic Phyllite
Jasper
Jaspery Phyllite
The diabases and keratophyres are closely associated with the spilitic lavas and tuffs, and constitute a single volcanic suite. The formation has a wider distribution than any other in the Island, being found at intervals all the way from Carmel Head to Garth Ferry. Except where it is involved in the Penmynydd Zone of metamorphism (a special phase which will be considered in connexion with that zone), this group has undergone less mineral reconstruction than the rest of the Complex; but it has been excessively broken up, so that bedding can seldom be traced for more than a few yards. The rocks that will here be termed Alternating Beds, Mélange, and Green-schist are undoubtedly phases of one and the same formation in different states of destruction and reconstruction: but the two last occupy so much more space than the first that they may be regarded, for Anglesey, as the normal states of that formation. On account of their great importance they will be allotted separate headings in this chapter. They have a characteristic aspect, and are not difficult to recognise, even without the aid of the other members of the Gwna Group.
Alternating Grit and Phyllite
Passage Beds.The original bedding is hardly ever seen for more than a few yards at a time, except in the zones of minimum deformation that skirt the Malldraeth Marsh. Here we find alternations of banded green phyllites and rather fine green grits, with purplish beds that graduate into the jaspery phyllites. They contain minute clastic micas, and the grits have a good deal of angular broken felspar which when determinable, is found to be allied to albite. The phyllites alternate near Llangefni with the fine epidosites, and the grits graduate by increase in the size of their fragments into the Tyfry Ashy Grits (with which, for convenience sake, both have been coloured on the maps); but both graduate, in the other direction, into the general mass of the Gwna sediments. The group must therefore be looked upon as a zone of passage from the Gwna Beds proper into the pyroclastic Skerries Group, and is decidedly more felspathic than the normal Gwna sediment. These passage beds, though traversed by more or less cleavage,, retain their bedding well, and it is fine and even. Minute filmy sericite has often developed along the cleavage, and some of the phyllites are excessively chloritic.
Alternating Beds
A picture of the normal Gwna sediment can be obtained only by consideration of such original characters as can still be made out in the mélange and green-schist. The materials were, speaking generally, grit and shale, the latter, however, having been reconstructed everywhere. Now, from an inspection of the strips and fragments of grit that crowd the mélange, it will be seen that the beds that were broken up to make them could not have been thick or massive (the few massive ones are ashy, and probably nips of the Tyfry Beds). A foot or two was probably the limit, and the average thickness not more than a. few inches, much the same being, apparently, the case with the shales; the series was, therefore, one of rapid alternation.
The grits are grey on parts of the northern coast, but everywhere else are greenish, with much chlorite in the matrix. Some are hæmatised. But nearly all of them are siliceous enough to weather white and quartzite-like. Not only are they much less felspathic than the Tyfry Beds, felspar (though always present) being often a mere accessory, but fragments of spilitic and other volcanic rocks are only locally abundant. Their felspar is of the usual sodium types, often albite, with some oligoclase, but orthoclase is also present. Rutile, tourmaline, and zircon are not uncommon, but garnet very rare. Some scarlet fragments are present, but whether these be jasper is not yet certain. The quartz is often of plutonic type, and there are fragments of sodium-granite, micropegmatite, albite-quartz-felsite, hypabyssal albite-rocks like those of The Skerries, keratophyre, and spilite, with some of schistose grit, quartz-schist, and mica-schist. Their texture varies usually between fine and medium, coarse grits with grains one-eighth of an inch across being rather rare. The form of their grains is that of true sediments, for though many are sub-angular, many also are well rounded. Besides the grits that are still visibly clastic, a fine siliceous sediment is an important member of the series, especially in parts of the Aethwy Region. It is a very fine hard granular material, sea-green with chlorite, but weathering white, and on weathered faces remains of clastic texture may sometimes be detected. A felspar of low refractive index is present as well as quartz, but the rock must have been an unusually fine siliceous sand. It occurs in seams that seldom reach a quarter of an inch in thickness, with partings of fissile matter, once a shale, so that the fine-bedded, alternating type of sedimentation is pronounced. These fine siliceous beds appear to have preserved their bedding ky reason of their amenability to folding, but they are almost the only ones that have preserved it.
Autoclastic Phyllite-and-Grit Mélange
This is really a gigantic autoclast, extending over many miles of country in several districts, as does the 'crush-conglomerate' of the Isle of Man, but on a still greater scale. It consists essentially of lenticular strips and lumps of grit
Rounded fragments are rare, but in the Cemaes district the mélange is more of a pseudo-conglomerate than elsewhere, having less parallel structure, both in me forms of the lumps and the nature of the matrix. Almost everywhere the lumps are phacoidal, their boundary curves meeting at sharp angles in the direction of the strike. The matrix is now a fine greenish or pale straw-coloured schist, composed of minutely flaky sericite (see p. 67) in curving sheets and seams, always with a considerable quantity of chlorite and some finely granular quartz. In the matrix of the northern breccias these minerals are but feebly developed, and the colour may be a dull grey. The matrix not only sweeps round the phacoids, but often invades them, so that they are traversed by films of it, along which they tend to part. And where the larger augen are not close together, it is full of smaller and smaller augen, as well as detached clastic grains that have been torn from them. In the cores of the augen the clastic grains retain often their original rounded outlines quite uninjured, but along the margins and the fissile films they are deformed and flattened. This may take place without 'crushing', but it is possible that matter has been stolen from the sides of the grain, thus thinning it. Undulose extinction is general, but far from universal. The matrix of the grit has become a mosaic, with which almost all the grains, felspar as well as quartz, interlock, especially at their 'ends', in the direction of the strike; so that the old clastic outlines are better seen in ordinary light than between the nicols. Many of the grains have broken up, optically, into a mosaic. In the unsheared areas there is a tendency to marginal enlargement of the grain at the expense of the matrix— In the shear-zones the mosaic of the grain becomes gradually incorporated with that of the matrix, into which it merges and finally disappears. The crystalline elements of such mosaic tend to be fusiform and nemablastic, especially towards the ends of the augen. These grit-augen are often excessively quartz-veined, especially in the Aethwy Region. There is usually a system parallel to the minor axis, doubtless a 'stretching' system, but more and more come in, sometimes to such an extent that in the meshes of their intricate net-work the original structure of the grit can hardly be made out.<ref>This mélange has been treated here because it is the usual condition of the alternating Grit-and-Phyllite member of the Gwna Group, which could hardly be described without reference to it. But it must not be forgotten that the Gwna Group as a whole is usually in the condition of an Autoclastic General Mélange in which all the members of the group are involved
The Gwna Green-Schist
This term is proposed as a brief convenient working designation for a widespread type to which, though undoubtedly a petrological unit, it is not easy to give a concise name based either upon its structures or its mineral composition. That it is confined, so far as is known, to the Gwna Beds, appears to be due to an accident of the folding, by reason of which a particular stratigraphical horizon has been brought on to a particular tectonic horizon over the greater part of Anglesey (see Chapters 7, 8).
The type is more easy to recognise than to describe. It is a pale sea-green schist, whose fissile seams tend to weather to a straw-colour; and usually dull upon the foliation planes, because of the small size of its foliating minerals. The hard parts are really much more siliceous than would be expected from their green colour, and often weather nearly white. Its aspect in the field is more irregular than that of any other member of the Complex, for it is not at all platy or evenly laminated<ref>Where a platy type does appear, it is really a survivor of the fine siliceous beds described on p. 65.</ref>; and hand-specimens have an undulating, almost lumpy, surface, apt also to be scored with fine striae, due to nemablastic foliation. This aspect is due to its being built up of lenticular overlapping sheets, often rather short and thick, of hard siliceous matter (too irregular to be called augen) with winding fissile seams between them, the whole being usually corrugated, sometimes cross-corrugated also. The essential constituents are quartz, chlorite, and a white mica, usually 'sericitic ' but sometimes in larger, though never well-formed flakes.<ref>Where, however, as in the Aethwy and Middle Regions, the rocks approach the Penmynydd Zone of metamorphism, the micas rapidly increase in size, and the grade of crystallisation rises generally.</ref> An alkali felspar, which where determinable is albite, seems always present, but not abundantly. There is usually a little haematite, and opaque iron-ores. The proportion of mica to chlorite is very variable; sometimes one is in excess, sometimes the other. The chlorite is apt to be in irregular sheets and clots as well as in minute flakes, but never in well-defined crystals; and there is generally less of it than would have been expected from the colour of the rock. A carbonate is not uncommon. Tourmaline, garnet, apatite, and zircon, have been observed, but heavy minerals are rather rare. In the more altered portions, a pale actinolite seems to be developed among the chlorite in minute needles, but its presence is obscured by that of the all-pervading sericite.
The irregular aspect of the rock is determined not merely by its megascopic but by its microscopic structures'
Several varieties may be noted. One is a purple schist or phyllite, which, however, is not the jaspery phyllite, for it contains albite, and differs from the green-schist merely by its richness in haematite. Another is a quartz-schist, nearly white
The Gwna Green-schists are traversed by vast numbers of quartz-veins at all angles, most of which are only a small fraction of an inch, but many also an inch or two in thickness. One series has separated along small cross-wrenches, imparting to the rock a look as if tied up by little cords at intervals; and some of the veins that cut across the dominant nemablastic foliation are themselves traversed by a similar one that is in line with it, softening the sharpness of their outlines and making them seem to melt off a little into the adjacent rock. Movement therefore was taking place at intervals, between which the rock was sufficiently brittle to be fissured. Yet the later movement was on the borderline of the molar and the molecular, for the veins are seldom shifted by it. In fact, the amount of segregated quartz in the Gwna Green-schist, especially in the Aethwy Region, is enormous, amounting sometimes to local metasomatism, though there is no reason to suppose that the silica was introduced from without. It is a product of the metamorphism, separating at several different episodes, and the presence of large albites in it shows that the temperature was still high.
Origin of the Type — The material of the Gwna Green-schist is without doubt of epiclastic origin. In almost all microscopic slides (unless taken from zones of exceptional alteration) a few clastic grains are to be found, and many schists that show no signs of such externally are crowded with small ones, many of which, however, have undergone partial absorption. Its nemablastic mosaic is identical with that into which the grits pass locally by deformation. Moreover, the Green-schist, when considered on the large scale, is found to pass gradually into the Autoclastic Mélange. If we cross the Gwna Beds of either the Middle or the Aethwy Regions in an easterly direction we find first, as we leave the Penmynydd type, a green-schist' with well-developed micas; then a normal green-schist, still completely reconstructed; then (the rock remaining the same in every other respect) isolated clastic grains appear; then small knots of them; then well-defined lenticles; until, as these increase in number, the type changes to that of the Autoclastic Mélange, whose lepidoblastic matrix differs from that of the schist merely in being rather less well-crystallised.
Put conversely, there is a progressive metamorphism from the Alternating group, through the Autoclastic Mélange, into the Green-schist. In the earlier stages we have disruption and deformation with subordinate mineral reconstruction; in the later, mineral change is obliterating the effects of deformation. There can be no doubt that the Green-schist is a curiously altered condition of a rapidly alternating grit and shale series, that its lepidoblastic schists represent the shales, and that the hard portions are the grits, now in the condition of siliceous mosaic, some nema-, some granoblastic. But the bedding has totally disappeared, and the schist, in spite of the low grade of anamorphism, often retains no traces of its origin.
The following analyses have been made of Gwna Green-schists and of a grit from the Autoclastic Mélange.
I | II | III | IV | V | ||
SiO2 | 72.76 | 74.19 | 62.38 | 63.65 | 5315 | |
TiO2 | 0.45 | not est. | 0.46 | 0.60 | 0.55 | |
Al2O3 | 12.49 | 14.52 | 15.35 | 17.10 | 23.15 | |
Fe2O3 | 1.07 | 0.75 | 1.75 | 1.17 | 1.11 | |
FeO | 3.69 | 2.04 | 4.77 | 5.12 | 5.95 | |
MnO | 0.41 | not est. | 0.20 | 0.37 | 0.07 | |
CaO | 0.43 | 0.08 | 2.36 | 0.28 | 0.29 | |
BaO | 0.03 | not est. | 0.02 | 0.03 | 0.04 | |
MgO | 1.57 | 1.09 | 2.80 | 2.42 | 3.08 | |
K2O | 2.11 | 1.21 | 0.21 | 3.63 | 5.22 | |
Na2O | 2.10 | 4.74 | 3.64 | 1.81 | P84 | |
CO2 | 0.34 | none | 1.70 | none | none | |
SO3 | 0.06 | not est. | 0.04 | 0.02 | 0.03 | |
P2O5 | none | not est. | 014 | 011 | 017 | |
H2O at 110° | — | 0.15 | — | — | — | |
H2O (combined) | 2.79 | 1.13 | 3.76 | 3.78 | 4.69 | |
100.30 | 99.90 | 99.58 | 100.09 | 99.94 | ||
Spec. Grav. | 2.735 | 2.768 | 2.748 | 2.784 |
Nos. I, III, IV, V; were kindly made by Mr. Edmund Dickson, in the year 1900, in aid of the present work. He remarks that a little carbon is present, and that S03 belongs to sulphates soluble in hot dilute HCl. It is probably from the oxidation of pyrite.
I. Pale green grit, lenticular mass in Autoclastic Mélange. Same type but not collected at same time as (E9825)
II. Hard siliceous part of Gwna Green-schist. Roadside, at a farm (Ysgubor-fawr of six-inch map), 442 yards north-east of Soar Smithy, north of Bodorgan Station (E10426)
III. Typical Gwna Green-schist. Roadside, 760 yards north-east of Garth Ferry Inn (at B.M. 77.0 on six-inch map) (E9911)
IV. Typical Gwna Green-schist. Same locality at Llansadwrn as No. I, but from quarry on north side of road (E9934)
V. Gwna Green-schist. Locality record lost, but from near Llansadwrn.
Comparison with the composite analyses given on p. 49 shows that these rocks are not normal grits and shales. Iron is high throughout, and the relative proportions of Fe2O3 and FeO are the reverse of those in ordinary sediments. In I and II the alkalies are high, as well as the aluminium, and sodium tends to be higher than potassium, due respectively to muddiness of the grits and to the presence of albite. In III, IV, V the silica, too high for a shale, is due to the intimate interfelting of thin seams of grit, which could not be eliminated in collecting. The relations of sodium to potassium are variable, and there seems less albite in (E9911)
As in the case of the Green-mica-schists of the New Harbour Group (see p. 50) the persistent green colour of these rocks conveys an impression (shared, again, by Dr. Teall when traversing them in 1911) that they contain an admixture of volcanic dust, and this is borne out by the analyses. They are rich in iron, their alkalies are high, and their magnesium somewhat (though less than would be expected) above that of normal sediments. In the Gwna Series, as in the New Harbour Group, there are spilitic lavas; and in this case tuffs are also known. It is reasonable to suppose that fine dust of their explosions was carried in small quantities (probably from some distance away) over the basin of deposit throughout the period represented by the Alternating group, and that this accounts for the composition and colour of the rocks. Moreover, the green colour is most pronounced in the Aethwy and Middle Regions, and those are the regions where the spilitic lavas and their tuffs are developed on the greatest scale. On the northern coast the colour is feeble and often absent altogether, and there, accordingly, the development of the volcanic rocks is feeble also. A noteworthy difference between the New Harbour Beds and the Gwna Green-schist is that the former contain an unusual proportion of titanium, the latter very little. This, again, reflects the composition of the lavas; for those of the New Harbour Group are rich, those of the Gwna Beds (whether in their original or schistose condition, see pp. 74, 78) poor in that element.
The Spilitic Lavas
The Spilitic Lavas, where unmodified, are massive, and thoroughly igneous-looking, but too fine in grain for their texture to be visible by the unaided eye. Under the band-lens, on polished or wet surfaces, a mesh-work of little crystals can be seen, with, sometimes, a few felspar phenocrysts. The normal colour is a pale grey-green, but reddish mottling is rather common, and this may extend itself until the whole rock is of a uniform low purplish tint. Far more striking is their aspect in the field, for, where undeformed, they always display the characteristic ellipsoidal or pillowy structure, sometimes in great perfection. On Llanddwyn Island and among the dunes of Newborough, boss after boss is built up entirely of these curious pillowy bodies, often with small interspaces (which are usually filled with jasper, but sometimes with limestone), often pressing one another's sides into gentle re-entering curves that impart a strangely vivid sense of softness, and suggest the rolling over and over each other of pasty masses, kept from adhering by immersion in such a medium as the water of the sea. Under the incessant sandblast, they are not obscured by soil or vegetation; are not blurred even by a weathered crust; are as fresh and clean at the surface as they are within; and look almost as if their motion had been arrested but yesterday
What may perhaps be called the normal spilite
A marked feature of the Gwna spilites (and indeed all the spilites of the Mona Complex) is the frequency with which they display variolitic structure, sometimes in great perfection. It may be remarked that the best variolitic developments have not, so far, been found to be coincident with the strongest developments of the pillowy structure. In some of the augitic rocks no variolitic arrangement is discernible. In others, the little felspars begin to form the rudiments of sub-radiate groups and brushes, and sometimes the augite rods also are grouped in the same way, so that we have the beginnings of a variolitic structure. This can be traced in other slides through further stages, until the rock would certainly be called a variolite. The highest developments are reached, however, in the anaugitic rocks, in some of which the whole body is a plexus of radiate groups and brushes of delicate lath-felspars, as in the beautiful variolite (E9843)
The spherulites with definite boundaries, already described as visible to the unaided eye (E9956)
The Gwna spilites display in a high degree the decomposition now known to be characteristic of such rocks. Fresh augite has been found in a few slides only, and the felspar is generally riddled with cavities now filled with chlorite, epidote, sericite, calcite, and quartz. The glasses have been converted into chlorite, epidote, quartz, and iron-ores. Often the decomposition is complete, and the felspars are mere pseudomorphs. The steam-cavities are filled with the same secondary minerals. Hzematisation, unusual in other British districts, is very frequent in the Gwna spilites, and is the source of the purple nolouration already noted. When haematite is abundant chlorite is rare, and sometimes every mineral of a lava has been replaced by haematite except the felspar, which then, whether fresh or sericitised, is clearly outlined by it, as in (E9843)
Finally, it can be shown in many cases that the decomposition, the hmmatisation, and the albitisation all took place before the shearing, and therefore before the great movements of the Mona Complex. There are spilites in which all the felspars have the cores decayed and the margins clear and fresh. Where such have been a little sheared many of the felspars are broken and slightly shifted along the planes of movement, sometimes a single crystal by two or three such planes. The fractures are unhealed, and the shifted fragments correspond exactly, margins to margins, cores to cores, each zone being in the same condition in each fragment.
The following analyses will show the relations of these rocks to the spilites of other parts of Britain.
I | II | III | IV | V | VI | |
SiO2 | 47.45 | 50.05 | 51.31 | 46.4 | 48.58 | 47.56 |
TiO2 | with Al2O3 | trace | 1.92 | 0.24 | 1.77 | 2.40 |
Al2O3 | 17.54 | 17.34 | 12.67 | 20.4 | 14.58 | 14.27 |
Fe2O3 | 2.04 | 3.18 | 0.54 | 6.9 | 1.89 | 1.63 |
FeO | 7.44 | 7.92 | 7.99 | 7.65 | 6.80 | |
MnO | not det. | — | 0.45 | — | 0.46 | 0.30 |
(Co, Ni)O | not det. | — | ? trace | — | 0.03 | 0.08 |
CaO | 10.96 | 9.06 | 8.17 | 7.7 | 9.80 | 10.95 |
MgO | 6.72 | — | 2.19 | 3.5 | 6.36 | 4.90 |
K2O | trace | — | 0.54 | 0.54 | 0.43 | 0.27 |
Na2O | 3.93 | 4.43 | 5.21 | 6.93 | 4.02 | 4.61 |
H2O at 110° | 0.23 | — | 0.04 | 1.1 | 0.68 | 0.42 |
H2O (above 110°) | 2.67 | — | 2.31 | 2.93 | 2.65 | |
CO2 | 0.55 | — | 6.15 | 5.8 | 1.00 | 2.95 |
P2O5 | not det. | — | 1.37 | — | 0.45 | 046 |
99.53 | — | 100.86 | 99.51 | 100.63 | 100.25 |
I. Boss south-west of Bryn Llwd, Newborough Dunes (E9895)
II. From close to the same spot. Anal. C. T. Gimingham (for which I am indebted to the kindness of Sir William Ramsay) in 1903 (E9895)
III. Tayvallich Peninsula, Argyllshire. Anal. E. G. Radley. Geology of Knapdale, Jura, and North Kintyre' (Mem. Geol. Surv.), p. 87.
IV. New Cumnock, Ayrshire. Anal. J. J. H. Teall. 'The Silurian Rocks of Britain, vol. I, Scotland' (Mem. Geol. Surv.), p. 85.
V. Mullion Island, Cornwall. Anal. W. Pollard. 'Geology of the Lizard and Meneage' (Mem. Geol. Surv.), p. 185.
VI. Tregiddon, Cornwall. Anal. E. G. Radley. Loc. cit.
Nos. I and II are from the large pillows, shown in
Compared with those from other British districts, they are on the whole finer, perhaps more often glassy, and olivine is not quite as rare as usual. The tendency to variolitic structure is more pronounced than elsewhere. Though they have undergone the characteristic early decomposition, they have been less extensively albitised, but more often hmmatised, than the other spilites of Britain.
Azinite — The spilitic lavas are traversed at the north end of Llanddwyn by a six-inch vein of a heavy mineral (E11389)
The Tuffs
These are usually green, but sometimes haematised. Most of them are of medium grain, but some are agglomerates with fragments of jasper and blocks of the lavas that may be several inches in diameter. Some of these are isolated ellipsoids, as if detached by explosion during flowage under water. The tuffs are distinctly bedded and, at the north end of Llanddwyn, some bands of pillowy lava from one to two feet thick appear to be interbedded with them. They consist of a completely chloritised or haematised base in which are (sometimes with a few round grains of quartz) jagged and torn lapilli, sometimes vesicular, of highly felspathic lavas, identical in character with the adjacent spilites, some of them even delicately variolitic. They are true spilite-tuffs, and are of no small interest; for, if any doubt on the point could be entertained, they show that the spilites themselves must be regarded as contemporaneous outflows. Some are full of fragments of the banded glass already described, and are thus allied to the 'palagonite tuffs'.
The Albite-Diabases
Being externally dull 'greenstones' of medium grain, these present nothing special in their external appearance. They are composed of albite, pale brown augite, iron-ores now generally leucoxenised, and sometimes a few pseudomorphs that may be after olivine. Fresh augite is rather more frequent than in the lavas. Nearly all the determinable felspar is albite, in laths that penetrate the augite ophitically, but porphyritic varieties are occasionally, though very rarely, seen. Sometimes it is decomposed throughout; but there are many zonal felspars whose cores
Hornblende-diabase — There is a sill on Llanddwyn composed of large plates of green hornblende and albite, some of which only is in ophitic relation, and large grains of leucoxene. With this may be considered the large epidiorites of Bodowen Warren, heavy green rocks with lustre-mottled fibrous pale hornblendes a third of an inch in length, and full of yellow epidote. Their felspar is albite, but is often almost entirely replaced by pleochroic epidote in large hypidiomorphic crystals, which here and there penetrate the plates of hornblende ophitically; and there are some iron-ores, partly leucoxenised. The hornblende is in well-formed plates, but contains good-sized cores of a nearly colourless augite, and is therefore, secondary. But it is older than part of the movements, for the product of its deformation is not a hornblendic but merely a chloritic schist. The adjacent Gwna grits and phyllite have been baked and at Bone Twni cove converted into a true adinole, composed chiefly of albite, with iron-ores.
Keratophyre
Where recognised in situ, this is a fine, dull-green, speckled rock. Small phenocryts of either albite or orthoclase, fairly preserved, are 'scattered freely in a fine matrix which is now green with chlorite. This has been composed essentially of minute rods of felspar, and there are grains of magnetite, but no recognisable pseudomorphs after ferro-magnesian minerals. The contents of conglomerates (pp. 62, 251) reveal that keratophyres must have been abundant.
Basic Schists
Catamorphic Schists — The tracts of undeformed spilite are never wide, and along their margins the lavas break down rapidly, so that even their pillowy structure may become inconspicuous in 100 yards across the strike. The soft skins' give way first, then the outer portions of the pillows, which break up along the concentric shells, the fragments shearing into phacoids, and the hard cores into larger phacoids, about which dark green schistose matter winds. This gradually increases at their expense, until all is converted into a dull green schist in which lenticular structure may hardly be discernible, as may be seen very clearly along the -western side of Llanddwyn. Internally the process begins by appearance of planes which break the felspar laths that lie across them. More of these appear until they are quite close together, by which time the ferro-magnesian minerals have been converted into a sheet of schistose chlorite, with grains of calcite and epidote. Such a rock, while showing no sign of igneous structure to the unaided eye, will still be full of broken felspars, and may be called a spilite-schist. The felspars then break further down into a micro-breccia, and igneous texture disappears. Finally the felspar breaks down chemically also, into kaolinous and epidotic dust with streaks of sericite, interfelted with the long-since schistose chlorite. Such are the chlorite-schists of Llanddwyn and other zones along the margins of the spilites; dull-green, with parallel structure, but no banding, rough upon the foliation-planes, unelastic, and shattering under the hammer. Where the spilites had been hmmatised, the resulting schists are purple, and may easily be confused with the purple phyllites that are often their associates. Rocks of this kind are built up of minerals that may arise as products of mere decomposition (though probably not of mere weathering); and are to be regarded as degradation-schists, their foliation not being anamorphic.
Anamorphic Schists — In the Middle Region, however, from Llyn Coron to the Cefni, there is a great zone of basic schist (p, 352), derived from spilitic-lavas (which will be called, from the crags of Cerig-engan, the Engan spilite), that is very different in aspect. It is compact, heavy, dark green, with a fine parallel foliation, smooth upon the planes, and with a faint lustre, sometimes even a banding due to thin epidotic seams, while wriggling epidotic veins cut the foliation, and is tough and elastic, not shattering under the hammer. This rock is a dense felt of chlorite, full of granules of pleochroic epidote, with some iron-ores (often octahedral), a varying amount of quartz, and minute grains that seem to be an alkali felspar. These are still the minerals of the degradation-schists, though they are far better crystallised and interfelted. With a higher power, however, the chlorite is found to be full of minute short needles of a pale green hornblende. The physical properties of the rock are therefore due, not merely to a better foliation, but to the presence of the hornblende. The rock is a true granoblastic anamorphic-schist, though of a relatively low order.
In the Aethwy Region there are also large tracts of basic schist that are just as certainly derived from these same lavas. Heavy, dark-green, while on the whole fine in grain, they are still better foliated than those of the Middle Region. A platy character is general, there is greater fissility, the foliation begins to show small corrugations in a hand specimen, and in the field is seen to be powerfully folded, while the divisional planes, especially towards the western margin where they approach the Penmynydd Zone, acquire a low but a decided lustre. Their mineral components are the same as in the group just described, but the crystal individuals are clearer and larger. Most noteworthy is the amount and the condition of the hornblende, a sure measure of advancing metamorphism. Minute in the Middle Region, this is now easily visible with a one-inch objective. The chlorite is shot through and through with it, flashing up, when the nicols are crossed, in countless needles, which in some cases approach 0.5 mm. in length. Perhaps chlorite even then preponderates, but the rock has become an actinolitic epidote-chlorite-schist. Thin pale seams are always present, and swell out locally to an inch or two. Some of these
The following analyses of typical basic schists from the Middle and the Aethwy Region respectively show that their composition is essentially the same as that of the spilites, for the differences from any one spilite are no greater than those of the spilites from each other. There are two exceptions: the curious reversal of the proportions of calcium and magnesium in No. II (may this. be a slip of the pen in transcribing No. II?) and its ferric iron, for a consideration of which see p. 88.
I | II | III | |
SiO2 | 45.94 | 45.86 | 47.89 |
TiO2 | trace | 0.97 | — |
Al2O3 | 17.39 | 15.83 | — |
Fe2O3 | 4.68 | 2.84 | — |
FeO | 7.49 | 7.96 | — |
MnO | trace | 0.32 | — |
CaO | 11.05 | 5.64 | — |
BaO | not det. | 0.02 | — |
MgO | 8.29 | 10.76 | — |
K2O | 0.14 | 0.17 | — |
Na2O | 2.86 | 3.49 | — |
H2O at 100° | 0.24 | — | — |
H2O (above 100°) | 2.22 | 5.14* | — |
CO2 | none | 0.64 | — |
SO3 | not est. | 0.17 | — |
100.30 | 99.81 | — |
I. Chlorite-epidote-actinolite-schist (E10019)
II. Actinolitic epidote-chlorite-schist (E9913)
III. Similar schist, but with a little glaucophane (E10208)
The Quartzites
These rocks are very massive and uniform, bedding being discernible at a few places only, most of which are on the northern coast; and on the whole are fine in texture, though clastic grains are usually to be seen under the hand-lens, and often by the unaided eye. Internally there may be a tinge of blue or green; and they are apt to oxidise to a light brown within a few inches of the surface, but all weather white externally. They are almost wholly composed of quartz, felspar being no more than an accessory, and sometimes absent. All the determinable grains are albite. Zircon, tourmaline, and rutile are generally present, and in some slides quite a number of the two first are to be seen, the zircon being sometimes in beautiful doubly-terminated crystals. A few of them are to be found enclosed in the grains of quartz, in which are also minute 'hairs' like rutile, and moving bubbles, all of which are characters of the quartz of granitoid or gneissoid rocks. Fragments of fine mosaic rocks are not uncommon, a few of which are granoblastic mica-granulites, and one or two of these are foliated and are true mica-schist (E10196)
SiO2 | 96.40 |
TiO2 | 0.05 |
Al2O3 | 0.84 |
Fe2O3 | 0.31 |
CaO | 1.22 |
MgO | 0.21 |
K2O | 0.16 |
Na2O | 0.04 |
Loss at 109° | — |
Loss over 109° | 0.34 |
CO2 | Nil. |
P2O5 and SO3 | Nil. |
99.57 |
Dried at 109°. Anal. J. W. Mellor, D.Sc., Director of the County Pottery
Laboratory, Stoke-on-Trent, March, 1909. aterial composite, from a number of blocks then at the Basin Wharf, Stoke-on-Trent.
The amount of lime is remarkable, for it cannot have been calcite, and in two slides (E10953)
Metamorphism
An old secondary enlargement of the grains, anterior to the regional metamorphism, and resembling that found in ordinary quartzites of non-metamorphic regions, can here and there be detected; but it has been obliterated for the most part, and the union of the grains with the elements of the matrix, which is very common, and has in great measure destroyed their epiclastic relations, is due to incipient granoblastism. The matrix has become finely granoblastic, and its micas are often foliated, sometimes enwrapping the clastic quartz, but more often penetrating it after the manner of a true schist. Along planes of deformation the clastic grains begin to break down into a mosaic like the matrix, which grows at their expense. Undulose extinction is common along the northern coast, where the rocks are less reconstructed.
The Quartzite of Mynydd Bodafon has peculiarities of its own. Where unfoliated, this is full of unoriented mica like that of the adjacent hornfels, it has a 'glassy' fracture, and there is reason to think that it has been thermally affected by the granite. It is rich in zircon, one perfect crystal of which
Black Quartzite
Only one or two thin beds of small extent are known, all on the northern coast; but much more of it must exist about the middle of the Island, for pebbles abound in the Arenig conglomerates of Bod-Deiniol, which indeed led the writer to search for it in situ. The rock is a true quartzite with conchoidal fracture due to the usual cement of secondary quartz, but is dark almost to blackness. There is russet oxidation on the joints, and a little in the matrix. Two colouring matters are present: one which transmits a faint brown light when cut thin, another which is opaque even in the most minute specks. The first occurs as films in the matrix, the second as little clots and granules that penetrate the clastic grains of quartz along their cracks and along the bands of inclusions that pass from grain to grain. Mr. J. O. Hughes has investigated the colouring-matter in (E10508)
Limestones
Amid many variations, two principal types can be distinguished: the Simple or 'Cemaes' type, and the Complex or 'Llanddwyn' type.
The Simple Type
The Simple type is, normally, a very massive blue-grey rock, rather fine in grain and uniform in aspect, and is composed of a mosaic of clean calcite. Small round grains of quartz, though very rare at Cemaes, are found in other places. From their form and distribution they are evidently clastic, but in the present condition of the rock interlock with the adjacent calcite. Films of carbon are generally present. Fine parallel bedding can sometimes be seen on the margins of the massive rock. Oolitic structure is not uncommon, and is highly developed at Cemaes Bay, where the rock is, locally, a true pisolite, for a good many of the grains are as much as a quarter of an inch in length. The larger ones are usually flattened, but there is no sign of this being due to deformation, and flattening is also common in the 'Pea-grit' of Cheltenham. Some have good concentric structure, otners are mere shells, the mosaic being finer in the oolitic rings than in the matrix. Many of the grains are compound
I. | II. | |
CaCO3 | 96.560 | 53.11 |
MgCO3 | 0.776 | 42.61 |
Ca3(PO4)2 | 0.091 | not est. |
SiO2 | 1.650 | 3.70 |
TiO2 | — | not det. |
Al2O3 | 0.040 | 0.44 |
Fe2O3 | 0.076 | |
FeO | 0.182 | not est. |
MnO | trace | not est. |
K2O | 0.069 | none |
Na2O | 0.016 | none |
H2O ('Combined') | 2.270 | not est. |
C | 0.228 | not est. |
101.958 | 100.10 | |
Percentage CaCO3 | 53.11 | |
MgCO3 | 42.61 |
I. Fine limestone from Cemaes. Anal. Holland and Dickson. Proc. Lpl. Geol. Soc. 1890 Cf. (E10518)
II. Grey limestone. Pedair-groeslon kiln, 15/8 mile north of Menai Suspension Bridge (E10801)
The exact locality of No. I. is not given, but there can be little doubt that it came from the large quarry west-north-west of Gadlys (Penrhyn-mawr of the six-inch map) (E10518)
It is not easy to see with what element in such a rock so much water could be combined, and the high total suggests that the powder must have absorbed moisture between weighing and ignition; also possibly CO2 absorbed by free lime in the CaCl2 used. Mr. J. O. Hughes tells me that he treats his own CaCl2 with a stream of CO2 before using it. In No. II., Residues insol. in 'HCl' have here been placed under 'SiO2', as it can be seen from thin section that there is no such material but quartz, in veins. The body of that rock is therefore a nearly pure dolomite. In the Cemaes rock there is so little granular quartz that the SiO2 may safely be taken to be that of the veins. If, therefore, we eliminate this, as well as —say—two per cent. for moisture, it will be seen to be a nearly pure calcite-limestone.
The Llanddwyn Type
This class, well-developed on Llanddwyn, includes really several sub-types, differing considerably from one another. They vary, also, with great rapidity, the character of the rock changing often in the space of a yard or two, so that no adequate picture of the class can be conveyed in words. Three sub-types may be distinguished, namely, rose-coloured, green, and breccia-limestones. Nearly all of them are massive.
The first sub-type is the one that is most characteristic of the class. It has a delicate rose-colour, is of medium grain though saccharoid on fracture, and tends to be rather hard. All the rose limestones are magnesian, and the typical one analysed is a thorough dolomite.
Residues insol. in HCl | 5.84 |
Al2O3 +Fe2O3 | 2.72 |
MnO | trace |
CaO | 29.93 |
MgO | 18.76 |
CO2 | 42.84 |
100.09 | |
Percentage CaCO3 | 53.44 |
MgCO3 | 39.19 |
Llanddwyn Island, south of Lifeboat Station (on six-inch map, at west end of Pilots' Cove Breakwater) (E10100)
The iron resides chiefly in thin brown skins between some of the elements of the mosaic, but the rose-colour is diffused throughout the grains, and so the carbonate of these rocks may be regarded as a dolomite with a slight. isomorphous admixture of rhodochrosite. The tint of the rose limestones, indeed, is precisely that which is found in so many of the manganous salts; and it is known that surprisingly small quantities of manganese are sufficient to diffuse that tint throughout a crystal. Quartz in allotriomorphic grains and veinlets is always present; and there are small aggregates of a white mica, flakes of which are also to be found enclosed in the grains both of quartz and dolomite. Sometimes there is a good deal of granoblastic albite.
The green types are really varieties of the rose limestones that are mottled with aggregates of chlorite, usually also with iron-ores. These are the most variable rocks of all, composition, and still more, texture,. often changing within the limits of a hand specimen, while a few of them are banded. Others have a rudely spherulitic structure, their chlorite aggregates being set in a frame-like ring of carbonate. In the coarser parts of the mosaic the carbonates are idiomorphic, and sometimes there are rhombic pseudomorphs of chlorite with a core of carbonate. They are also less dolomitic, the larger rhombohedra being zonal, ruddy dolomite within and clear greenish-white calcite without. Their quartz is apt to be moulded on the faces of such rhombohedra. All these limestones are much veined, both by quartz and by a carbonate, which is almost invariably white calcite.
Breccia Limestones — At a good many places the rose-green limestones are studded with angular green and purple fragments a quarter to half an inch, and sometimes as much as two or three inches, in diameter. Quite half the bulk may be composed of them, so that the limestone comes to function as the matrix of a many-coloured breccia, which is a beautiful and striking rock. All these fragments are volcanic, and those that retain definite internal textures can be recognised as the spilitic lavas. The purple ones
Ellipsoidal Limestones — Some of these limestones, however, have a remarkable ellipsoidal structure, which at once recalls that of the spilitic lavas
Dynamical structures
are not conspicuous, even where the adjacent rocks are highly schistose. Carbonates, however they may be reconstructed under stresses, are not apt to acquire a foliation, and may even protect their enclosures from acquiring it, doubtless from the ease with which the mass yields as a whole. The northern oolites are traversed by slide planes, along which the oolitic grains are cut and shifted. Where the ashy limestones are full of fragments, these are often deformed, and impart a schistose structure to the whole. The hæmatised spilite fragments, whose 'eisenglimmer' lends itself to foliation, have become so schistose as to simulate the purple phyllites. But even where massive, it is evident that the limestones have been profoundly reconstructed. The presence of allotriomorphic felspar and of well-formed flakes of mica, reveals that they are truly anamorphic rocks. It is, indeed, somewhat surprising that calc-silicates do not seem to have been formed in them.
Graphitic Phyllite
Adjacent to the laminated outer parts of the simpler, grey, limestones are beds of soft black schist or phyllite, seldom exceeding a few inches in thickness. They yield a strong black streak, and soil the fingers, but have a faint sheen upon the foliation planes. In the northern districts they are in actual contact with the limestone, and are themselves calcareous, the carbon films of the Cemaes Limestone being really an attenuated form of the same deposit. They are composed of parallel seams of carbon, with fine granular quartz and a little white mica, parted by thin bands of calcite mosaic. The carbon is not mere dust, but is in authigenetic scales, and is evidently graphite.
The Jaspers
According to the rock in which they are found, these may be termed Limestone- and Spilitic-lava- (or briefly) Lava-Jaspers; but the two differ in habit only, not petrologically. The lava-jaspers fill the spaces between the ellipsoids of the spilites
The rocks are composed
The spherulites display several stages of development. Some are mere shells of haematite dust in ordinary quartz mosaic which has the same structure within and without the shell, so that between the nicols they tend to disappear. The first of the true spherulites are tracts of colourless mosaic in which the elements become elongated, fusiform, and radially arranged, so as to yield an incipient cross. The higher stages of development are approached by these becoming more finely and definitely radial, and at the same time picked out with spherical zones of keinatite. Some of the larger ones contain only about a dozen elements of quartz, which widen out greatly towards the margin. The most perfect
Origin of the Jaspers — From the small dimensions of the jasper-bodies, and from their mode of occurrence, it is impossible that they can have been silicified rhyolites. But the relations of some of them point to their being local silicifications of the spilites. Occasionally the red matter has an outer shell of pale greenish quartz, that seems to graduate into the surrounding igneous material. There are also (as well as the definite and dense inter-ellipsoidal nodules) rather loosely knit aggregates with ragged margins, outside which may be isolated spherulites in the midst of lava substance. Thin vein-like strings, too, may sometimes be seen.
On the other hand, felspar pseudomorphs have not been detected, even where in close contact with the spilites; and so far from their spherulites representing those of the lavas, the latter usually lack spherulitic structure at the junction. The jaspers of the vesicular spilite of Cerrigceinwen have been searched for pseudomorphs of its amygdules, but with indecisive results. For, though they are spher-ulitic, so are those in many that are not vesicular; and though some contain oval bodies that might represent amygdules, they are grouped as are the spherulites, not as the isolated vesicles. And some nodules in the midst of lava crowded with vesicles are as dense and homogeneous as any in the Island. The identity in character of the limestone- and the lava-jaspers is not in favour of their being silicifications of either of those rocks. Moreover, limestone, banded, fine, and granular, fills (just as in Scotland) some of the interspaces of the lavas instead of jasper; and on Llanddwyn may occasionally be seen to have been the first of the deposits on the walls of the cavity, and to enclose a core of jasper. It is not easy to see how such a jasper core can be a pseudomorph of lava substance.
Their modes of occurrence are, in the one case, that of cataclasts of chert nodules in deformed and reconstructed limestone; in the other, identical with that of radiolarian chert in ellipsoidal spilite, as may be seen by comparing
The following are analyses of typical Gwna jaspers:
I | II | III | |
SiO2 | 88.07 | 93.52 | |
Al2O3 | 1.31 | None | 0.27 |
Fe2O3 | 10.75 | 6.56 | 1.76 |
Alkalies | None | None | 0.51 |
10013 | 100.08 | 99.70 |
I. Lava-Jasper, in interstices of spilite. Cerig-mawr, Newborough, 742 yards north-east of Llanddwyn Island (E10306)
II. Limestone-Jasper. 700 yards north-east of Llanddwyn Island: a little to the east of (I). The great (20-ft.) jasper (E10307)
III. Limestone-Jasper. 300 yards south-west of Hendre-bach, Cerrig-ceinwen (E10012)
Except in their high percentage of Fe2O3, they compare closely with the analyses of seven cherts given in Bull. U.S. Geol. Surv., No. 224, p. 297, but differ in several respects from those of nine siliceous sinters there given, in which (among other differences) there is a loss on ignition ranging from 2.29 to 7.50 per cent.
Metamorphism of the Jaspers
The structures described above, though denoting great internal alterations, are found only where the spilitic lavas have suffered little or no deformation; and are therefore older than the regional metamorphism. Elsewhere, especially in the Middle and Aethwy Regions, they are involved in that process. Torn, by reason of their hardness, from out their enclosing rock, they often become parts of an autoclastic mélange, cut into thin lenticular strips and interfelted with phyllite and with crystalline mica-schist. They then undergo internal deformation, their quartz-mosaic becoming nemablastic and their haematite foliated. The structure is not merely catamorphic, for both minerals are now new crystalline grains, and the carbonates are often perfect rhombohedra even in thorough jasper-schist. Thin quartz veins in them are cut and shifted, especially at the micaceous folia, some of which pass right through the shifted vein. The veins are also cross-foliated without being shifted (E9965). Where enclosed in limestone, the easy plastic readjustments of that rock have protected them. But in the Engan belt of the Middle Region, where they are enclosed in great flows of spilite that have been converted into actinolitic epidote-schists, they have not only become schistose but have suffered a metasomatic change. Their concave ellipsohedra have been drawn out into long lenticular augen, and they acquire the foliation just described; but concurrently with this begin to lose their colour, and finally become bleached altogether, passing into a white quartz-schist.<ref>Many years ago Dr. Horne drew my attention to a loss of colour in the Torridon Sandstone where traversed by the Post-Cambrian thrust-planes. See also ' Geology of the North-West Highlands of Scotland' (Mem. Geol. Surv.), pp. 581.</ref>
It would appear as if the iron must have been absorbed by the enclosing rock, and we find, accordingly, that the basic schist of this tract yielded 4.68 Fe2O3 as against 2.04 and 3.18 in the New-borough spilite (see pp. 74, 78) and still lower percentages in the Scotch and Cornish rocks. In this district all stages of the bleaching can be studied, but no one would recognise jasper in an isolated specimen of the final product; and it is possible that some of the siliceous augen of still more altered basic schists may have originated in this manner (pp. 118, 120).
The Jaspery Phyllites
These are fissile purple rocks, closely resembling those of Amlwch (see p. 52). They contain minute clastic quartz and white mica, and are undoubtedly hmmatitic shales, the bedding even surviving on Llanddwyn, where one of them is associated with a fine purple grit, full of broken albites, with a little tourmaline. But some are jaspery, and have a crypto-crystalline matrix, of the kind that replaces colloidal silica. Some contain oval chlorite bodies, like those in the Penrhyn slates, an analysis of which is given for comparison.
I | II | |
SiO2 | 63.93 | 63.59 |
Al2O3 | 17.55 | 16.28 |
Fe2O3 | 6.54 | 8.42 |
FeO | 0.73 | 0.66 |
MnO | — | 0.42 |
CaO | 0.60 | 0.72 |
MgO | 5.88 | 1.95 |
K2O | 2.47 | 2.98 |
Na2O | 0.34 | 2.14 |
H2O | 146 | 2.92 |
CO2 | None | None |
99.50 | 100.08 |
I. Jaspery Phyllite, 300 yards south-west of Hendre-bach, Cerrigceinwen (E10011)
II. Purple Slate, Penrhyn Quarry, Bethesda. Anal. Holland and Reade, Proc. Lpl. Geol. Soc., 1898, p. 293. SiO2 includes 0.58 TiO2.
Some red slates quoted by Clarke in Bull. U.S. Geol. Surv., 1900, have as much MgO as I., whose chlorite accounts for it. The excess of potassium over sodium is unusual in the Mona Complex, but a frequent character of red slates.
The Fydlyn Group
This group, well seen on the sea cliffs of the Fydlyn Inlier, is composed of peculiar white rocks of highly acid character, whose original structures are tolerably well preserved, in spite of the innumerable planes of schistose deformation. For the most part they seem to have been rather massive
Many of the hard cores are considerably silicified, and, as these are older than the planes of deformation, which sweep round them, they are to be referred to the volcanic episode itself, as products of geyserisation that set in towards its close.
The rocks have been powerfully deformed, and their less resistant parts have become fissile. Anamorphism, however, is low, and is restricted to the production of minute white mica. The phenocrysts are not often sheared out into phacoids.
The Coedana Granite
Four principal types can be distinguished, which may be called the Normal Granite, the Porphyritic Granite, the White Mica Granite, and the Fine Veins. The first three are often foliated, and all very frequently schistose or crushed. The normal granite has a good deal of slight local variation, but is generally rather coarse, its crystals often exceeding a quarter of an inch in diameter, and in colour may be grey or sea-green, but is usually a salmon-pink, mottled with grey and with dark green aggregates. The porphyritic is a variety of the normal rock that is full of large pink felspars. The white mica type, which is marginal, is decidedly finer than the normal, and is a clean white glistening rock. The fine types, which, when their junctions are exposed, are seen to be veins, are rare. The great intrusion of the Middle Region may be called the Coedana Granite (pronounced 'Koidánna').
The minerals of the normal granite are quartz, felspars, biotite, and white mica. Accessories are rare, but apatite, garnet, and zircon are occasionally found. The biotite (which was brown) is usually chloritised, and this chlorite is often studded with secondary ilmenite and leucoxene. The nature of the alkalies of the white micas has not been determined for any of the Coedana granites. Epidote, and rarely zoisite, also occur as alteration products, but in small quantity. The rock was rather poor in micas, brown was in excess of white, which is intergrown with it; and both micas are somewhat unevenly distributed; being found in nests with several plates close together. The dominant felspar is albite, sometimes with lamellar twinning, sometimes simple, often twinned on both planes with a microcline-like structure. But orthoclase is present as well, in varying proportions, and it may be accompanied by microcline. There are some perthitic intergrowths, and veinlets of albite penetrate the orthoclase. The structure of the rock is typically granitoid.
The porphyritic differs from the normal granite in containing conspicuous phenocrysts of pink orthoclase an inch or more in length. They are distributed rather capriciously, a few yards of rock being often closely crowded with them, while in the surrounding parts they may be scanty. From a comparison of their refractive index with that of orthoclase of known composition, it is probable that they contain about two per cent. Na2O. Some are Carlsbad twins; but they are hypidiomorphic, often only developing the pinacoidal, and sometimes no crystal faces at all. Faces, even when developed, may be invaded by any of the minerals, even by quartz, and the interior of the crystal usually encloses grains of the albite of the ground-mass. Although early, they cannot, therefore, be a first product of the consolidation unless modified by corrosion as that went on. Inclusions of the same kind are found, though on a much smaller scale, in the idiomorphic phenocrysts of Shap.<ref>Marr and Harker, Quart. Journ. Geol. Soc., 1891, p. 278.</ref> In the foliated varieties there is a tendency to parallelism in the micas and to elongation of the quartz. But the foliation is never conspicuous, and scarcely affects the arrangement of the phenocrysts in the porphyritic rock.
The white mica granite is more acid, and though containing also the same three felspars, appears to be rather richer in orthoclase than the normal granite, but is never porphyritic. It contains no biotite, but is rather rich in white mica, probably muscovite. Foliated varieties are found, in which a parallel arrangement of the micas is conspicuous.
In the fine veins pink orthoclase appears to be the dominant felspar, and white-mica, which is abundant, certainly the dominant if not the only mica. One of them contains a good deal of garnet. They are the only varieties with much micropegmatite.
All these granites are more or less affected by the latest movements of the Complex. They are sometimes crushed to mere endoclasts; are traversed by innumerable seams of greenish mylonite; are often optically strained; and frequently rendered rudely schistose. But this schistosity can easily be distinguished from the true foliation, which it may traverse at any angle, the late structure striking steadily north-east, the older in more than one direction. The old foliation is not accompanied by destruction of the minerals, and sometimes its elongated quartz elements will send out rounded tongues transversely
It is of interest to note that the Pre-Cambrian granites of Pembrokeshire are also rich in sodium.<ref>Thomas and Jones, Quart. Journ. Geol. Soc., 1912, p. 387.</ref> The Coedana rock resembles them in the dominance of albite, in the titaniferous character of its biotite, and in its poverty in accessories. It differs from them in the presence of porphyritic orthoclase, in the presence of some orthoclase, microcline, and muscovite in its ground mass, and in the rarity of perthitic and pegmatitic structures. It is also nearly related to the granites of Eastern Sutherland<ref>Horne and Greenly, Quart. Journ. Geol. Soc., 1896.</ref>, a relation partially disguised by the injuries inflicted by the last movements of the Complex. It differs from these somewhat in composition, for they contain more biotite, no muscovite, and their dominant felspar is oligoclase. Structurally its resemblance to their less foliated portions is much greater, especially as they contain red phenocrysts of natron orthoclase which are but hypidiomorphic and enclose many grains of the oligoclase of the ground mass. The affinities of the Coedana granite to some great Pre-Cambrian and Metamorphic granites are therefore close. Its relations to the granitoid parts of the adjacent gneisses will be discussed later on.
Hornfels
The rocks grouped under this name are all found in association with the Coedana granite. Some of them are highly crystalline, and can only be termed hornfels in accordance with the extended use of the word that has been made in recent years. The compact varieties (which predominate) may be termed Crypto-crystalline, the others Phanero-crystalline, or briefly Crystalline Hornfels.
The crypto-crystalline Hornfels
These are compact grey-green rocks with a rudely conchoidal fracture, seldom, but sometimes harder than steel, and weathering to a light cream colour. But this material, though a large proportion of the whole, usually occurs in rather slender, curving, lenticular cores, between which a decided though never strong schistosity appears, the rock remaining otherwise much the same. Sometimes a strong parallel banding that cannot be anything but bedding can be traced for a few yards, and on the moor north-west of Gwalchmai it is thoroughly stratified over a considerable area. Spotted hornfels also occurs.
The essential minerals are quartz, alkali felspar, a green mineral most of which is now chlorite, magnetite, and white and brown mica. What proportion of the colourless mosaic is felspar is difficult to determine on account of the fineness of the grain, but it must often be considerable. Some of the felspar, which is very seldom twinned, is albite, but some is negative and must be an orthoclase. The white micas are very small. Sometimes the iron ore is larger than usual, and is then seen to be octahedral, and being strongly magnetic, must be magnetite. Idiomorphic tourmaline of bluish-brown tint in small prisms is almost always present as an important accessory. Pseudomorphs after andalusite have been found at Bodafon Moor. Minute granules of sphene are often plentiful, and also leucoxenised ilmenite, from which doubtless the sphene has been derived. The spots are complex encarsioblasts of a green mineral in which, though much chloritised, portions that are still a xanthophyllite<ref>For the characters of this mineral, where better preserved, see p. 113.</ref> can be identified, though not so well preserved as in the graphite-schist. The banded varieties have the same composition as the rest.
The texture is finely granoblastic
The Crystalline Hornfels
Three principal kinds are known, Mica-Hornfels, Hornblende-Hornfels, and Epidote-Hornfels. All are holocrystalline and granoblastic.
Mica-Hornfels
The mica-hornfels is a saccharoid sea-green rock spangled with bright micas that lie in all directions. Often it has a parallel structure that is not a foliation, and it is interbedded with white fine siliceous bands in a way that is unmistakably stratification. The essential minerals are quartz, alkali felspar, white mica, brown mica now much chloritised, and iron-ores, tourmaline also rising in some beds to the rank of an essential. Cordierite has not been found. Apatite and sphene occur occasionally. Besides the white micas of the body, there are abundant white mica porphyroblasts which when in crystal units are often one millimetre and when compound often two to three millimetres in diameter.
Hornblende-Hornfels
This, which is found as a zone in mica-hornfels, is a dark green but light-weathering rock of medium grain, saccharoid, and with a fine, steady, parallel banding that is manifestly bedding. It is homoeoblastic, and composed of alkali-felspar, hornblende, and quartz, with minute epidote, zoisite, iron-ores, and sphene. In the colourless mosaic felspar predominates over quartz. It is untwinned, the refractive index unusually low as a whole, and as some is negative, some positive, it is evidently orthoclase with a large quantity of albite. The hornblende is of a good clear tint, and pleochroic, thus: X, pale straw-colour, Y, rather strong brownish-green, Z, grass-green. It is hypidiomorphic, and in one coarse band
Epidote-Hornfels
The epidote-hornfels is a finely saccharoid, pistacio-green rock, sometimes with an even banding and well-bedded siliceous seams, but sometimes rather massive. It is a homoeoblastic mosaic
Unity of the Hornfels
The crypto-crystalline hornfels, though not observed to pass into typical mica-hornfels with large porphyroblasts of muscovite, becomes here and there so much less compact, with such much larger micas, as to constitute an intermediate type; and another intermediate type is a fine but saccharoid hornfels with alkali felspar and a little white and brown mica that is developed on rather a large scale on Gwalchmai Moor. The persistent presence of tourmaline also links the types. Epidotic bands link the crypto-crystalline with the true epidote-hornfels. The epidote-hornfels at Cwm rests upon a bedded mica-hornfels and is seen to graduate into this in clear section; while hornblende- and mica-hornfels come into similar relations in the section near Coedana. All the types are therefore linked up together, and must be regarded as varieties of one and the same product.
Chemical analyses
The following are analyses of different types of hornfels
I | II | III | IV | V | VI | VI | VIII | IX | X | |
SiO2 | 74.02 | 58.40 | 60.08 | 58.87 | — | 62.91 | 60.36 | 55.58 | 74.02 | 55.58 |
TiO2 | not det. | not det | not det | not det. | — | 0.53 | none | not det. | — | — |
Al2O3 | 1213 | 23.42 | 17.93 | 18.74 | — | 16.52 | 16.81 | 13.96 | 23.42 | 12.13 |
Fe2O3 | 0.89 | 3.10 | 6.46 | 6.54 | — | 4.39 | 112 | 4.76 | 6.54 | 0.89 |
FeO | 3.62 | 2.26 | 1.88 | 3.43 | — | 4.47 | 4.85 | 2.20 | 4.85 | 1.88 |
CaO | 1.10 | 011 | 3.89 | 1.23 | — | 1.41 | 5.13 | 9.73 | 9.73 | 0.11 |
MgO | 1.95 | 1.52 | 2.27 | 2.07 | — | 2.41 | 2.77 | 4.88 | 4.88 | 1.52 |
K2O | 1.89 | 6.59 | 7.21 | 8.97 | 4.04 | 2.57 | 3.69 | 6.97 | 6.97 | 1.89 |
Na2O | 3.19 | 0.29 | 1.57 | 2.99 | 3.76 | 0.20 | 3.76 | 0.20 | ||
H2O(at 110°) | none | 0.46 | — | — | — | 0.31 | 0.15 | — | 0.46 | 0.15 |
H2O | — | — | 0.17 | 0.31 | — | — | — | — | — | — |
H2O (above 110°) | 1.54 | 3.53 | — | 1.83 | 0.99 | 1.09 | 3.53 | 0.99 | ||
CO2 | none | none | none | 0.42 | — | 0.19 | none | 0.63 | 0.63 | — |
100.33 | 99.68 | 99.89 | 100.58 | — | 100.53 | 99.63 | 100.00 | — | — |
I. Banded crypto-crystalline hornfels (E10188)
II Bedded crypto-crystalline. hornfels (E10345)
III Crypto-crystalline hornfeis, 200 yards north of Ynys-fawr, Coedana (E10003)
IV Spotted xanthophyllite-hornfels (E9888)
V Banded crypto-crystalline hornfels (E9972)
VI Crystalline mica-hornfels (E9806)
VII Crystalline hornblende-hornfels (E10002)
VIII Crystalline epidote-hornfels (E9949)
IX Maximum percentages of the constituents in I–VIII.
X Minimum percentages of the same.
It will be seen at once that there is a great variety of composition, affecting every element estimated, even the aluminium; and the range of the variations can be gauged at a glance from columns IX and X. The combined alkalies range from 5.08 to 8.97. A number of different rocks must, therefore, have been converted into hornfels. It will also be noted that a mean of the separated alkalies in I, II, V, VI, VII, VIII, yields K2O = 4.29, Na2O = 2.00, and that in II and VIII potassium is almost the only alkali, a reversal of the proportions usual in the Mona Complex. From this it follows that orthoclase must be the dominant felspar of the fine mosaic, and that the minute white mica must be muscovite.
Origin of the Hornfels
1. Original Structures — are found at several places. A parallel interbanding of different kinds of material, often of coarser and finer material, is frequently to be seen both in the crypto-crystalline and crystalline varieties, which resembles in every way a true sedimentary stratification, and at a place 275 yards south-south-east of the tenth milestone at Gwalchmai thin bands of quartzite lie along this. A purple phyllite occurs within the zone 190 yards east of this quartzite. The crystalline types are completely reconstructed, but a banded crypto-crystalline hornfels a few yards from the rock of analysis No. I contains numerous undoubted clastic grains of quartz and albite (E11190)
2. Chemical Composition — From the remarkable range of composition shown in the analyses it is evident that rocks of very different character and origin have, in this zone, been converted into hornfels. One or two have the composition of acid and basic igneous rocks, another (No. II) that of a sediment, others of neither normal igneous rocks nor normal sediments. Taken singly, No. I might be supposed to have been a rhyolite, No. VII a diorite. Yet No. I has a stratified structure and contains clastic grains, No. 7 is also stratified and is a band in mica-hornfels that resembles No. VI, which is totally unlike either a diorite or any ordinary igneous rock, but resembles many sediments in composition. Nos. I, III, IV, V, again, have close community of structure with No. II, which is undoubtedly a sediment; while No. VII is related structurally to No. VIII, which cannot possibly be dioritic. Yet none of them, not even No. II, can be normal sedimentary rocks, and No. VIII, with its 9.73 per cent. of CaO and its 6.97 per cent. of K2O, is abnormal altogether. The outstanding feature of the zone, in short, is community of structure with diversity of composition. The structure which they have in common. is not of a kind that is known to result from the alteration of igneous rocks, but is well-known to result from the alteration of sedimentary rocks, and these undoubtedly exist within the zone; yet the composition of the majority of them is not that of any known sediments. Now there is one class of deposits, and one only, in which such a range of composition is at all probable, combined with a community of original structure capable of giving rise to a community of alteration structure. That is an alternating group of bedded tuffs with psammitic and pelitic sediments into which have been showered varying proportions of pyroclastic dust; and such deposits are known to exist within the Mona Complex, which contains both spilitic and rhyolitic tuffs (pp. 57, 75, 90). The hornfels, moreover, passes laterally into the Penmynydd Zone of metamorphism, which, as will be seen, must include rocks of both sedimentary and pyroclastic origin. The crypto-crystalline hornfels with clastic quartz may therefore be regarded as composed of gritty shales with rhyolitic and other dust, the mica-hornfels may be produced from similar material, the hornblende-hornfels would be a basic, and the epidote-hornfels a calcareous tuff. Much of the crypto-crystalline hornfels has in the field a strong resemblance to the Church Bay Tuffs, in which, moreover, we find precisely the same rare, local, and pronounced but impersistent bedding.
3. Causes of the alteration — Among the many metamorphic types of the Mona Complex the rocks here called hornfels are unique in that they are found in one association only. The distribution of the rest is regional; the hornfels, of whatever type, clings to the Coedana granite. The crypto-crystalline hornfels is for the most part external; behaving, indeed (though small xenoliths are found), as an aureole along the flanks of the granitic tract: the crystalline hornfels is only found in the great xenoliths (one of which is a mile in length) of its interior, where the temperature would be higher and maintained for a longer time. In the crypto-crystalline hornfels granite apophyses are rather rare, but the crystalline xenoliths are riddled by innumerable sills and veins, and no chilled selvages are known.
The textures and composition of the hornfels itself are fully in harmony with its dependence on the granite. The flinty fracture, the spotting, the frequent absence of parallelism in the micas, the presence of large porphyroblasts whose position is independent of the direction of the banding, and of large ragged encarsioblasts full of small inclusions, are all characters of thermal as distinct from dynamic metamorphism. Tourmaline (which is found also in the granite at the margin), andalusite, and the chloritoids are all contact minerals, both micas are well known in that connexion, and the hornfels of Gwalchmai Moor has the structure of an adinole. The epidote rock with its pale hornblende is an impure calc-silicate-hornfels.<ref>The preponderance of potassium over sodium, so exceptional in the Complex, is also curious, and suggests that some of the potassium of the Coedana granite (the only great orthoclase rock of the Complex) has found its way out into the aureole.</ref>There can be no doubt, therefore, that the special characters which distinguish these rocks from the rest of the Mona Complex are due to the thermal influence of the granite.
Foliated Hornfels
Their frequent lack of any foliation being a matter of importance in these rocks, attention has been focussed on it. Yet the fissile-parts of the crypto-crystalline varieties are finely foliated. What is the relation of this foliation to the thermo-metamorphism? Now, tourmaline prisms are found in many slides of the foliated parts, but they never show the slightest deformation, and in some cases (E10346)
Diorites
Rocks of this type are (except in the Gneisses, whose basic members are described under the heading of that formation) both small and few, and are all either within the Penmynydd Zone or the Coedana granite. The small cores of albite-diorite that are found in some of the hornblende-schists are described on p. 115. The diorite of Llangaffo cutting is coarse, but slightly foliated even in the centre, while its margins pass into hornblende-schist. It contains greenish bodies that look like pseudomorphs after deformed porphyritic felspars, but none of the slides contain sections of them. On the Aberffraw coast at Ynysoedd Duon are some singular amphibolites, grey-green, tolerably coarse, and quite unfoliated in the middle. They are composed of large ragged plates of pale hornblende with pleochroism: X, colourless; Y, pale brown; Z, very pale blue-green, in a matrix of zoisite and albite. The albite is granular, the zoisite chiefly granular but sometimes eumorphic. This matrix is penetrated in all directions by good-sized plates of a white mica, chiefly grouped in aggregates that are sometimes rudely rectangular, as if pseudomorphs after a porphyritic felspar. Epidote and calcite are also present, and plates of hmmatite are intergrown with those of mica. On its margins this rock, which may be called a mica-zoisite-amphibolite, acquires a foliation, in which, however, the micas hardly participate. In an undeformed specimen (E10175)
Dioritic rocks with amphibole that must be original are found at a few places within the Coedana granite, especially at Tre-ddolphin and by the side of the Holyhead main road near Treban, but the nature of some of these suggests that they may be xenoliths of the basic gneisses. Four small diorites of much more unequivocal character occur within the granite at the curve of the Caradog river near Y Werthyr. As they seem to graduate into hornblende-granite, and adjoin mica-hornfels, they may safely -be regarded as basic portions of the Coedana granite magma. But they need further investigation.
The Serpentine-Suite
On either side of the winding Strait of Holy Isle (as the channel isolating that island may conveniently be called), a number of plutonic rocks have been intruded into the New Harbour Beds. All are basic, but several types are present,<ref>A most of the slides and specimens of these rocks were kindly examined by Dr. Flett.</ref> and each of the larger masses is of the nature of an igneous complex. Isolated bodies of the same kind are found also about the mouth of the River Alaw, and among the Amlwch Beds of the north. The intrusions are composed chiefly of serpentine and gabbro, the serpentine being somewhat in excess. Coarse pyroxenites are present, and certain dolerites of the north 'appear to belong to the same suite of intrusions. Associated with them are a number of interesting metamorphic products, including talc-schist, tremolite-schist, tremolite-marble, ophicalcite, chlorite-chromite-magnetite-schist, andalusite-hornfels, epidote-hornfels, and epidosite, all of which owe either their existence or their condition to the basic intrusions.
Serpentine
Nearly all the serpentine is dark green, red varieties being rare. It is usually granular, with a clean, subtranslucent aspect. Locally it is mottled with a lighter green variety, and has then the appearance of noble serpentine'. In perhaps the greater part of the rock the only visible crystals that interrupt the general uniformity are iron-ores, but varieties containing plates of a fissile pyroxene are common. Sometimes there is a rude banding.
The granular body is a serpentine with the mesh-work structure denoting derivation from olivine. The opaque iron-ores are, when tested, found to be magnetite; but brown spinellids (chromite or picotite) are frequent. Both minerals have a tendency to cluster. The pyroxene was largely enstatite, but diallage is also present. These pyroxenes are generally scattered about in the serpentinous body, but sometimes grains of olivine-serpentine are poikilitically enclosed in them. Their plates are often large, attaining a diameter of five inches at Rhyd-bont creek, so that the original peridotites must have been coarse, and were evidently deep-seated intrusions.
The homogeneous granular material is a true dunite-serpentine; thence, by the coming in of enstatite, it passes into a saxonite-serpentine; again, where diallage is also present, it becomes a lherzolite-serpentine; while some varieties may be regarded as chromite-serpentine. But it would not be easy to lay down lines for these types upon a map.
The following analysis (No. I) was published by Prof. Bonney in 1881:
I | II | III | |
SiO2 | 38.62 | 40.12 | 39.58 |
TiO2 | not est. | tr. | 0.10 |
Al2O3 | 4.15 | 0.98 | 3.19 |
Fe2O3 | 5.21 | 6.52 | 4.70 |
Cr2O3 | not est. | 0.28 | 0.20 |
V2O3 | not est. | tr. | not fd. |
FeO | 4.34 | 1.21 | 2.76 |
MnO | tr. | 0.52 | 0.34 |
(CoNi)O | not est. | 0.15 | 0.16 |
BaO | not est. | not fd. | not fd. |
CaO | tr. | 0.12 | 1.09 |
MgO | 33.83 | 35.78 | 36.21 |
K2O | 0.70 | 0.08 | 0.06 |
Na2O | 0.24 | 0.28 | |
Li2O | not fd. | tr. | |
H2O at 105° | 12.52 | 1.69 | 0.51 |
H2O above 105° | 12.17 | 10.79 | |
P2O5 | not est. | 0.10 | 0.16 |
FeS2 | not est. | 0.01 | not fd. |
CO2 | — | 0.15 | 0.24 |
99.37 | 100.12 | 100.37 |
(Two serpentines from the 'Geology of the Lizard and Meneage' are given also.)
I Serpentine, from close to the 't' of 'Pen-y-bont', Valley. Anal. F. T. S. Houghton.
II Dunite-serpentine (E5172), 70 yards west of Parc Bean Cove, south side Predannack, Lizard. Anal. E. G. Radley.
III Bastite (lherzolite)-serpentine (E5031)
The rock seems to have been a dunite-serpentine with a little enstatite, but contains much more aluminium than the dunite-serpentine of the Lizard. Comparison, however, must not be made too closely between analyses differing in date by 30 years.
Serpentinisation
The peridotites are highly serpentinised, fresh olivine being not yet recorded, while the fissile pyroxenes are for the most part converted into bastite. The serpentine is partly fibrous, partly in well-formed crystalline elements with varying birefringence, and some of it is nearly isotropic. Tremolite has also grown upon the plates of diallage and bastite, and sometimes the serpentine has been to a great extent replaced by carbonates.
A quasi-spherulitic variety, which has been found at several places, is also due to alteration. In this case a compact serpentine is full of pale green spherulitic bodies ranging from one-eighth to one-third of an inch in diameter, so as to simulate a variolitic spilite. The bodies tend to crowd into groups, or even into confused aggregates, which often take the form of rows like those of a spherulitic obsidian. They tend to weather out, but also weather hollow. The matrix is usually an olivine-serpentine with rather irregular mesh-work. Many of the bodies are not spherical, but sub-angular, or even rudely rhombic. They are composed of a mineral that resembles actinolite in short needles, intergrown in varying proportions with a carbonate, sometimes almost entirely of the carbonate. Concentric structure is rare, and radial arrangement, though common, is usually confined to the marginal portions, the interior being matted, with an approach to an interlacing of the needles at angles of about 55°. These bodies are therefore products of a late stage of alteration, when the serpentine wasbeing replaced by carbonates. Signs of cleavage are perceptible in some, and as the effects of malachite staining show (Prof. Bonney and Miss Raisin remark) that these cannot have been olivine, they would seem to be pseudomorphs of enstatite. Elsewhere, however, the mesh-work of olivine, still traceable by winding trains of iron-ores, may be seen to pass through the body of a spherulite. The rocks may therefore be regarded as lherzolite- or saxonite-serpentines in which the pyroxene, and portions of the olivine, have been replaced by ternary quasi-spherulitic structures that are later than most of the serpentinisation.
At Mynachdy is a serpentine rich in minute garnets, in clusters and veinlets, together with stars of antigorite. Bundles of asbestos, also, several inches long, are still to be found in it. The refractive index is 1.4 and the extinction parallel. They are therefore chrysotile.
Pyroxenites
Though important links in the plutonic sequence, and composed of large and beautiful crystals, these rocks are of small bulk, being found but rarely, and in aggregates or veins that cannot be traced for more than a few yards in any direction. The diallage-rock is almost wholly composed of that mineral in lustrous plates that attain an inch and a half in diameter, with poikilitically intergrown pseudomorphs after enstatite and olivine. The enstatite-rock may be nearly pure, containing, besides a little augite, only a few grains of a mineral that seems to be perofskite. The enstatite is bounded by the faces 010 and 110, and may be half an inch in length. Its smaller plates, broken across the cleavage, simulate a green matrix on fresh fractures. Websterites are also found, which were composed of diallage and enstatite with little or no olivine, while others contain a good deal of serpentine. Mineralogically, therefore, transitions can be found from all the types of pyroxenite into the peridotites. The enstatite of these pyroxenites is usually bastitised; their diallage is often fresh, but sometimes replaced by chlorite or carbonates; and both pyroxenes are locally amphibolised.
Gabbros
Enstatite-gabbro — A vein is known that consists of augite, kaolinised felspar, serpentine after enstatite, and granules doubtfully ascribed to garnet and perofskite. This rock therefore links the pyroxenites to the true gabbros. The gabbro proper is a pale green rock with a rather confused aspect on fresh fracture, though diallage and saussurite can always be made out on examination. Usually it is not coarse, the diallage being from one-eighth to a quarter of an inch across, but the texture may vary even in a hand-specimen. Large plates of diallage are quite rare, but some have been found an inch and a quarter across. Even where least modified, pale amphibole has been developed in and around the diallage in fringing acicular growths and compact plates. There seems no trace of enstatite or olivine. The saussurite of the matrix is composed of granular epidote and small irregular plates of untwinned felspar optically positive and probably albite. Some, however, is fine or even crypto-crystalline. A gabbro that is unusually massive has been analysed. Its differences from those of the Lizard and Skye, both of which contain olivine, are considerable.
I | II | III | |
SiO2 | 47.02 | 50.69 | 47.28 |
Al2O3 | 15.85 | 20.98 | 2139 |
Fe2O3 | 0.94 | 1.65 | 3.52 |
FeO | 3.96 | 3.26 | 4.06 |
CaO | 11.42 | 11.99 | 13.42 |
MgO | 13.99 | 6.84 | 8.06 |
K2O | 0.20 | nf. | 0.29 |
Na2O | 1.91 | 3.36 | 1.52 |
H2O (at 110°) | 0.18 | 0.18 | 0.13 |
H2O (above 110°) | 4.49 | 0.94 | 0.53 |
99.96 | 99.89 | 100.20 |
I. Gabbro, 'hyphen' of 'Pwll-pillo', at the foot of a high boss, by the lane-leading to Cerig-moelion (six-inch map) (E10213)
II. Olivine-gabbro, Coverack, Lizard. Anal. E. G. Radley. 'Geology of the Lizard and Meneage', p. 100 (0.16 of P2O3 and FeS2 omitted).
III. Olivine-gabbro, Cuillin, Skye. Anal. W. Pollard. 'Tertiary Igneous Rocks of Skye', p. 103.
Dolerites
Those that have been investigated are now deeply amphibolised, but contain cores of brown augite and are ophitic. Their felspar is labradorite. They have chilled selvages and are thus less deep-seated than the gabbros, but are (p. 321) certainly apophyses from an unseen and doubtless gabbroid intrusion.
Mutual relations
Between the several members of the suite, neither chilled selvages nor clear intrusive junctions of any kind are known. ' But pyroxenite and enstatite-gabbro certainly vein serpentine, and are never known to vein gabbro. The distribution of the gabbro itself, as shown upon the maps, particularly its ring-dykes
Associated metamorphic rocks
Talc-Schist — This is grey, platy, rather fine, usually well foliated, and very unctuous to the touch. It consists often almost entirely of talc, with a few scales of chlorite and octahedra of magnetite. Bright scales with a strong basal cleavage are present in some varieties (AP. 281). They show a uniaxial cross, or a bisectrix with a very small and variable axial angle, and are optically positive. The refractive index is very close to 1.570. They are therefore brucite. The composition of the typical rock should be compared with those of theoretical talc, of peridotites, and of the tremolite-schist, to the latter of which it is evidently related, aluminium, however, taking the place of calcium.
Tremolite-Schist — Some of these rocks are white, others have a very pale tinge of green. The finer ones are perfectly foliated and even fissile, with a silky lustre; but the prisms of colourless amphibole are often large enough to be seen easily with the hand-lens. They are composed
I | II | III | |
SiO2 | 56.34 | 63.49 | 53.65 |
TiO2 | — | — | 0.06 |
Al2O3 | 8.21 | — | 3.24 |
Fe2O3 | 3.04 | — | 3.48 |
FeO | 2.00 | — | 3.88 |
MnO | traces | — | 013 |
CaO | 0.52 | — | 9.23 |
MgO | 25.43 | 31.75 | 24.51 |
K2O | — | — | none |
Na2O | 0.79 | — | 0.51 |
H2O (at 110°) | — | — | 0.03 |
H2O (above 110°) | 2.86 | 4.76 | 1.36 |
99.19 | 100.00 | 100.08 |
I. Talc-schist (E10168)
II. Theoretical talc, Mg2H2Si4O12, given by Dana.
III. Tremolite-schist (E10226)
Tremolite-Limestone and Ophicalcite — These peculiar crystalline limestones fall into two groups according to the nature of the dominant silicate. A beautiful gneissose marble (E10563)
From the tremolite-limestones there is a gradual transition to the ophicalcites. To convey a clear general picture of these rocks is not easy. They are composed of saccharoidal carbonate intergrown in various ways with clear green serpentine. The carbonate may be white or with a tinge of green from flecks of serpentine. Generally more or less schistose, they are often banded, but very frequent is a brecciated structure, fragments of serpentine being embedded in the crystalline carbonate, and rapid passages are common from one structure to another. The beautiful ophicalcite of the old marble quarry at the 'w' of 'Pwll-pillo' (Cerig-moelion lane of six-inch map) consists of snow-white granoblastic calcite with scales and films of serpentine, an abundance of tremolite needles, talcose scales, iron-ores, and a spinel, probably chromite. About Llanfwrog there are talc-marbles, composed of talc with varying proportions of a white carbonate, sometimes calcite, sometimes dolomite or perhaps magnesite, and some chromite and magnetite. The ophicalcites are therefore serpentine-limestones, generally containing tremolite and talc, and thus connected by gradations with the tremolite-limestones, which in their turn are specially calcareous parts of the tremolite-schists.
The following analyses will enable the types to be compared, but it must be understood that the proportion of silicates varies greatly in both groups. Mr. J. O. Hughes writes: 'The effect of using hot HCl (20 per cent.) was a decrease of 8 to 12 per cent. in the insoluble residues, and increases of some 2 per cent. of MgO and 4 per cent. of Al2O3 + Fe2O3 in the solution obtained, the percentage of CO2 being unaffected. Nos. I and IV were decomposed by hot hydrochloric, Nos. II and III by acetic acid. No Mn was found in the solutions'.
I | II | III | IV | |
Insoluble residues | 5.29 | 34.45 | 28.17 | 15.01 |
Al2O3+Fe2O3 | 6.60 | 0.43 | 0.13 | 4.27 |
CaO | 32.68 | 26.85 | 38.96 | 27.55 |
MgO | 14.49 | 7.52 | 0.49 | 14.83 |
CO2 | 41.26 | 29.42 | 31.10 | 38.11 |
H2O | — | 1.15 | 1.11 | — |
100.22 | 99.82 | 99.95 | 99.77 | |
Percentage CaCO3 | 58.35 | 47.94 | 69.62 | 49.20 |
Percentage MgCO3 | 30.27 | 15.71 | — | 31.14 |
I. Dark hard limestone (E10217)
II. Tremolite-marble with radial structure (E10563)
III. Ophicalcite .(E10214)
IV. Reddish limestone. A few yards west of the house at Tyddyn-dai, Amlwch. Anal. J. O. Hughes.
That these ophicalcites are metasomatic products of the serpentines is hardly to be doubted. One of them (E10388)
Chlorite-chromite-magnetite-schist — At several places a peculiar basic rock appears, which is never more than a few feet, usually only a few inches, thick. Sometimes well foliated, sometimes rather massive, it is dark green, soft, and studded with black octahedra which attain a diameter of nearly a quarter of an inch. The green matrix is a felt of chlorite with some granules of epidote and iron-ore. The nature of the chlorite has been discussed by Prof. Bonney<ref>Geol. Mag. 1890, pp. 539.</ref>, and he writes me that he has now no doubt that the mineral is one of the chlorites. The large octahedra were ground out of his slide and so left undetermined. If, however, they be tested by an ordinary magnet, they rise briskly on edge, but do not leap to it as would magnetite. If a fragment from a single crystal be finely crushed, the dust is found to be partly opaque, partly translucent with the deep colour of chromite. It is therefore probable that the crystals are isomorphous intergrowths of magnetite and chromite. The following analysis was published by Prof. Bonney in his paper of 1881. It is, however, of the green matrix only, the octahedra having been removed. The rock must therefore be even more basic than this analysis, and must contain a high percentage of iron with a considerable amount of chromium. It does not correspond in composition to any other known rock in Anglesey, and is doubtless a secondary product.
SiO2 | 28.56 |
Al2O3 | 39.54 |
Fe2O3 | 0.99 |
FeO | 2.87 |
Cr2O3 | traces |
MnO | traces |
CaO | 1.73 |
MgO | 15.79 |
Alkalies | 0.70 |
Water | 11.09 |
101.27 |
Chlorite-chromite-magnetite-schist, adjoining talc-schist (pp. 104, 277). Quarry 250 yards north of Bronddel (south-west of Plâs-coch, six-inch map). Anal. F. T. S. Houghton.
Deformation and metamorphism
These intrusions have been considerably affected by the dynamical metamorphism of the Mona Complex. It is probably safe to say that the greater part of the serpentine is undeformed, but such a statement, unqualified, would convey a_most misleading picture. For it is so riddled with planes of gliding that the lenticular cores of massive rock are seldom as much as a few yards in length, and usually a foot or a few inches only. Round them sweep schistose films, generally light yellow, slickensided, shiny, slippery, and unctuous to the touch. So strong is the tendency of the rock to part along these planes that hardly any others are presented on the faces of exposures, and it is often rather difficult to obtain specimens with good cross fracture. Sometimes the serpentine is thoroughly schistose for a width of 30 or 40 yards, though anamorphism is limited to the production of antigorite. It would seem as if the ease with which serpentine gives way along planes of molar movement is a substitute for the molecular movement that results in a truly anamorphic schist; and it thus appears that the serpentinisa-tion of the peridotite preceded its deformation.
In the gabbro, massive cores are far larger, often 80 yards or so in length, and from these its great steep-sided bosses have been shaped. Yet a rude parallel structure is often to be seen, and at a few places it passes into a perfect, fissile, gabbro-schist
The associated metamorphic rocks are all true crystalline schists, and in the tremolite-schists and tremolite-marble anamorphism has been carried very far. In the ophicalcites, the relations oft the silicates to the carbonate-mosaic are those which are usual in the crystalline limestones of regional metamorphism. What local conditions determined the production of such rocks, instead of merely schistose serpentine, from the peridotites, is not yet known.
Speaking generally, there can be no doubt that these intrusions, and their products, have been far more than merely deformed; they have been affected in a considerable degree by the anamorphism that has produced the foliation of the Mona Complex.
Marginal rocks
Andalusite-mica-hornfels — A wide halo of induration that surrounds the dolerites of the north is described on pp. 320–1. Its more crystalline parts are chiefly composed of criss-cross' white and brown mica, in which are porphyroblastic pseudoinorphs, now chiefly composed of white mica, but sometimes idiomorphic, zonal, and with outlines as of andalusite.
Epidote-hornfels and Epidosite — Skirting the margins of the intrusions of the Strait of Holy Isle are interrupted borders of peculiar altered rocks. Though possessing certain characters in common, such as the general presence of epidote and absence of a fissile structure, they fall into two natural-groups.
Those here termed 'hornfels' are compact, with a conchoidal fracture. In colour they range from a grey green like that of the New Harbour Beds to a pistacio green due to disseminated epidote. They are composed of quartz (often crypto-crystalline), chlorite, epidote, a little pale hornblende, and albite. That they are of sedimentary origin there is no doubt. They have a fine even banding, and some of the quartz retains an clastic aspect. This bedding is folded sharply and the folds are cut by shear lines. Along the southern shore of Rhyd-bont Creek one of them is clearly seen to be a modification of the New Harbour Beds, and at the creek-head it is full of needles of actinolite that lie in all directions and penetrate all the structures. Those here called 'epidosite ' are developed on a much greater scale. Along the southern margin of the large intrusion of Holy Isle, a zone of them a quarter of a mile wide extends for more than a mile. They are of medium grain, but rapidly variable, so as to weather lumpily and ruggedly. Weathered surfaces look well-foliated, but on fracture the fissility is found to be almost obliterated, and they are extremely tough under the hammer. In places they retain a grey-green tint like that of the Green-mica-schists, with granular and fissile bands as at Holyhead, the quartz being sometimes also 'rodded'; but these types pass rapidly into pistacio-tinted epidote-granulite in which all fissility has disappeared. The minerals of this are quartz, epidote, chlorite, and amphiboles, with some albite and carbonates. The epidote occurs both in granules, rods, and large glandular aggregates; it is partly colourless, but chiefly coloured and strongly pleochroic. The amphibole is for the most part very pale, and finely matted. The rudely lenticular seams of quartz, which contain albite and a little carbonate, are often yellow with rows of epidote granules, which occur also freely in the seams of chlorite. The quartz of some is full of slender hairs of amphibole. Many specimens (E9755)
In the heart of the zone the rocks are highly reconstructed; but on the craggy platform above the talc-schist north of Bronddel, and by the ruin 433 yards north-west of Bodior Lane, schist with the same epidote and amphibole, contain undoubted clastic quartz; and at the '36' level, bedded jaspers are found within the zone, with their quartz seams epidotised. These epidosites must therefore be regarded as a special state of alteration of the New Harbour Beds, whose pyroclastic element probably accounts for the amphibole and epidote.
It must be admitted that the zone contains none of the minerals usually regarded as thermo-metamorphic. Yet epidosites resembling these have been found in a thermal aureole at Old Lizard Head<ref>'Geology of the Lizard and Meneage' ' p. 36.</ref>, and the destruction or prevention of fissility as well as the mode of occurrence of the actinolite points to contact alteration. The epido-site zones undoubtedly behave as an aureole to the basic intrusions, and may with confidence be looked upon as their thermal product.
Chronology — It is evident that when this thermal influence was exerted the foliation of the New Harbour Beds was imperfectly developed, though it had been initiated, and the same is the case with the epidote-hornfels, as well as with the andalusite-mica-hornfels of the north. We have seen that the serpentines and gabbros became in their turn deformed and foliated. Their intrusion must therefore have taken place during an interval, or intervals<ref>This is confirmed (see pp. 208, 211, 321) by their field-relations</ref>, of the great movements of the Mona Complex.
The Penmynydd zone of metamorphism
The Penmynydd Schists, named after a village in the midst of their principal district, are to be regarded not as a stratigraphical but as a metamorphic horizon. Several, possibly all of them, indeed, can be identified elsewhere in a less altered state. But whatever their origin, the rocks of the zone, in the condition in which they are found in it, are marked and important metamorphic types, and as such they will be considered in this section. All of them are holocrystalline schists, and next to the Gneisses are the most highly reconstructed rocks in the Island. They are:
Mica-schists
Quartz-schists
Limestones
Graphite-schists
Rutiliferous-schists
Hornblende-schists
Glaucophane-schists
Banded Marginal Rocks
The Mica-schists
The Mica-schists are by far the most extensive, being, indeed, a foliated 'country' in which lenticular masses of all the others float. Two leading types may be recognised: a flaggy or evenly foliated, and a flaser or lenticularly foliated. Intermediate types connect them, and there are sub-types of each too numerous for description here.
The flaggy type tends to be rather fine, its mica, though well and sharply formed, being usually small, though there are exceptions to this. On the whole, its aspect recalls the rocks that are found immediately above the mylonites of the Moine thrust-plane in Scotland. The essential minerals are quartz, felspar, white and brown mica, and iron-ores, accessories being unimputant. The brown mica is often chloritised, but when fresh has a moderate pleochroism. The felspar is an alkali variety, usually untwinned, but where determined is a sodium species. The flaser or lenticular type, which is more extensively developed than the flaggy, is more highly crystalline and with a greater variety of minerals. Instead of being even, it is wavy on the foliation-planes, an appearance due to its being built up of overlapping lenticular seams, one-eighth to a quarter of an inch in thickness, of saccharoid granular matter, about which bend the fissile folia. The rock is very clean and fresh, and the foliation-surfaces brilliant, with a tinge of pale sea-green upon them. The flaser structure is further emphasised by conspicuous augen and twisted lenticular sheets of white venous quartz
The essential minerals are quartz, felspar and white mica. Epidote often rises to the rank of an essential. An abundance of accessories is a feature of the type. They are epidote, zoisite, garnet, sphene, zircon, apatite, rutile, haematite, biotite, chlorite, and opaque iron-ores. The felspar is albite, with an occasional grain of microcline, and this being the case, it results from the analyses (p. 112) that the white mica must be muscovite. The albite is generally clear (save for inclusions in the larger grains) and often untwinned. The muscovite is well formed, in flakes that may exceed one millimetre in diameter. The epidote is largely in yellow pleochroic prisms, with usually high but often variable birefringence, and some give the polarisation hues of zoisite. The garnets are usually small, and sometimes idiomorphic. Small flakes of blood-red haematite are a feature of the schists. Tourmaline is very rare. Some slides are so crowded with minute accessories of high refractive index that it is not easy to say what are the proportions among them of the several minerals. Delessite in radiating groups fills small fissures. The structure is granoblastic, with lepidoblastic seams. But some of the rocks
Undulose extinction is rare in the Penmynydd Zone. The quartz of the white venous augen is in some cases coarsely granoblastic like ordinary vein quartz, in others nemablastic, and then usually contains a few large plates of muscovite. Many of them have milky bands of minute cavities. No felspar has been found in these white ones. There are, however, augen composed of coarsely crystallised pink potassium-felspar with a varying proportion of quartz. The felspar was kindly determined, some years ago, by Dr. Teall, using Szabo's method.
Quartz is therefore found in these rocks in three conditions: (1) that of the granoblastic body, (2) that of certain finely granoblastic pinkish, twisted, augen, (3) that of the stout venous augen
The following analyses have been made of typical Penmynydd mica-schists. One of a rhyolite has been added for comparison, and they will be discussed on pp. 122–7.
I | II | III | IV | V | |
SiO2 | 70.35 | — | 67.42 | 73.48 | 73.51 |
TiO2 | not det. | — | not det. | 0.29 | — |
Al2O3 | 15.16 | — | 17.51 | 14.79 | 14.42 |
Fe2O3 | 0.53 | — | 1.71 | 0.03 | 0.46 |
FeO | 4.31 | — | 2.27 | 1.04 | 1.49 |
MnO | none | — | — | trace | trace |
CaO | 1.23 | — | 2.22 | 0.53 | 1.26 |
MgO | 1.89 | — | 1.32 | 0.43 | 0.33 |
K2O | 2.27 | 2.63 | 2.53 | 4.24 | 4.29 |
Na2O | 2.98 | 2.51 | 3.76 | 4.40 | 4.03 |
H2O (at 110°) | 0.141} | — | 1.06 | 0.81 | — |
H2O (above 110°) | 1.06} | 0.04 | |||
SO3 | none | — | none | 0.03 | — |
P2O5 | none | — | none | 0.02 | 0.04 |
99.92 | — | 99.80 | 100 09 | 100.23 |
I. Well foliated muscovite-biotite-schist. Porth Nobla, south side (E9900)
II. G-arnetiferous mica-schist. North-east end of Llyn Hendref, Gwalch-mai (E9993)
III. Typical Penmynydd mica-schist. 300 yards north-north-east of Braint Farm, at 200-foot contour (E9912)
IV. Foliated quartz-albite-rock, with broken phenocrysts of microcline, and a little white mica, epidote, sphene and garnet. 100 yards east-south-east of Graig-fawr, Holland Arms, about two feet from north-west margin of boss
V. Rhyolitic obsidian. Medicine Lake. Anal. U.S. Geol. Surv.
Quartz-schists
These are white, foliated, glistening with-mica, and saccharoid on cross-fracture. They are simple homoeoblastic schists, composed of quartz, with a varying proportion, sometimes very small, of white mica. No felspar has been seen. Some of them have the aspect of quartzites, but show no clastic grains.
The limestones
The limestones are grey or cream-coloured in tint, some are mottled, some have thin dark seams. Most of them bear some resemblance to the grey Gwna limestones, but even the finest are slightly foliated, which is due to trains of tolerably well-formed flakes of mica, lying in a granoblastic base of carbonate, in which are a few small grains of quartz. The carbonate of the grey type is calcite, of the cream-coloured ones dolomite.
A series of slides taken across the limestone of Trecastell, which is a good deal more altered, show that it graduates through calc-mica-schist into mica-schist. A few limestones of the zone are far more highly crystalline, and may be described as gneissose marbles or cipolini. The Bodwrog marble, perhaps the most beautiful rock in the Island, is composed of snow-white granular calcite, with parallel flakes of well-formed white mica and some rounded grains of quartz. The marble of Erddreiniog is grey, and composed also of granular calcite, but with abundant accessories, including quartz, chlorite, iron-ores, white micas, albite and oligoclase, tourmaline, zircon, sphene, rutile, and anatase. Most of them are anhedral, but some of the anatase (identified by Dr. Thomas) has its characteristic form. These two rocks have been analysed, as follows:
I. | II. | |
Residues insol. in HC1 | 4.96 | 23.30 |
Al2O3 | 2.01 | 6.66 |
Fe2O3 | ||
CaO | 50.14 | 37.32 |
MgO | 0.15 | 0.69 |
CO2 | 42.29 | 30.42 |
99.55 | 98.39 | |
Percentage CaCO3 | 89.54 | 66.64 |
I. 767 yards east of Bodwrog Church. Second band of limestone from west. (E10057)
II. Quarry by wall, south of wood, about half a mile north-north-east of Erddreiniog. (E10080)
In No. I. it would seem as if some silicate must have yielded a little to the acid, and its SiO2 and Al2O3 have come down with other elements of the rock. Both rocks differ greatly from the cipolini of the Lewisian Gneiss of Scotland ('Geol. North-West Highlands'. Mem. Geol. Survey, p. 82), as well as from the ophicalcites of the Mona Complex. The absence of magnesium is remarkable.
Graphite-schist
Where the black schists occur within the Penmynydd Zone they are far more highly crystalline, being thoroughly lepidoblastic. Some varieties are lustrous, others dull and sooty on the foliation-surface, but all yield a black streak, one that.. adjoins the Bodwrog marble yielding a very strong black streak. A specimen from a little chasm in the cliff south of Porth Tre-castell, 200 yards south-west of the Telegraph Cable Hut (E10030)
Rutiliferous schists
The graphite-schist is very rich in rutile; but still more is present in a dull green schist at Bwlch-y-fen (E10058)
The hornblende-schists
The hornblende-schists are heavy, platy, dark-green rocks, often with pistacio-tinted epidotic seams. A few varieties are nearly black, a few quite pale in tint. Their essential minerals are hornblende, epidote, zoisite, albite, sometimes quartz, and occasionally pyrite. Sphene is often plentiful, and the other accessories are a white mica, magnetite, ilmenite, apatite, and occasionally zircon and rutile. The rocks may befine, but are usually of medium grain, hardly lepidoblastic, but foliated granoblastic schists. The hornblende is in rather long blades, and pleochroic, thus: X, pale straw-colour, Y, brownish-green, Z, blue-green, that of the pale schists being: X, colourless, Y, nearly colourless, Z, pale blue-green. Most of the epidote is normal, some pale with low birefringence; but in some of the rocks typical zoisite with delicate blue polarisation-tints is quite abundant, often in long prisms. Granoblastic albite is often an important constituent; it is usually water-clear and untwinned, sometimes disseminated, sometimes in seams which contain also quartz and epidote. A few of the dark rocks contain feathery' porphyroblastic hornblende lying in all directions on the foliation-planes. It has the same optical characters as the rest of the hornblende, but is a good deal larger, and is idiomorphic, with the prism and pinacoid well-developed. Oval porphyroblasts of albite-oligoclase, poiciloblastically crowded with inclusions, are occasionally a character; they resemble those in the albite-mica-schists, but their inclusions are much smaller. Some of them are compound, and contain granoblastic quartz. A remarkable schist at Gwalchmai is rich in contemporaneous, granoblastic, pyrite, developed in thin 'schlieren' along the foliation, and therefore a true metamorphic mineral. This unusual rock is also rich in zoisite and rutile, and contains albite porphyroblasts, with some hexagonal hsamatite. The hornblende-schists of the Aethwy Region have many quartz-augen, like those in the mica-schists, some being venous, others nemablastic in texture.
Usually these rocks are well-foliated throughout, but about Holland Arms and Llangaffo there are cores with remains of igneous texture. The hornblende is larger and broader, with pleochroism: X, straw-colour; Y, olive-green; Z, blue-green; their albite is in large broad laths with strong lamellar twinning, and their sphene (which is abundant) is eumorphic. Parallel structure is never absent, but is often very slight, and the rock is here an albite-diorite. The metamorphic process was long, for some of the quartz-augen are cut by old faults that were afterwards healed up by crystallisation; and a few of the quartz-albite augen south-west of Bwlch-gwyn, though the main foliation bends round them, are themselves a little foliated.
The glaucophane-schist
This remarkable rock is unique in Britain, for glaucophane has not yet been detected anywhere else in the British Isles. Even in Anglesey it is, not known outside the Aethwy Region, in which there are 18 masses. It is a dense, heavy schist, very tough, and of a dark steel-blue, sometimes dark lazuli-blue, tint externally, thoroughly foliated, and decidedly but not excessively nemablastic. The body of the rock is very homogeneous, but this is varied by quartz-augen, thin quartzose and epidotic seams, and bright films of white mica tinged with scarlet scales of hematite, usually adhering to the quartzose augen. The foliation is rapidly folded, a structure well brought out by the weathering of the thin hard quartzose seams. The structures on the large scale — are usually parallel, but knots of epidosite about six inches long are not uncommon, and on the crags that overlook Llyn Llwydiarth the normal schist winds about great phacoidal masses of similar but rather less foliated schist several yards in length. Near the same place are cores with surviving plutonic texture.
The essential minerals are glaucophane and epidote; the accessories are white mica, quartz, albite, green hornblende, chlorite, zoisite, hematite and ilmenite, with a little sphene. Lawsonite has been searched for but not found. In one small quartz-knot at Castellior are a number of prisms of brown tourmaline. The aspect of the rock in thin section, which is now well known from the striking coloured plate (No. 47) in Dr. Teall's 'British Petrography',<ref>Photographic plates have been published in Mr. Adye's ' Atlas ' and in Gruben-mann's 'Kristallinen Schiefer', Tafel viii.</ref> is of unusual beauty, nearly two-thirds of it being composed of a continuos foliated weft of clear blue glaucophane, in which float the epidote and all the other minerals.
This weft of glaucophane is composed of slender prisms elongated in the direction of the vertical axis. The basal planes have not been observed, but sections of the rock taken across the foliation show that large numbers of the crystals are idiomorphic in the prismatic zone, the faces (110) meeting at the characteristic angle of 124.2° to 124.4°, being often quite perfect, sometimes combined with (010), and that both prismatic cleavages may be well developed. The refringence and bi-refringence differ but little from those usually obtained. Distinct optical pictures in convergent light are not easy to obtain. The extinction angle is normal, being about 5° in the typical blue glaucophane, but in some crystals of a feebler tint it may rise to 15°. The pleochroism is pronounced, and is: X, very pale straw colour; Y, lavender-violet; Z, strong sky-blue. The moderate proportions of aluminium and of water that are present in the rock show that the mineral is not gastaldite, but a true anhydrous glaucophane.
The epidote is partly in granular aggregates, but largely in idiomorphic prisms elongated in the direction of the orthodiagonal, and a good many show the cleavage. It has a high bi-refringence, and is rather strongly coloured, with the characteristic lemon pleochroism. Epidotes of low bi-refringence are less common than in the other basic rocks of the Complex; but there are a few prisms of true zoisite with blue polarisation-tints. Much of the clear green component that is present is chlorite; but there is also a green hornblende, which is intimately related to the glaucophane, sometimes eumorphically as a core within it, and graduating into it through a narrow blue-green zone, the angle of extinction sinking as the colour changes from green to blue.
These green minerals are apt to be developed on either side of epidote-aggregates in the direction of the foliation, so as to form with the epidote small compound augen. The thin granoblastic lenticular seams of colourless minerals are largely quartz; but contain a little water-clear felspar. This has a much lower refractive index in all cases than the quartz, and in some cases undoubtedly lower than 1.536: it is optically positive; and sometimes displays lamellar twinning with extinction angles of about 8°. It is therefore albite. Bordering the siliceous seams are often trains of well-formed plates of clear scarlet huinatite, and there are small schlieren of ilmenite, sometimes passing into hzematite along their edges. The granules of sphene are very small, and rather rare, and may have been developed from the ilmenite.
In many slides hardly any white mica can be seen, but there is a good deal in the rock as a whole, concentrated, however, into the films alluded to. It is in well-developed plates, often as much as a millimetre in diameter, many of which display a perfect optical picture in convergent light, with an acute bisectrix emerging nearly at right angles to the cleavage, and always optically negative. Some of the plates, however, have undergone much optical distortion, producing undulose extinction and disturbance of the optic axes. When free from this, the axial angle is a wide one. The refractive index and birefringence are indistinguishable from those of muscovite. Some flakes of this mica were detached, freed from other minerals, and destroyed by hydric fluoride. The solution was examined spectroscopically, and Mr. J. O. Hughes reports that it displayed the spectrum of sodium strongly, without any trace of the spectrum of potassium. This mica, therefore, is paragonite.
The large epidosite knots consist of granoblastic epidote with short needles of glaucophane, and are quite unfoliated. The quartz-augen are of the same types as those in the green hornblende-schists. Thin quartz veins cut the foliation at right angles, but contain a little glaucophane and are themselves foliated, so that they must belong to an interval in the metamorphism. There are also lenticular bands of granoblastic quartz, with epidote, in which are plates of paragonite and many needles of glaucophane; and these, though seldom exceeding an inch in thickness, may be allied to some of the siliceous glaucophane-schists analysed by Washington.
The rocks of plutonic aspect occur as phacoids a few yards in length, floating in ordinary glaucophane-schist, compared with which they are rather coarse. They are composed of lenticular tracts of glaucophane (in which is a little green hornblende) inosculating with similar tracts of granoblastic epidote, zoisite, quartz, and albite, with aggregates of sphene. Some of the glaucophane is in broad plates, which may lie in any direction. The rock is a modified and foliated glaucophane-diorite.
The true glaucophane-schist is a rock sui generis, and is found in large tracts of its own. But some of the green hornblende-albite schists contain small quantities of a blue-green amphibole with low extinction angles, as well as of real glaucophane, so that intermediate types of rocks certainly exist.
The following analyses will enable this glaucophane-schist to be compared with the hornblende schist and with standards.
I | II | III | IV | |
SiO2 | 45.87 | 47.47 | 47.859 | 57.67 |
TiO2 | not det. | not det. | 1.376 | — |
Al2O3 | 18.80 | 15.25 | 15.614 | 11.07 |
Fe2O3 | 5.72 | 8.22 | 4.921 | 3.20 |
FeO | 5.44 | 719 | 7.050 | 9.68 |
MnO | trace | trace | 0.077 | 0.06 |
CaO | 11.64 | 11.32 | 9.113 | 0.95 |
MgO | 6.76 | 5.96 | 6.328 | 9.85 |
K2O | 1.99 | 0.56 | 0.822 | 0.42 |
Na2O | 2.61 | 2.11 | 3.210 | 6.80 |
H2O (at 110°) | 0.05 | 0.04 | 0.161 | 0.12 |
H2O (above 110°) | 1.35 | 213 | 2.789 | 0.36 |
P2O5 | not det. | — | 0.037 | — |
CO2 | not det. | — | 0.696 | — |
100.23 | 100.25 | 100.053 | 100.18 | |
Spec. Grav. | 2.21 | 3.77 | — | — |
I Hornblende-epidote-albite-schist (E9914)
II Glaucophane-epidote-schist (E9829)
III. Average of nine basic glaucophane-schists given by Washington. Op. cit., Nos. I–VI, VIII–X.
IV. Glaucophane of Syra. Anal. H. S. Washington. Op. cit.
The specific gravity of II is rather above a mean of the specific gravities of glaucophane and epidote. That of I is much lower than a mean of those of green hornblende, epidote, and albite; low even if we suppose a considerable excess of albite, which is visible in some slides. It will be seen that I contains much more potassium and less iron than II. Comparing II and III, the glaucophane-schist of Anglesey is seen to be a tolerably typical example of its class, but rich in ferric iron and in calcium, poor in both alkalies and presumably in titanium, as that was not estimated. In view of the proportions of its alkalies, it is of interest to note, that its amphibole, its felspar, and its mica, being glaucophane, albite, and paragonite, are all sodium species.
Origin of the glaucophane-schist
It is usually assumed that glaucophane-rocks, that of Anglesey included, are derived from gabbros or other basic intrusions. In the spring of 1903, however, the present writer, having found that the basic schists of the Gwna Beds (see pp. 76–8) are derived from the spilitic lavas, that amphiboles develop in those schists as they approach the Penmynydd Zone of metamorphism, and that in several places they contain a little glaucophane; began to seek for evidence on the possible derivation of the glaucophane-schist from the lavas. At that time the lavas had not been analysed, but the question at once arose as to what had become of their jaspers in the process. In the course of the summer it was found that the jaspers became bleached at a moderate stage of metamorphism (see p. 88), and the suggestion occurred that the quartz-augen of the glaucophane- and hornblende-schists might represent them. Quartz-augen, it is true, occur also in the mica-schists, but it was found that a skin of haematite usually surrounded those in the basic schists, which might represent the discharged iron of the jasper. When the lavas were analysed, it appeared at once that a common origin was possible. In 1911, Dr. Teall, quite independently and without knowing of any of this evidence, suggested, in a letter to the present writer, that glaucophane-schists might be derived from pillow-lavas, asking if there was any field evidence for such a connexion; and in 1912, Mr. J. O. Hughes, independently of both, suggested the connexion on the ground of the analyses alone<ref>Since writing the above, I have obtained a copy of a paper by Rosenbusch "Zur Deutung der Glaukophangesteine" (Ak. Wise. Berlin, 1898), in which he gives a study of some glauc-amphibole rocks from California regarded by Palache as altered tuffs. He considers them to have been "diabase- or spilite-tuffs', and regards their fragments as diabase- or spilite-lapilli, but speaks with reserve, the nature of the fragments being difficult to determine. It will be remembered that spilitic lavas had pot at that time been very closely studied.</ref>. If the analyses on p. 74 be compared with those on p. 118, it will be seen that the rocks are closely allied in composition, especially in the relations of their alkalies. The difference is chiefly in the ferric iron, a difficulty that may perhaps be surmounted by supposing that the original of the glaucophane-schist had become haematised at an early stage of its history, a change that is known (see pp. 73–4) to have affected the Gwna spilites very widely.
Garth Ferry — Now, in the basic mass that ranges south-westward from Garth Ferry, a rather dull glaucophane-epidote-schist (E9526)
Yr-allt — The basic band that ranges along the road at Pedair-groeslon and Yr-allt is, as far south as Yr-allt, a green chlorite-epidote-schist rich in ternary albite (p. 367), but at its southern end a good blue glaucophane-schist appears. The two types are not seen in continuity, though they lie on the same line of strike. A little to the north-east of Yr-allt, however, the green chlorite-epidote-albite-schist contains (E6092)
Llaniestyn — At the farm by Llaniestyn Church is a dull chlorite-epidote-schist (E9691)
Llandysilio — A little glaucophane is also found in the chlorite-epidote-albite-schist (E10208)
Inferences — There can be little doubt, therefore, that these four imperfect glaucophane-schists are modifications of the spilitic lavas of the Gwna Beds. Were no other evidence forthcoming, there would be no hesitation in identifying the perfect ones of the Penmynydd Zone with the same lavas, though it would be unwise to lay stress on an identification of their quartz-augen with the Gwna jaspers. Their occasional phacoidal structure, and especially their large knots of epidosite, are certainly reminiscent of the ellipsoids of the lavas. No quartzite or limestone has been found with them, so the original rock is probably not the Llanddwyn spilite, but may be the Engan spilite (pp. 76–8), with which no quartzite or limestone are associated. The cores of glaucophane-diorite and zoisite-amphibolite might easily have been derived from the small associated sills of albite-diabase.
On the other hand, we have seen that the glaucophane-schist is linked by intermediate mineralogical types to the green hornblende-schists, and that some at any rate of those must be intrusive, as they have cores with good plutonic texture. From the presence of cores of green hornblende in some crystals of glaucophane, it has been inferred that the blue has been produced from the green amphibole. But the glaucophane of Garth Ferry has developed in a rock that must have been pyroxenic without any development of green amphibole as an intermediary. Whichever the origin of the typical glaucophane-schist, it must have been produced either from a hornblende-albite or an augite-albite rock; most of the elements of the albite going to the production of epidote, the sodium being transferred to the ferromagnesian mineral so as to produce glauco-phane, and a little albite remaining over in a reconstituted form.
Dr. Teall points out to me that the higher density of glaucophane-schist implies that it was pressure that determined whether the sodium should enter into albite or into glaucophane. Now, in the Penmynydd Zone the hornblende-albite-schist and glaucophane-schist occur side by side, and there is not the slightest evidence of any greater pressure in or around the latter. Under dynamo-metamorphism, the outer portions of a deep-seated albite-diorite containing 1.99 per cent. of K2O would tend to produce a green hornblende-schist with some reconstituted albite; while a spilitic lava, having consolidated originally under low pressures, would, when passing into an amphibolitic schist of some kind (as it could not fail to do), tend to transfer its sodium to the high-pressure mineral, and give rise to a glaucophane-schist. The uniformly fine texture of the glaucophane-schist over large areas also points to a fine rock as its origin, for basic intrusions of such size could hardly fail to show coarser centres, whereas the glaucophane-diorites referred to are known only in one place and are quite small.
It therefore seems probable that much of the glaucophane-schist has been produced from the spilitic lavas themselves; but it must also be admitted that parts of it may represent the intrusive portions (not very deep-seated) of the same magma, which had consolidated at still lower levels as coarse albite-diorite, now partly transformed into albite-epidote-hornblende-schist.
Banded marginal rocks
Along the margins both of the hornblende- and the glaucophane-schist the mica-schist often assumes an unusually compact and flaggy structure. This material, which contains very little mica (sometimes none at all), is rich in albite, usually also in epidote, sometimes in zoisite as well. It is a typical homœoblastic quartz-albite-epidote rock. About Holland Arms and elsewhere long narrow lenticular strips of it occur as inclusions in the hornblende-schists. They lie along the foliation planes, and such foliation as they themselves possess is conform'able to that. In many places, especially on Mynydd Llwydiarth, this material alternates rapidly with both the amphibolitic schists along the junctions, so that there is a zone of interfelting, sometimes forty yards in width. On the crags north-east of Tyn-y-mynydd ('west') this is so pronounced as to give rise to what might be called strong banded gneisses, but that they have not the coarse granitoid texture that is usually implied by that term. In one crag of hornblende-schist nine feet wide, seven acid bands were counted, contrasting strongly with the dark ones. But both acid and basic bands may be so thin as to be little more than films. In these finely banded rocks the white seams are granoblastic albite and quartz with a few garnets, the dark seams chiefly straight prisms of hornblende with many of blue-plarising zoisite (some of which have cores of epidote), some iron-ores, and rutile. Often the junctions are perfectly sharp; at other times there is a narrow zone of passage that is probably a reaction-rim between the acid and the basic matter.
Now, whatever the origin of the mica-schists, it is evident that this compact modification depends on the presence of the basic schists. We have seen that some of the latter contain coarse dioritic centres. There is therefore presumptive evidence that these were intrusive into the original material of the mica-schist, that the inclusions are xenoliths, and that the banding is due to rolling out of thin branching sheets at the margin of a basic sill. The richness in albite of the compact acid rock, and its texture, are suggestive of its having been an adinole, a kind of material that is known to possess great powers of resistance, and thus to retain its compactness under dynamic metamorphism. That this material is found on the margin of the glaucophane-schist of Llyn Llwydiarth points to that particular mass having been intrusive, and it is the one in which the cores of glaucophane-diorite occur.
Origin of the Penmynydd Mica-schists
Survivals of original textures
Remains of original structures have been found at four places only; and as in three cases these are igneous, in one sedimentary, it is evident that the problem is not a simple one. The field elations also indicate that the rocks must have had a heterogeneous origin.
Holland Arms — In the Aethwy Region, at a craggy knob 100 eet in width, about 100 yards east-south-east of Graig-fawr, Tolland Arms
Gaerwen — This conclusion is confirmed by finding that a compact, unfoliated, rock, near Gaerwen Junction (E9480)
Ynysoedd Duon (1) — The other cases are on the coast of the Middle Region at Ynysoedd Duon. Some 200 yards to the south of the southern islet, on the north cliffs of a chasm, are massive cream-coloured bands composed of a crypto-crystalline mosaic full of broken phenocrysts of albite, quartz, and micro-perthite. The rock, though crushed, is not much reconstructed, and is undoubtedly a sodium-felsite (E9184)
There is no direct evidence as to whether this felsitic material be intrusive or effusive. The included acid strips in the hornblende-schists might be (and have been) regarded as intrusive veins. But they have no transgressive junctions, and there is nothing to prevent their being regarded as xenoliths, as suggested on p. 121. And, as no cores with plutonic texture have been discovered in the felsitic mica-schist, whereas cores of the kind survive within the basic schists, it would appear probable that the latter are intrusive in the former, the intrusions being anterior to the dynamic metamorphism.
Ynysoedd Duon (2) — About 100 yards to the south of the southern islet of Ynysoedd Duon, a flaggy mica-schist appears on the low cliffs, upon whose weathered faces are little grains of clastic quartz, and in thin section (E11086)
Marginal phenomena
Let us now consider the field relations of the zone. Its mica-schists adjoin the Gwna Beds along many miles of boundary, not only of the main masses but of outliers and inliers; and except where basic rocks come against the line, the Gwna material is invariably the Gwna Green-schist, which has been shown (pp. 67–9) to be sedimentary in origin. We have already seen that clastic structures disappear as we pass from the Gwna Grits to the Gwna Green-schist. If, further, from a tract of Gwna. Green-schist we pass into a tract of the Penmynydd Zone, we find, first, that there is perfect conformity between the foliation planes; next, that the character of the schistosity remains the same, except that nema-blastic texture disappears; and thirdly, that there is a rapid rise in metamorphism. As the margin is approached, chlorite begins to disappear, green (and sometimes brown) mica to develop; white mica to increase in quantity and very greatly in size and individualisation of the flakes; epidote, zoisite, apatite, sphene, and garnet appearing when the junction line is reached. Small porphyroblastic albites develop locally, and the texture of the body rises from crypto- to granoblastic. When basic schists are present, green and blue amphiboles take the place of chlorite. That the change is not catamorphic but anamorphic is shown by the characters of the minerals along the junction. The crystals of the Penmynydd Zone are not cataclastically broken down. The bladed amphiboles of the basic schists, for example, are not crushed as we follow them back towards the Gwna tracts, they diminish in size, and in the zone of passage are slender, but perfect, actinolitic needles. These changes can be observed anywhere along the boundaries. But there is perfect exposure of the junction itself at five places at least, and in each case there is an uninterrupted passage.
Aberfraw — One of these is on the Aberffraw coast, where the main boundary runs out to sea 833 yards south by east from the island church, and has been examined by Dr. Horne and Mr. Clough, with the writer. It is at a deep chasm, in which there is probably a fault, but the junction is not in this chasm, it is at the brow of its northern cliff. At one place there is a small crush, but it is insignificant, and passing obliquely into the cliff, leaves the passage visible on either side of it. Typical quartzose Gwna Green-schist passes into typical Penmynydd mica-schist, the structures on the large scale remaining unchanged. In the bay north-east of Braich Lwyd is an inlying strip of Penmynydd mica-schist, with limestone and graphite-schist. A little west of the cove at the nook of this bay a buttress runs out eastward from the cliff, and on it is another exposure of the junction, which is again a passage from Gwna schist with grit and jasper to siliceous mica-schist with small surviving clastic grains. Slices taken from close to the boundary show that the Gwna schist is unusually micaceous, the Penmynydd schist less so than usual, but still perceptibly better crystallised than the other.
Mynydd Llwydiarth — The third and best exposure is in Mynydd Llwydiarth. North-east of the 'h' is a cottage, called on the six-inch maps
The Strait — The fourth is on the Menai cliffs between Glyn-y-garth and Craig-y-don, where the Gwna Green-schist develops locally higher crystalline types than usual (pp. 360–1) and passes imperceptibly into mica-schist that if found in a tract of the Penmynydd schists would not be separated from them.
Llanddona — A fifth is at Wern, Llanddona, where a large glauco-phane-schist occurs among the Gwna Beds. Approaching this from the south, it is found that the Gwna rocks, there very siliceous, begin to develop larger micas, until close to the glaucophane-rock they might be treated as Penmynydd schists. There is no change either of structure or material, but only of crystalline condition. Along its margins, therefore, it is certain that the Penmynydd mica-schist has been derived from rocks of sedimentary origin.
An Horizon within the Zone
Further, we have seen that in the Middle Region a quartz schist, a crystalline limestone, and a graphitic schist are found within the zone. Now these rocks do not occur in a merely sporadic manner; they are menibers of a tripartite group, of which, according to the accidents of thrusting and erosion (pp. 192–4, 343–4), one, two, or all three may be found together. But it will be remembered that a quartzite, a limestone, and a graphitic phyllite are found as a similar group within the Gwna Beds. There they graduate by change of composition into the adjacent phyllites, and here they likewise graduate into the mica-schist.
Chemical composition and inferences
In both regions, therefore, it is certain that the Penmynydd mica-schists must be derived in part from felsitic igneous material, in part from the sedimentary material of the Gwna Beds.
When once, however, we leave the margins of undoubted felsite and undoubted sediment, and pass out into the country of highly anamorphic schist, no criterion has yet been found for separating, in the field, schist of the one origin from schist of the other. Yet, pending such discovery, some idea may be arrived at of the general nature of that country. Consider the analyses (p. 112). No. IV corresponds so closely with No. V. that there can be no doubt of its being a true rhyolitic rock, its alkalies being high even for a rhyolite. But in the others, while they approach the composition of a rhyolite, there is a marked falling off in alkalies, though these are still not much below the rhyolitic average. There is an increase both in calcium and magnesium, and a very serious increase in iron, especially in ferrous iron, the proportions of all three elements exceeding those characteristic of rhyolitic rocks. That these great tracts of schists were produced from uniform felsitic sheets is therefore impossible. Comparing the analyses with those on p. 70, it will be seen that in proportion as they depart from the composition of a felsite they approach that of the Gwna Green-schists. If, however, we exclude Nos. IV and V of the Gwna Group, which are exceptionally micaceous, we find that in the Penmynydd Zone there is a decided increase of potassium. Now the passages from Gwna Green-schist described above, although undoubtedly continuous, are curiously rapid, the change coming on in the course of a few yards, and the new type reaching its average degree of development within a quarter of a mile. That progressive metamorphism should produce this result without any concurrent change in the original material seems impossible, and accordingly we find an increase of white mica, which must mean an increase of potassium. Dynamo-metamorphism, indeed, could not have produced continuous passages between the products of sediment and those of solid felsite along miles of junction that must, in such ease, have been originally well defined. Pyroclastic matter, however, may mingle with sediment in any proportion. If, therefore, we suppose the Penmynydd mica-schists to be composed of rhyolitic dust and tuff, with rhyolitic lavas on some horizons and bands of sediment on others, all the phenomena they present can be reconciled.
The occasional survivals of igneous and clastic structures might be expected in specially resistant beds. The analysis of column IV would be that of a pure flow of rhyolitic lava; those of I and II representing rhyolitic tuffs with admixtures of sediment. The compact quartz-albite-epidote rocks could be regarded as modified adinoles produced from fine ashy sediment in aureoles around and xenoliths in the basic intrusions. The zones of passage at the junction with the Gwna Green-schists find an explanation when regarded as zones of alternation where (as in the well-known ashy grits of Snowdon) felsitic tuff and ashy sediment were mingling, and (assuming the Penmynydd schists to be the older) explosions of rhyolitic dust were gradually ceasing to mingle with the sediments. A passage of this kind is, in fact, visible at the junction of the Fydlyn group (see p. 90) with the Gwna Beds of the northwest; and it is a rapid one. Such a zone of passage, when subjected to crystalline reconstruction, would show an abnormally rapid progressive metamorphism, for the alkaline volcanic rocks would recrystallise much more readily than would the sediments, and, if rich in potassium, would at once yield an abundance of muscovite, so that there would be a rapid passage from a dull sericitic schist into a lustrous mica-schist, which is the characteristic feature of the zone in question.
The Coedana Granite and the Zone
Further evidence as to the origin, and also as to the age of the Penmynydd metamorphism is obtained along the edges of the Coedana granite. From Coedana to Gwalchmai the two rocks come together without any intervening zone of hornfels, two small granites lie along the junction of hornfels and mica-schist on either side of Ty-croes, and at Gwalchmai village one lies within the mica-schist. Now when the granite is exposed close to the Penmynydd Zone it is intensely sheared, and fine granoblastic matter like that of the mica-schist appears within it; while thin seams of granitoid matter are to be found within adjacent mica-schist that shows no sign of cataclastic deformation or thermal alteration. There are no transgressive junctions, and sometimes the granite fades off into mica-schist. It is certain, therefore, that the granite is involved in the Penmynydd metamorphism. To some extent it has been incorporated, but the evidence points to this being merely marginal, and that there has been no bodily transformation of granite into mica-schist. West of Bod-wrog Church, not only is the transition too sudden, but the schist is a quartz-schist, far too siliceous to represent the granite, and the junction is evidently an old intrusive margin sheared and recrystallised. In a slide from Bodwrog Church (E8484)
Conclusions
From the foregoing evidence it is clear that the Penmynydd rocks are a metamorphic, not a stratigraphic zone; and that the original rocks involved are partly sedimentary, partly volcanic, the latter being both effusive and pyroclastic; partly also, though to a small extent only, plutonic: The great body of alkaline mica-schist must be derived from felsitic lavas and tuffs, and there is good reason to suppose that these belong to the Fydlyn Group. The sedimentary material is undoubtedly that of the Gwna Group, and includes its alternating grits and phyllites, as well as its quartzite, limestone, carbonaceous-phyllite division. The basic schists are derived, there can be little doubt, from the Gwna spilitic suite, whose effusive and intrusive members seem both to be represented. The Coedana granite is also involved, but only to a small extent, along the margins. All these rocks are converted into holocrystalline schists of different kinds, the glaucophane-schist being a special feature of the zone. The metamorphism is later than the intrusion and consolidation of the Coedana granite.
The Gneisses
These are coarse, granitoid in texture, and more deep-seated and plutonic in aspect than the other foliated rocks of the Complex. The term as here used includes basic rocks which will be called hornblende-gneiss, and biotite-gneiss or gneiss proper, which will be termed briefly 'the Gneiss'.
Hornblende-gneiss
This term will be used in precisely the same sense as it is on p. 42 of the Memoir on the North-West Highlands of Scotland; that is to say, it will include not only well-banded rocks and rudely-banded rocks, but also what might be called foliated, and even unfoliated, diorite. As it is, however, doubtful whether the original material had the chemical composition of a diorite, that word will be employed for local description, only, and not for the formation as a whole. Nearly all are dark, heavy, rocks, the banded gneisses having a totally different aspect from that of the hornblende-schists of the Penmynydd Zone. Four principal types may be recognised a coarse, dark, massive rock of dioritic aspect
The minerals identified are hornblende, felspar, biotite, quartz, epidote, zoisite, sphene, ilmenite, magnetite, pyroxene, apatite, zircon, rutile, garnet, pyrite, orthite, chlorite, leucoxene, and natrolite.
The only essential minerals that are always present are hornblende and felspar. But biotite, quartz, epidote, and even sphene, rise in one variety or another to the rank of essentials. Thus, we have hornblende-felspar rocks, hornblende-felspar-quartz rocks, horn-blende-felspar-quartz-biotite rocks, hornblende-felspar-sphene rocks, and hornblende-felspar-epidote rocks.
All the felspar that yields definite optical reactions is albite. Much, however, is turbid, and oligoclase is probably present, for some crystals with ill-preserved lamellation appear to extinguish at very low angles; but albite is undoubtedly the dominant felspar. It is partly twinned, partly simple, and in all the types occurs in the isodiametric interlocking grains characteristic of plutonic products.
Different varieties of hornblende are found to characterise different types of rock, with pleochroism:
X, Pale straw-colour; Y, pale brownish-green; Z, bluish-green.
X, Straw-colour; Y, brownish-green; Z, deep-green.
X, Colourless; Y, pale brownish-green ;_Z, pale-green.
The first variety is usual in the rocks of dioritic aspect; the second in the dark bands that make up the bulk of the banded gneiss; the third (which has the unusual absorption Y slightly> Z > X) in the lighter bands with biotite and quartz. All these hornblendes have a broad, short habit, never bladed or acicular, and though usually a little longer in the direction of the vertical axis, may have their greatest dimension transverse to the prism. They are never eumorphic, but a slight tendency to development of the prism faces may be noticed, and the cleavages are strong. There is no reason to doubt the original nature of all these hornblendes, but slender needles of secondary actinolite are found in albite near Holland Arms. The biotite. has been brown, but is often much chloritised, the pleochroism, where it survives, being pronounced but moderate.
The quartz occurs as rounded grains included in the albite and hornblende, or as a mosaic with the albite.
Epidotes are very abundant in some of the rocks. In the Middle Region they are clear pistazite with the usual pleochroism, and some of them may be original, that is, products of the metamorphism, but others that are found in veins must be later, though probably not much later. A few dark-brown grains that appear to be biaxial are probably orthite. In the Holland Arms district an epidote that is dusky with minute inclusions is an important constituent. Its crystals are often elongated, sometimes along the orthodiagonal, but sometimes along the traces of the principal cleavage, which is presumably basal, and are scarcely pleochroic. Nearly all of them have a high birefringence, but sometimes they vary towards zoisite. Some of the large albites of this area are crowded with sheaves of slender prismatic epidote and of true zoisite disposed often with great regularity. This must be regarded as a stage of saussuritisation, but spaces of clear albite remain which retain their optical integrity. It is in these felspars that the needles of actinolite are found. In others the albite has been wholly replaced by granular zoisite. The large dusky epidotes are often found in contact with the sheaves of slender epidote after albite, but the boundaries are sharp. Most of the Holland Arms and Gaerwen slides are old and thick, but these rocks offer interesting studies in saussuritisation.
Sphene is remarkably abundant as an accessory, and as above stated, is sometimes an essential. It also attains unusual dimensions, one or two crystals being as much as 2.5 millimetres in length
Ilmenite, often leucoxenised, appears to be more plentiful than magnetite.
A pale-green pyroxene is occasionally found in the Middle Region, but in small quantity. It is anhedral, does not form cores to the hornblende, and both minerals appear to be independent and original. It is of interest to note that it is found in the well-banded gneissoid facies.
Apatite, in short hexagonal prisms, is remarkably abundant. The remaining accessories are never plentiful, garnet being rare.
Pegmatite, and textures
Pegmatite
The unbanded rocks, which are commonly quartzless, are typically granitoid in texture. The banded rocks are granoblastic, rather coarse in grain, though less so than the unbanded, and the darker ones are also often quartzless. The finest are the lighter bands with quartz and biotite. All are veined by and interbanded with pegmatite.
Biotite gneisses without hornblende are also present, but they will be discussed further on, as they may be foreign to the group.
Development
The development of the hornblende-gneiss can best be studied in the Middle Region, between Treban alluvium and Llandrygarn Church. The most primitive type, which is seen in many places, appears to be a massive, mottled rock
For the sake of simplicity the pegmatites have been, so far, ignored. But they appear at quite an early stage, and take part in the process throughout. Their first appearance is in the nodular rock of Llandrygarn, throughout a large part of which the black nodules are isolated, not merely by the mottled hornblende-rock, but by veins and shells of pegmatite. Close by, at the farm next the church, this aggregate has been drawn out into a gneiss with short, rudely lenticular banding. Various further stages may be seen to the west of Clegir-mawr until we reach the perfect banded gneisses, with pegmatite seams, well seen on Craig-yr-allor, between Clegir-mawr and Treban. The banding has, in the meantime, become still more accentuated by the development of the finer granoblastic type with biotite and, which may be supposed to have originated from reaction between drawn - out quartz-albite-pegmatite and normal hornblende-gneiss. As a few large plates of biotite may be found in the unfoliated rocks, there seem to be two generations of that mineral. The banded gneiss thus consists of granoblastic horn-blende-albite rocks, rich in sphene, and of various shades of darkness, with the finer biotite-quartz bands, the banding being accentuated by innumerable seams of pegmatite, the whole complex being folded. But the production of pegmatite had by no means come to an end. Short, stout knots of it (as well as of pure quartz) appear between the bands of the gneiss
Comparisons
To readers who are familiar with the Lewisian Gneiss of Scotland the basic parts of that great formation will doubtless have been recalled by the foregoing description. The resemblance is indeed remarkable. The rocks correspond to those of Group III. of the scheme given on p. 43 of the Memoir on the North-West Highlands, and the gneisses correspond so closely in microscopic structure that the figures on
Granitoid biotite-gneiss or gneiss proper
This is the most deep-seated member of the Mona Complex, being a combination of a granitoid with a foliated element itself highly crystalline.
The granitoid component
The minerals are quartz, felspar, biotite, and white mica, with a little sphene, apatite, and zircon, but these accessories are in small quantity. The quartz is of the type usual in granites. The biotite, which is in fair-sized flakes, has been brown, but is commonly chloritised with separation of leucoxenised ilmenite, showing that it was titaniferous. There is more of it than of the white mica, but not very much of either. The dominant felspar is albite. No potassium-felspar has been detected. Dr. Teall, after examining the ground with the writer, compared the felspar of four of the granitoid bands of Henblâs with four specimens of the Coedana granite. All of the latter contained orthoclase (p. 91), the former only albite with a possible inclination to oligoclase. In a series, also, of many, slides and powders taken from the Middle Region, from the Nebo and Gader Inliers, and from Mynachdy, the writer has found that albite is general, but that some of the rocks contain a considerable proportion of oligoclase. No porphyritic felspar is known. The rocks may therefore be described as albite-granites containing in some places oligoclase. Whether the white mica be muscovite or paragonite has not yet been determined. The structure is typically granitoid, and of coarse to medium grain. The rocks differ, therefore, from the Coedana granite both in structure and in composition. Not only are phenocrysts absent, but so is orthoclase, all their felspar being of sodium or sodio-calcium species. The magmas were evidently different.
The foliated component
includes mica-gneisses of three types and also some crystalline limestones.
Mica-gneisses — The minerals identified in the mica-gneiss are quartz, felspars, biotite, chlorite, muscovite, hornblende, magnetite, ilmenite, sphene, leucoxene, rutile, sillimanite, garnet, idoerase, tourmaline, zircon, apatite, graphite, epidote, and talc.
The quartz is often in rather large grains, and though usually clear may be so crowded with minute inclusions as to be hardly less turbid in aspect than the decomposing felspar. The dominant felspar is probably albite or albite-oligoclase, but these rocks differ from all the rest of the Mona Complex in the importance of oligo-clase. It is present in many of them alongside of albite, in a good number is the principal, and in some appears to be the only felspar. Both it and albite are often in large grains, with or without lamellar twinning, intergrown granoblastically with the quartz. Potassium-felspar has been found only once, and that where (p. 323) there is reason to suspect an apophysis of the Coedana granite.
The biotite, often in large flakes, though much chloritised, is frequently well preserved, and is deep-brown in basal plates. It has a stronger pleochroism than the other micas of the Complex, being pale straw for rays vibrating at right angles to, very deep-brown, sometimes reddish-brown, for rays vibrating parallel to, the base. As it is also very nearly uniaxial in most cases examined, and is (see analysis No. I, p. 137) rich in FeO, it is evidently a haughtonite. The gneisses of the Nebo and other northern inliers are brilliant with a large white mica, which is almost uniaxial, and is a bleached biotite. Parts of the crystals are occasionally still brown and pleochroic, the bleaching having proceeded along the cleavage, so as to simulate intergrowths of muscovite. The bleaching is accompanied by separation of clots of iron-ore and needles of rutile. But the biotite retains its optical properties, especially its high, negative, bi-refringence.
The true white-mica, which from the analyses (p. 137) must be regarded as muscovite, varies a good deal in axial angle. Both micas develop the basal planes well, those of the biotite nearly always lying along the foliation; but the muscovite is occasionally in stellate groups. Theyareoften intergrown, but the muscovite sometimes pierces the biotite (E9935)
In some of the gneisses of the Nebo Inlier, on the northern side of Porth Helygen, there are, as well as rose-coloured garnets, abundant porphyroblasts, about four millimetres in diameter, of a clear, glassy, grass-green mineral, which weather into hollows. Those cut through in thin section are unfortunately in very bad condition, but show signs of a pair of cleavages at right angles unlike the curved cracks of garnet. The mineral has a high refractive index and low bi-refringence, and, so far as can be made out (though no good optical figure has been obtained), seems to be uniaxial. From the powder of a better preserved crystal Dr. Thomas considers that it is almost certainly idocrase. Graphite also occurs on the same coast, and being partly foliated with the gneiss, may be original. It was determined chemically on a specimen from Rhosmynach-isaf by Mr. J. O. Hughes.
Sillimanite — After the quartz, felspars, and biotite, this is the most abundant mineral of the gneisses, and is undoubtedly the most significant in regard to their nature and origin. It is rare in the most highly granitoid portions, but in some of the coarse lepido-blastic parts is extremely abundant, imparting to them, indeed, a nemablastic texture. The richest localities are the coast of the Nebo Inlier (E9527)
Limestone — A massive grey crystalline limestone occurs at several places in the Nebo Inlier. Its carbonate is nearly all calcite, but it is rich in silicates and heavy minerals. Conspicuous among these is brown sphene, often in double wedges, sometimes pseudomorphed in leucoxene. Albite in large grains is abundant, and there is a little quartz. In some of the slides (E10568)
Chemical analyses
The following analyses have been made by Mr. J. O. Hughes.
I | II | III | ||
SiO2 | 54.01 | 68.09 | Residues insol. in HCl | 37.60 |
Al2O3 | 21.19 | 17.44 | Al2O3 | 2.44 |
Fe2O3 | 1.43 | 4.81 | Fe2O3 | 3.07 |
FeO | 10.27 | — | CaO | 29.21 |
CaO | 1.08 | — | MgO | 2.22 |
MgO | 1.74 | — | CO2 | 25.60 |
K2O | 3.94 | — | H2O | not det. |
Na2O | 1.83 | — | — | — |
H2O (at 110°) | 0.60 | — | — | — |
H2O (above 110°) | 2.71 | — | — | — |
99.04 | — | — | 100.14 | |
Percentage CaCO3 | 52.16 |
I. Albite-biotite-sillimanite-garnet-gneiss, 617 yards east-south-east of Llecheynfarwydd Church (at 'yd'), in angle between road and farm lane of Tyddyn-gyrfa (six-inch map) (E9939)
II. Albite-muscovite-biotite-gneiss, with a little sillimanite and garnet (E9887)
III. Forsterite-limestone (E10266)
The high percentages of Al2O3 and of FeO in No. I will at once be noticed.
Nature and relations of the components of the gneiss
These components may be roughly classified as follows:
A. Fine hard siliceous bands
B. Coarser granular biotite-gneiss
C. Coarse flaky biotite-gneiss
D. Crystalline limestone
E. Granite or pegmatite
Of these, D is rare, and A never present in large quantity. B and C make up the great body of the gneiss, in so far as it is tolerably free from granitoid matter. The hard bands (A) are composed of quartz, albite, and a little biotite. The texture is always finely granoblastic, but some of the rounded quartz weathers very much like clastic grains. The second type (B) is also granoblastic, but rather coarsely so, and its quartz and felspar are often elongated along the foliation, the albite in large grains with lamellar twinning. Short, wavy, lenticular micaceous seams occur in it, and by increase of these it may pass into the third type (C). This, though often extremely micaceous, with biotites that may be four or five millimetres in diameter, is hardly lepidoblastie, coarse granoblastic felspar and quartz generally making up a large part of it, and the biotite being often in good thick plates. Its structure is typically lenticular and its foliation undulose. It is in this rock that oligoclase tends to exceed albite, and that sillimanite and all the more unusual minerals are apt to be found. The prevalent types may thus be briefly described as albite-biotite-gneisses, oligoclase-albite-biotite-gneisses, oligoclase-albite-biotite-sillimanite-, and oligoclase-albite-biotite-sillimanite-garnet-gneisses.
Origin of the foliated components
Before describing the way in which they are modified by the granitoid element (E), it will be well to consider the probable nature of the original materials. The first (A) is highly siliceous, more so in many cases than any known igneous rock. The second (B) is quartzo-felspathic, and might have been derived either from an albite-granite or from an albite-grit, albite-arkose, or albite-tuff. The third (C) closely resembles many rocks of the Scottish Highlands that are certainly pelitic sediments, such -as the wavy mica-schist of Suisgill, Sutherland, described by the present writer.<ref>Quart. Journ. Geol. Soc., 1896, p. 643.</ref>
From the analysis No. I (p. 137), it is seen to be highly aluminous. No igneous rock, save some of exceptional composition that differ totally from it in their other components, contains anything like such a percentage of aluminium. But the specimen analysed was collected in the year 1901, and many examples of the type that have since been found contain far more sillimanite, and also more garnet, some being, indeed, mainly composed of quartz, sillimanite, and garnet, or of quartz, sillimanite, and biotite. The percentage of Al2O3 in specimens lately collected must exceed 30.00. Even the specimen analysed<ref>The percentage of iron, especially of FeO (evidently derived from haughtonite) is remarkable, but there must be quite as much in the Suisgill mica-schists.</ref>, and still more so those just mentioned, could not have been derived from anything but pelitic sediments. And the mineral sillimanite itself is now well established to be a characteristic of such sediments when subjected to a high grade of thermo-metamorphism. If such, however, be the origin of type C, then types A and B, which graduate into it, must be regarded as psammitic sediments, siliceous and felspathic respectively; and type D, the crystalline limestone, may reasonably be looked upon as an impure calcareous deposit. The balance of evidence, therefore, is at least in favour of regarding the rion-granitoid elements of the gneiss as of sedimentary origin.
Relations of the granitoid element
Now the granitoid component is related to the foregoing coin-ponents in seven different modes, arranged here in order of intimacy, the degree of intimacy reached in the last three being very high, and in the last the highest yet known in the study of gneissose rocks. They are: (1) Veining; (2) Flooding and Isolating; (3) Banding; (4) Lenticular Interfelting; (5) Permeation; (6) Granitoid Gneiss; (7) Gneissoid Granite. But it must be understood that these modes are not sharply separable; they merge gradually into one another, more than one being present in most portions of the gneiss.
(1) Veining, in the sense of granitoid strings of small width cutting the Gneisses at high angles, is quite subordinate. (2) Flooding and isolating by well-defined streams and sills of granite or pegmatite with sharp edges (the usual relation of the Coedana granite to the hornfels) is also subordinate. Good examples, however, are to be seen at Llandrygarn
The less intimate modes (1) to (4) can be well studied on the coast of the Nebo Inlier, all the modes (the banding at Henblâs, the fourth mode at the crags that overlook the road just south-east of Gwyndy), in the Middle Region, and the advanced modes (5) to (7) at the same crags, and on the great sea-cliffs of the Gader Inlier.
Comparisons and conclusions
The phenomena of these granitoid gneisses must, like those of the hornblende-gneiss, have recalled to the reader certain districts in the Scottish Highlands. But the parallel in this case is not so much with the Lewisian gneiss (except, to some extent, the district between Cape Wrath and Laxford<ref>'Geology of the North-West Highlands' (Mem.. Geol. Surv.), pp. 103–125.</ref>, as with the Forfarshire country described by Mr. Barrow<ref>Quart. Journ. Geol. Soc., 1893, p. 330.</ref>, and the parts of Eastern Sutherland described by Dr. Horne and the present writer<ref>Quart. Journ. Geol. Soc., 1896, p. 633 (on work ending in 1895).</ref>, whose description has been extended by Dr. Crampton and others in the Annual Summaries of the Geological Survey from 1909 onwards. The behaviour of the granites is the same throughout, but the parallel with Eastern Sutherland is much more complete than with Forfarshire, for the great orthoclase pegmatites and the zones of kyanite and staurolite have not been identified in Sutherland or Anglesey. The resemblance to Eastern Sutherland, indeed, is extremely close. There are certain differences. Independent foliation in the granite, rare but present in Eastern Sutherland (op. cit., p. 644,
Foliation
The varying developments of this have been described under the head of the petrology of the different members of the Mona Complex. In crystalline character there is the widest possible range, embracing almost all grades, from the faintest signs of anamorphic reconstruction to the permeation-structures of the deep-seated granitoid gneisses and gneissoid granites. Of the various types of crystalloblastic<ref>The terminology of Grubenmann wears, it must be confessed, a somewhat ponderous, not to say grim-visaged aspect Yet it is the only one that has been devised as a systematic expression of the textures of the crystalline schists, and has therefore been adopted in this book. We may hope that a petrologist who is also a classical scholar may some day devise one that is a little less formidable.</ref> texture, the leading ones, granoblastic, lepidoblastic, and nemablastic, are all widely developed; and of the special types, the poikiloblastic, diablastic, porphyroblastic, and encarsioblastic, are often to be seen. Of relict- or palimpsest-structures, the igneous rocks in various stages of incorporation yield blastogranitic, blastophitic, and blastoporphyric; and the sedimentary rocks in like manner the blastopsephitic, blastopsam-mitic, and blastopelitic textures, corresponding ones being yielded by the pyroclastic rocks. What may, perhaps, be called blasto-venous textures result from the incorporation of the quartz and quartz-albite venous sills.
The various grades of anarnorphic reconstruction are distributed in an involved and, apparently, capricious manner, but really according to definite laws. Those laws cannot, however, be discussed with advantage until after discussion of the tectonics and the stratigraphy. They will, therefore, be found on pp. 237–241.
General mineral characters of The Mona Complex
A short study of its minerals will serve to bring out certain characters that attach to the Complex considered as a whole, some of which are common to its igneous and to its sedimentary members, and have influenced the subsequent history of the whole region. Comparisons and contrasts with other foliated complices will doubtless be suggested by them.
The minerals identified are as follows: quartz; the felspars orthoclase, microcline, albite, albite-oligoclase, oligoclase, andesine-labradorite, and labradorite; the micas muscovite, paragonite, seri-cite, green biotite, biotite, and haughtonite; the amphiboles dark-green hornblende, blue-green hornblende, pale hornblende and actinolite, tremolite, asbestos, and glaucophane; the pyroxenes enstatite, augite, diallage, colourless and green diopside; serpentine, chrysotile, bastite, antigorite, brucite, and talc; the chlorites penninite, clinochlore, and delessite; the carbonates calcite, dolomite, and rhodochrosite; the iron-ores pyrite, magnetite, picotite, chromite, hematite, and ilmenite; the other titanium minerals perofskite, sphene, leucoxene, rutile, and anatase; the epidotes pistazite, pale epidote, orthite (?), and piedmontite; zoisite; natro-lite; tourmaline, xanthophyllite-chloritoid, andalusite, sillimanite; zircon, apatite, graphite, axinite, forsterite, spinel, garnet, and idocrase.
The Felspars — Now, the most salient fact in the composition of the Mona Complex is the extraordinary predominance of albite-felspar. Orthoclase is hardly known outside the Coedana granite and its hornfelses; microcline outside the less altered parts of the Penmynydd mica-schists; andesine-labradorite is known only in the basic intrusions of Caerau; labradorite only in a few cores of the albite-diabases; oligoclase is a component of the biotite-gneisses. In all these rocks, moreover, there is also an abundance of albite, especially in the Gneisses. But in every other member of the Complex, acid or basic, igneous or sedimentary, original or metamorphic, which contains a felspar at all, the felspar is albite. And as many of the grits and mica-schists are highly felspathic, the quantity of albite must be enormous; and the Complex must therefore be in great measure a sodium-complex. Idiotnorphic albite is known only in the undeformed parts of the spilitic lavas and their suite. The long history of some of the felspars is shown by the fact that the albite of the spilitic suite can often be seen to be secondary after a basic felspar which has decomposed, and that therefore, where reconstructed in anamorphic schists, it has become a ternary albite. Some degree of decomposition is commonly found in the felspars of the Complex, and it is usually of the micaceous type rather than the kaolinous. Its disposal in the grains is of interest. In the granites and in all the Gneisses it proceeds inwards from the periphery, so that fresh felspar tends to survive as cores in the interior. In the blastopsainmitic schists the reverse is the case, the core being full of decomposition-products and the margin fresh though in optical continuity. (
The Micas — The white-micas of the Complex also reflect its alkaline composition, but in a different way. In several cases, where the only abundant alkali-minerals are a felspar and a mica, it has been possible to show (pp. 45, 49, 112, 135) that the mica must be muscovite, because analysis of the rock reveals a considerable proportion of potassium, which cannot have been yielded by the felspar, that being albite. In some of the Penmynydd mica-schists it can be further shown that this muscovite is a product of the reconstruction of microcline, for that felspar disappears as the muscovite develops. Albite is evidently far more stable than orthoclase under dynamic metamorphism, and reconstructs itself as new albite. Yet paragonite has been produced. It has been proved in the glaucophane-epidote-schist, a rock in which there is still a little albite, and is probably much more plentiful elsewhere than is as yet known. In the clastic schists, the decomposition-products of the felspars are now largely represented by minute flakes Of a white mica, which, as the felspar is albite, may be safely regarded as paragonite. Para-gonite in this form is widely diffused throughout the Complex. Very likely much of the sericite ' may be paragonite, but the contact-micas of the hornfels must be chiefly muscovite. Brown biotite seems to be nearly confined to the Penmynydd mica-schists (where it is not abundant), the granites, the hornblende-gneisses, and the biotite-gneisses. In the last it has been shown to be haughtonite. It is often chloritised, and the great separation of leucoxene and rutile that then takes place shows that it was highly titaniferous. Its remarkable bleaching in the biotite-gneisses, where it often simulates a muscovite, has been described. A much more unusual mica is the grass-green biotite of the New Harbour Beds, of which a chemical analysis is much to be desired. It shows a tendency, in the South Stack Series, to development along with muscovite in compound encarsioblasts.
The Amphiboles — The strongly coloured amphiboles belong essentially to the Penmynydd Zone and the Gneisses, those of the gneiss having a stronger pleochroism and a broader habit. Pale green ones appear in the contact-aureoles of the Coedana granite and the serpentine, still paler ones in the schistose gabbro, and the colourless calcareous tremolite is essentially the amphibole of the ophicalcites. The great, and for Britain unique, development of glaucophane in the Penmynydd Zone is yet another product of the high sodium-content of the Complex.
Pyroxenes, doubtless plentiful in the original basic rocks, have now a restricted distribution. Augite is known only in the spilitic suite and in the sub-gabbroid sills of Caerau; enstatite and diallage only in the gabbros, pyroxenites, and some of the serpentines. A little green diopside exists in the hornblende-gneiss, and a colourless diopside is abundant in the fosterite-limestone.
Olivine has not been found unaltered, but its products, among which is talc, are abundant in the serpentine-suite. Forsterite has been identified in a cipolino of the gneiss.
Iron-ores and Titanium — Among the iron-ores; pyrite is known as a mineral of allomorphic foliation, and micaceous laumatite is quite a character of the Penmynydd Zone, both in acid and in basic schists, but the haematite of the jaspers is flocculent. Magnetite is probably not very abundant, for inspection in reflected light reveals that very much, perhaps the greater part of the opaque iron-ore has a brownish tinge, shows frequent alteration into leucoxene, and must therefore be ilmenite. Connected with this is the abundance of sphene in many rocks, especially in the green-mica-schists of Holy Isle, in parts of the Pemnynydd Zone, and in the hornblende-gneiss, where it attains to the rank of an essential and develops crystals of unusual size
Epidotes are widely distributed, both in igneous and sedimentary material. Some are post-metamorphic, and may be quite recent, but the great majority are true minerals of anamorphism. They are abundant and well crystallised in such rocks as the New Harbour Beds and the Penmynydd mica-schists, the amphibolic schists derived from the spilitic lavas, the hornblende- and especially the glaucophane-schist, in some of the hornblende-gneisses, and in the epidote-hornfelses of the granite and the serpentine; but on a smaller scale and more poorly crystallised in the less reconstructed rocks like most of the Gwna Beds, from which their anamorphic origin is evident. Typical pistazite graduates into varieties with low bi-refringence, sometimes without loss of the lemon-yellow tint and pleochroism. The discovery of piedmontite in the Green-mica-schists is of great interest, and it is to be hoped that more and better crystals will be found. Zoisite, recognised by its uniform low bi-refringence, and characteristic interference-tints of clear indigo-blue, usually accompanies the epidotes where the rocks are well re-crystallised, whether they be sedimentary or igneous. But it is especially a mineral of the Penmynydd Zone of metamorphism, where it is abundant in some varieties of mica-schist, but still more so in the amphibolites of the Aberffraw coast and the hornblende-schists of Gwalchmai. In these it seems to be al ways a clino-zoisite with the optic-axial plane transverse to the prism.
Various acecessories— Zircon is frequent in various rocks, but in moderate quantity. Apatite is abundant in the Penmynydd Zone, and still more in the Gneisses. Spinel has been identified in a limestone of the gneiss. Axinit-e in a vein in the spilitic lava. Graphite in a thin phyllite and mica-schist of the Gwna Beds and the Penmynydd Zone. Tourmaline (an accessory in many rocks) is especially developed in the hornfels of the Coedana granite, in which andalusite also has been found. Xanthophyllite occurs in the same hornfels, and also in graphite-schist of the adjacent part of the Penmynydd Zone, always as an encarsioblast. Garnet, small and idiomorphic, is found in the Penmynydd Zone; large, allotriomorphic, and much decomposed, is often abundant io the Gneisses, accompanied sometimes by green idocrase.
Sillimanite is known for certain only in the gneiss
The Carbonates calcite and dolomite, present everywhere as decomposition-products, form considerable masses of rock in the Gwna Beds, where they are often tinged with rhodochrosite. In the Penmynydd Zone and in the gneiss they are re-crystallised along with high-temperature minerals as cipolini, and the same is the case, also, in the ophicalcites.
Quartz-veins are only a subordinate feature, but venous quartz in lenticular augen is developed on an enormous scale in the Gwna Green-schist and in the Penmynydd Zone.
Green Tint and the Chlorites — No character of the Mona Complex can be more striking to the most superficial observation than its persistent pale-green colour. The extensive Gwna Beds, the Church Bay Tuffs and Skerries Grits, the Amlwch Beds, the Coeden beds, the New Harbour Beds, and, to a less degree, the South Stack Series, the Penmynydd schists, the Hornfelses, and even the Gneisses and the Coedana granite, are all inure or less pervaded by this pale green colouration. Now in all these great formations, except the New Harbour Beds and the South Stack Series, which are coloured by a green biotite, the green colouring matter is a chlorite. Looked upon usually as mere decomposition products, and suffering from somewhat indefinite optical properties, chlorites are apt to receive scant attention from petrologists; but it is evident that in this complex they must have no small physical significance and be worthy of a closer study. And it soon becomes clear that they have not all been produced in the same manner. Some are decomposition products, but others are true minerals of anamorphism, and are thus respectively products of destruction and of reconstruction. They may be distinguished as 'chlorite of catamorphic dissolution' and 'chlorite of anamorphic evolution'. The first of these can be recognised in the usual way. The chlorite of the undeformed parts of the spilitic lavas is after augite, that of the Gneisses, of the granites, of the hornfels, of the parts of the Penmynydd Zone that adjoin the latter, is for the most part after biotite, partly after hornblende. These, then, are chlorites of dissolution. But consider such a rock as the Gwna Green-schist. It is in a very early stage of reconstruction, minute white mica being the only new mineral that accompanies the chlorite. There is not, nor ever can have been (for in the autoclastic mélange the almost raw material is still preserved to us), any crystalline mineral after which this chlorite can be a product of dissolution. The original ferro-magnesian matter was probably a sprinkling of pyroxenie dust or glass of spilite, which would have decomposed very soon after the deposition of the beds. This chlorite was therefore produced in the early stages of dynamic reconstruction, and is a chlorite of ana-morphic evolution. So is that of the Amlwch and other northern rocks, only the evolution has proceeded further, so that both it and the white mica are more distinctly crystallised. Consider now the passage from the Gwna Green-schist into the Penmynydd Zone, which we have already seen (pp. 124–6) to be an anamorphic evolution. In the Penmynydd mica-schist we find a chlorite in much larger, better-formed flakes (or rather plates), clear green, intergrown with the muscovite, with no sign of being a pseudo-morph after any other mineral. It is a chlorite of evolution, the most perfect known in the Complex. In the most advanced stages of the Penmynydd Zone a biotite appears. Van Elise has expressed the opinion<ref>'A Treatise on Metamorphism', p. 369.</ref> that 'the equations which represent the reactions in the zone of catamorphism are reversible in the zone of anamorphism'. We have, accordingly, a chlorite of dissolution replacing a biotite of evolution, and a chlorite of evolution replaced by a biotite of evolution.
In geological time, however, the chlorite of dissolution is vastly later than that of evolution. Some of it may possibly be as old as the later movements of the Mona Complex, some may be due to Ordovician destructive movements, some may be as late as Tertiary erosion. In the parts of the Penmynydd Zone where biotite is beginning to appear and yet (long afterwards) has become chloritised, chlorites of both origins must occur in the same rock, a conjunction that may be looked for along lines running northeast and south-west through Gaerwen Church and Porth Tre-castell respectively<ref>A slide from near Gaerwen (E9919)
The chief special idiosyncrasies of the Mona Complex are therefore: its high sodium-content, expressed in albite, paragonite, and glaucophane; its high titanium-content, expressed in ilmenite, sphene, leucoxene, and rutile; and its persistent green colour, due chiefly to the great abundance of chlorite of anamorphic evolution.