Anderson, F.W. and Dunham, K.C. 1966. The geology of Northern Skye
Chapter 9 The petrography of the minor intrusions
History of research
The intrusive nature of the numerous basaltic sheets which occur within the Jurassic rocks wherever they are exposed beneath the lava plateau of Skye was first conclusively demonstrated by Macculloch (1819). Geikie (1897, p. 305) remarked that the east coast of the island, especially the stretch from Loch Sligachan to Rubha Hunish 'has been classic ground for this part of volcanic geology since it supplied the materials for Macculloch's descriptions and diagrams'. The sills of Trotternish have nevertheless not received from petrographers the attention that might have beeen expected.
Geikie identified the rocks of the sills as 'somewhat largely crystalline ophitic dolerites, gabbros or diabases' and stated that they exhibit a persistent uniformity of composition and structure characteristic of sills and dykes. He added that the sills probably continue north of Skye beneath the sea, for at least twelve miles, since sills of the same type form the Shiant Isles, where on Garbh Eilean the great northern cliff exhibits a single sheet over 500 ft thick. Judd (1885) visited the Shiant Isles and found that in addition to ophitic dolerite and gabbro, an ultrabasic type which he named dunite was present. Geikie was unable to find this rock in situ but remarked that it probably occurs at the base of some of the sills, where it has segregated from the rest of the mass. Notwithstanding his earlier statement, Geikie was impressed with the considerable variety in texture displayed by the Shiant sills (Geikie 1897, p. 309).
Modem petrographical study of the sills may be said to have begun with F. Walker's (1930) investigation of the Shiant Isles and since this and subsequent work offers strong support for Geikie's contention that the system of sills here is, or was, continuous with that of Trotternish, this work is germane to the present account. Walker found, at the base of the Garbh Eilean sill, a layer of picrite with 50–75 per cent olivine, which gives place to dolerite rich in olivine 15 ft above the beach; this in turn is transitional into crinanite at 45 ft above the beach. The sill is evidently an upper leaf of the system, for a lower leaf appears beneath the ledge of Whitbian strata on which it rests. The separation of the picrite was ascribed by Walker to gravitational differentiation by sinking of the olivine crystals. In addition to the picrite-crinanite series, he also recognized pegmatitic and syenitic segregations. Subsequently Walker (1931) investigated the small islands between the Shiants and Trotternish, Fladda-chuain, Gaeilavore, Gearran, An Bord, the three Skerries and Trodday, all of which lie within the area shown on the one-inch Rubha Hunish (90) Sheet. All expose alkali olivinedolerites and related rocks. Finally he investigated the north Trotternish sills (Walker 1932) demonstrating the existence of picritic types W. of Kilmaluag Bay, at Druim na Slochd, at Creag na-h-Eiginn and in the cliff at Meall Tuath. In all these cases, dolerite overlies picritic dolerite or picrite. Gravitational differentiation was advocated for some of them but intrusion of viscous picrite, crowded with olivine crystals was also envisaged (Walker 1932, p. 252) to account for the exposures W. of Kilmaluag Bay.
Interest in the Shiant sills has been revived by H. I. Dreyer (1953) and his associates. A new traverse of the difficult face of Garbh Eilean has revealed an abrupt contact between picrite and picrodolerite, defined by a thin layer with very small olivine granules, a little interstitial plagioclase and no clinopyroxene. The picrodolerite passes gradually upwards into crinanite. Detailed studies of the olivines (Johnston, 1953) and of the clinopyroxenes (Murray 1954) from the rocks on this traverse have yielded very interesting results; the olivines develop highly fayalitic outer zones in the upper part of the sill, while a limited upward enrichment in iron is displayed by the pyroxenes.
Harker's (1904) memoir contains descriptions of a few of the dykes within the present area but as the primary survey of the Portree (80) and Rubha Hunish (90) sheets had not been made, his account is necessarily incomplete.
Petrography of the sills
This account is concerned solely with the sills intruded into the Jurassic sediments, except for three inclined sheets exposed in Oisgill Bay, which penetrate the lavas, but which are believed to be connected with the sills exposed nearby in the sediments. As already noted, Harker's 'Great Group of Sills' (Harker 1904, pp. 235–54) are now considered to be the central columnar portions of lavas.
The sills in the Jurassic sediments, although they occupy various strati-graphical horizons from the Middle Lias to the Kimineridgian, are linked together and were most probably produced by a single pulse of magma, or a series of pulses close together in time, since (except at Oisgill Bay) clear evidence of chilled internal contacts have not been discovered. The variants may well have developed from a single magma, within the spaces now occupied by the sills.
Although the sills with their boldly columnar outcrops present an appearance of uniformity, detailed examination reveals considerable textural and mineralogical variation. The following types will be recognized for purposes of petrographical description: (1) normal olivine-dolerite, (2) marginal tachylitic and basaltic modifications, (3) picrodolerite, (4) crinanitic and teschenitic variants, (5) pegmatic dolerite.
Olivine-dolerite
The constituent minerals are forsteritic olivine, diopsidic augite, moderately calcic plagioclase, titanomagnetite and very small amounts of zeolites, particularly analcime and thomsonite. The rock in hand-specimen is dark grey, with the grain-size usually just sufficient to reveal to the naked eye that rounded olivines and tabular feldspars are present in a "doleritic" texture. Weathering imparts a dull reddish-brown or dirty grey skin.
The olivine is rounded to subautomorphic but it never shows sharply-developed crystal faces. It ranges from about 0.2 to 2.0 mm in diameter; occasionally a tabular tendency, parallel to (010) can be detected. In thin section it is invariably colourless in all the dolerites investigated. Yellowish-brown fayalitic varieties similar to those in the upper part of the Garbh Eilean sill, which were first noticed by Walker (1930, p. 366); commented on by Tilley in the discussion on this paper, and fully investigated by Johnston (1953), who found that they range up to Fa95 have not been discovered in any of the Trotternish rocks. Refractive index measurements indicate a range of composition from Fa18 to Fa24, with some indication of very thin outer zones a little richer in iron orthosilicate. Most olivines enclose one or two tiny magnetite octahedra.
The olivine has nowhere been found to enclose feldspar as at Garbh Eilean (Johnston, 1953); its crystallization here seems to have been completed before that of feldspar began.
The plagioclase is tabular parallel to (010) but shows no preferred orientation. The mesh of thin platy crystals imparts the characteristic doleritic texture to the rock. The maximum length of the feldspar is about 2.0 mm in the coarsest varieties of the normal olivine-dolerite; but the range of sizes is considerable, and not every thin section shows an average length of feldspars over 0.5 mm (the lower limit for dolerite sensu stricto adopted here). Albite and Carlsbad seem to be the dominant, though not the only twin laws. The maximum anorthite content recorded here is An76 (from refractive index and Albite-Carlsbad extinction measurements; this may be compared with An80 in the Shiant Sills). Normal composition zoning without reversals is the rule, and compositions down to An32 have been found. The mean feldspar composition cannot be estimated from microscopic observation but the normative figure derived from a chemical analysis (p. 148) is Or7Ab37An56.
No orthopyroxene and no evidence of pigeonitic clinopyroxene (of low 2V) has been found in these rocks. The pyroxene is augite, preserving a characteristic pale biscuit colour in every thin section, and forming xenomorphic crystals commonly up to 4 mm x 2.5 mm, but sometimes exceeding over 10 mm in length. In composition it is a diopsidic augite, and though Murray's analyses of pyroxenes with similar optical properties in the Shiant crinanite showed 124 to 1.33 per cent of TiO2 no distinct purple colour such as is found in the pyroxenes of some alkali olivine-dolerites was noted.
The titanomagnetite is automorphic or hypautomorphic, but it is a later mineral which sometimes had wrapped itself around the feldspars. There is some reason to believe that it may have developed its crystal faces by replacement of adjacent minerals, and the possibility that the opaque octahedra in the olivines are really of later crystallization than the olivines is worthy of consideration. A little apatite occurs.
Zeolites, though occasionally present, are minor constituents only of the normal dolerites. Pale brown or colourless analcime, and fibroradiate thomsonite are sometimes found in interstitial positions.
Excellent examples of the normal dolerites in the Geological Survey collection come from near the LochMealt waterfall (S33486)
Alteration in these rocks is usually confined to partial conversion of olivine into chlorite or bowlingite. It is interesting to note that although on the average the dimensions of the olivines in the rocks of the sills are similar to those of the phenocrysts of this mineral in the olivine-basalts of the lava-pile (see p. 105), the plagioclase and the augites are decidedly coarser in the sills. The exception to this rule is provided by the Vaternish-type lavas where both these minerals exceed in average dimensions their counterparts in the sills (p. 111).
Marginal types. In spite of the excellence of the exposures of the sills in N. Trotternish, fresh material at or near their contacts with the enclosing rocks is not easy to obtain. At Oisgill Bay, the 3-inch chilled rock at the base of the northern inclined sheet (S38068)
In the case of the thicker sills, the rock may remain holocrystalline right up to the contact. Slices across the top contact of the lower sill at Rubha Hunish (S38028)
At the Loch Mealt waterfall, the lowest specimen (S33483)
The implication of these observations is that olivine and calcic plagioclase were already present as crystals when the magma was intruded. No olivine, however, as coarse as that in the central parts of the dolerite and picrodolerite has been found in the marginal rocks, so that it appears that olivine continued to separate after intrusion.
Picrodolerite
The sills exhibit regions of profound enrichment in olivine, where the rock-type approaches an ultrabasic composition. Walker (1932) has used the terms picrite-dolerite for those rocks from the North Skye sills with 20–50 per cent olivine, and picrite for those with 50–70 per cent. It might be objected that the original picrite of Tschermak (1866) was an olivine-teschenite, in which the calcium and aluminium are mainly combined in analcime, whereas the present rocks always contain an appreciable feldspar content. However, picrite is a term well established in Scottish petrography for the olivine-rich differentiates of alkali dolerites. Few of the slices in the Geological Survey collection show as much as 50 per cent olivine, and it is considered that the term picrodolerite, recently applied by Dreyer (1953) to the rocks above the picrite on Garbh Eilean, adequately covers most if not all the olivine-enriched rocks of Trotternish.
The Meall Tuath cliff at Rubha Hunish has already been mentioned as exhibiting a picritic layer, with dolerite below and above. This has been investigated in more detail by collecting at 10-ft vertical intervals up the chimney which transects the cliff, starting from the lowest exposure above the scree and continuing, with a 30-ft break, to the cliff top. Unfortunately the bottom contact of the upper sill is not exposed but the lowest specimen is believed to be within 20 ft of the base. The results of modal analyses of the suite (S46734)
As the olivine dies out above the picrodolerite level, a significant change in the texture as well as the composition of the rock occurs. The feldspar becomes coarser, the maximum length of the crystals increasing to 1.0 mm. The augite not only becomes more abundant, but over a restricted range represented by the specimens from 150 to 160 ft (S46749)
The upper sill at Rubha Hunish thus shows three zones, transitional into one another: (1) normal olivine-dolerite at the bottom, probably 40 ft thick; (2) picrodolerite, 120 ft thick if the dividing line is placed at 20 per cent olivine; (3) non-olivine bearing dolerite, succeeded upward by dolerite with only insignificant amounts of olivine (now pseudomorphed in chlorite), at least 140 ft thick.
Discussion of the place and mechanism of olivine concentration will be deferred to the next chapter.
Other examples of sliced picrodolerites come from N. of Kilmuir Church Yard (S31331)
Crinanitic and teschenitic dolerites
Another cause of variation in the texture and composition of the sill rocks is the substantial fluctuation in the content of zeolites, especially analcime and thomsonite. Zeolites are normally present in amounts of 2–3 per cent in the olivine-dolerite and picrodolerites; but when this amount is substantially exceeded, the rocks pass into categories to which the terms crinanite and teschenite have been applied elsewhere in Scotland.
Crinanite was defined by Flett (1909) as a rock transitional between camptonite and dolerite rich in analcime. In an extended definition (Flett in Cunningham Craig and others 1911, pp. 42–3) he stated:
'The crinanites… are dark-coloured fine-grained basic rocks… consisting mainly of olivine, augite and plagioclase felspar, with a considerable amount of analcite and zeolites. Olivine is abundant in small grains… The augite is always purple… but the depth of colour varies in different crystals… The augite has a marked dispersion of one of the optic axes and shows hour-glass and zonal structures… The felspar… belongs mostly to labradorite, though the outer zones are more rich in soda… The iron oxides form irregular plates often fringed with scales of dark brown biotite. Most of these rocks have very perfect ophitic structure… Perfectly transparent analcite is not uncommon, but often this mineral is turbid and granular with weak double refraction. The radiate zeolite appears to be mostly natrolite… The crinanites [occur] as narrow vertical dykes… '
Although the original definition was extended by G. W. Tyrrell (1928) to cover the much coarser rocks of the four large sills in south-central Arran, it does not appear that the zeolite-bearing rocks of North Skye can properly be described as crinanites within its strict terms; they are not only coarser than the type rocks, but they are not dyke rocks, their pyroxenes are not appreciably purple and they do not carry biotite.
It is therefore proposed to describe as crinanitic dolerites those rocks in the Trotternish sills which contain over 3 per cent zeolites occurring in an intersertal relationship with feldspar, or filling subvesicular spaces. Good examples come from the lower sill at Rubha Hunish (S38026)
The same is true of the teschenitic variety. This is distinguished from the crinanitic type by the fact, well brought out in Walker's (1923) definition, that the plagioclase is partly or wholly replaced by analcime. This criterion has been accepted very generally in British petrographic nomenclature. The analcime, sometimes accompanied by other zeolites, here shows evidence of a hydrothermal role. Patches of teschenitic dolerite occur in the North Skye sills, for example on Ben Volovaig (S33616)
Pegmatitic dolerite
In the small islands of the North Minch, Walker (1931) identified bands of coarse gabbroid material traversing the normal dolerite, showing unchilled margins and interlocking junctions with the normal rock. Similar bands have been found 500 yd N.N.E. of Flora Macdonald's grave (S32704)
N | 0 | P | Q | R | S | T | U | |
SiO2 | 40.47 | 40.62 | 45.07 | 46.97 | 47.51 | 47.83 | 43.49 | 50.04 |
Al2O3 | 5.96 | 8.93 | 14.43 | 15.00 | 17.28 | 15.31 | 14.57 | 14.27 |
Fe2O3 | 2.10 | 0.57 | 0.80 | 1.71 | 3.56 | 1.15 | 5.62 | 3.76 |
FeO | 12.32 | 12.61 | 10.69 | 8.94 | 5.77 | 9.22 | 7.40 | 6.33 |
MgO | 29.32 | 26.31 | 14.61 | 10.52 | 5.98 | 6.60 | 5.32 | 5.99 |
CaO | 4.91 | 5.64 | 9.74 | 10.70 | 11.47 | 12.38 | 11.61 | 12.11 |
Na2O | 1.18 | 1.32 | 1.75 | 2.18 | 2.60 | 2.53 | 2.92 | 3.41 |
K2O | 0.40 | 0.13 | 0.34 | 0.63 | 0.79 | 0.40 | 0.92 | 0.83 |
H20+ | 1.12 | 2.19 | 1.05 | 0.38 | 1.40 | 1.28 | 3.58 | 0.79 |
H20− | 0.59 | 0.61 | 0.35 | 0.63 | 1.30 | 0.28 | 1.39 | 0.40 |
TiO2 | 1.50 | 0.82 | 0.83 | 1.59 | 1.80 | 2.86 | 2.95 | 1.89 |
P2O5 | 0.26 | 0.15 | 0.10 | 0.12 | 0.12 | 0.16 | 0.40 | 0.24 |
MnO | 0.23 | 0.39 | 0.33 | 0.37 | 0.13 | 0.36 | 0.12 | 0.28 |
BaO | — | — | 0.01 | — | — | — | — | — |
CoO NiO | — | 0.03 | 0.02 | — | — | 0.02 | — | — |
CO2 | — | 0.03 | 0.02 | — | — | 0.05 | — | — |
Cl | — | 0.01 | - | — | — | 0.01 | — | — |
100.36 | 100.36 | 100.14 | 99.72 | 99.71 | 100.44 | 100.29 | 100.34 |
N. Picrite, top of cliff W. of Camas Mor; analyst N. Sahlbom in Walker 1932, p. 247.
O. Picrite, S. face of Garbh Eilean, Shiant Is., by the shingle beach; analyst E. G. Radley in Walker 1930, pp. 371–2.
P. Olivine-dolerite (picrodolerite of present account), Garbh Eilean 30 ft above the beach; analyst E. G. Radley in Walker 1930, pp. 371–2.
Q. Olivine-dolerite ("normal dolerite"), just S. of mid-point of S.W. shore. Fladda-chuain, analyst N. Sahlbom in Walker 1931, p. 757.
R. Olivine-dolerite ("normal dolerite"), Loch Mealt near Waterfall, 80 ft above lower contact; analyst, N. Sahlbom in Walker 1932, p. 245.
S. Crinanite, Garbh Eilean, 125 ft above the beach; analyst, E. G. Radley, in Walker 1930, pp. 371–2.
T. Teschenite, Ben Volovaig, half way up slope; analyst, N. Sahlbom in Walker 1932, p. 249.
U. Pegmatitic dolerite, Fladda-chuain, N. end; analyst N. Sahlbom in Walker 1931, p. 760.
Chemical composition
All the variants described are adequately represented by chemical analyses published by F. Walker (1931) and it has not been considered necessary to undertake further rock analyses apart from the magnesia and lime determinations for the 20 rocks of the Meall Tuath suite
Norms | N | O | P | Q | R | S | T | U |
or | 2.2 | 0.6 | 1.7 | 3.3 | 4.5 | 2.2 | 5.6 | 5.0 |
ab | 4.7 | 3.3 | 14.7 | 17.8 | 22.0 | 21.0 | 19.2 | 28.8 |
an | 10.0 | 20.8 | 30.6 | 29.8 | 33.4 | 29.5 | 23.9 | 20.9 |
ne | 2.8 | 4.1 | — | — | — | — | 2.7 | - |
di | 9.9 | 5.7 | 13.5 | 18.2 | 18.5 | 25.4 | 24.7 | 29.6 |
by | — | 0.8 | 5.9 | 7.8 | 6.2 | — | 7.6 | |
of | 62.3 | 61.5 | 33.9 | 17.8 | 22 | 7.1 | 4.1 | 3.3 |
it | 29 | 1.5 | 1.5 | 3.0 | 3.5 | 5.5 | 5.6 | 3.7 |
mt | 3.0 | 0.6 | 1.2 | 2.6 | 5.1 | 1.9 | 8.1 | 5.3 |
op | 0.7 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 1.0 | 0.4 |
Normative Or | 4 | 6 | 7 | 4 | 9 | |||
Plagioclase Ab | 31 | 35 | 37 | 40 | 53 | |||
An | 65 | 59 | 56 | 56 | 38 | |||
Modes | ||||||||
Olivine | 66 | 59* | 31* | 18 | 9½ | 12* | 7½ | — |
Augite | 14 | 10 | 17 | 23 | 23½ | 24 | 22 | 27½ |
Plagioclase | 17½ | 26 | 50 | 51½ | 60½ | 60 | 46 | 52½ |
Titanomagnetite | 2½ | 2 | 2 | 6½ | 5 | 3 | 11½ | 8 |
Zeolites- | — | 3 | — | 1 | 1½ | 1 | 12 | 12 |
Apatite- | — | — | — | — | — | — | — | — |
* It is not certain that these correspond with the analysed specimens though they are from the same localities.
Petrography of the dykes
General. Of the very numerous dykes exposed in the area of the Portree and Rubha Hunish (90) sheets, a total of 177 have been sliced. Although this number cannot be regarded as a true sample, the distribution of rock-types, summarized in
Rock-Type | On One-inch map | No. of Slices |
Normal olivine-dolerite and basalt | KT) | 21 |
Normal crinanitic variants | Kc | 43 |
Picritic dolerite [Picrite on map] | fU° | 7 |
Mugearite, including feldspar-phyric types | XM | 12 |
Variolite | vK | 6 |
Leidleite | pL | 1 |
Trachyte | OT | 1 |
Feldspar-phyric dolerite and basalt, including crinanitic variants [Dolerite, basalt or Tholeite (un- classed)] | KD | 32 |
Allivalite, olivine-eucrite [E'gabbroic (unclassed)] | UA, Eʹ | 15 |
Tholeiitic dolerite and basalt | KT | 29 |
Tholeiitic feldspar-phyric dolerite and basalt | KT | 13 |
As already noted in the account of field relations, many of the dykes are of compositions similar to the lavas exposed in the same part of the island. This applies to some of the olivine-dolerites and basalts, which include olivine-phyric types; to the mugearites and the trachytes, and to a few of the feldspar-phyric dolerites and basalts, in which the feldspar phenocrysts are no more calcic than labradorite. On the other hand, the bulk of the feldspar-phyric dykes carry calcic bytownite or anorthite phenocrysts, and these rock types are not known to be represented among the lavas; the 'big-feldspar' mugearite lavas contain phenocrysts of labradorite composition. No lavas corresponding to the allivalites or olivine-eucrites are known, and this fact makes it difficult to believe that these curious lenticular dykes or pods acted as volcanic vents. The sliced rocks from North Skye include no lavas as olivine-rich as the picritic dykes, though one lava described by D. Almond (1964) from Strathaird compares with them. These dykes may well represent injections of olivine-cumulus from the sill system. The tholeiitic types, which carry little or no olivine and contain an intersertal mesostasis that may, at an earlier stage, have been glass, are likewise not represented among the lavas save by the pillow-lava of Creag Mor (p. 102). It is very noticeable that not a single quartz-dolerite has been found in North Skye, and the supposed tholeiites fail to reveal any examples comparable with the silica-rich Talaidh and Brunton types of Mull (Bailey and others 1924, pp. 301, 372). The situation in Skye generally is that rock-types referable to the tholeiitic lineage are very much rarer than in Mull, if indeed, they exist at all in significant quantities.
Normal olivine-dolerite and basalt
It has already been noted that the lavas include a class of dolerites (with the average length of the feldspar tablets greater than 0.5 mm) as well as basalts, but that there is no evidence of major differences in composition between the two types. In the case of the dykes, rocks which are texturally dolerites are somewhat commoner than basalts, but both occur in the suite and the artificial nature of the distinction is again evident.
Another comparative point of some interest is that whereas ophitic crystallization of the augite is very widespread both in the lavas and the sills, in the dykes the intergranular texture is commoner. Here small crystals of clinopyroxene sometimes showing crystal faces, nestle in the interstices of the mesh of feldspars. Good examples include (S31453)
The olivines in these dykes are usually rounded, as in the lavas and sills, though occasionally tabular, automorphic forms appear (e.g. (S31965)
The feldspar mesh is made up of zoned crystals in which the bulk composition lies within the labradorite range. Occasionally the centres are more calcic and usually there are thin marginal zones of andesine or even oligoclase.
The clinopyroxene is usually pale-coloured in thin section, not colourless when compared with olivine, yet with no well defined tint beyond a vague grey or pale brown in most cases. A few examples, however, show definite purple colouration and faint pleochroism e.g. (S31974)
The crystallization in the normal types is completed by the titanomagnetite, often automorphic or skeletal in outline, and no mesostasis is present. However, some glass usually occurs close to the contact with the country rock.
Crinanitic variants
In the crinanitic variants, zeolites are present in addition to the minerals described above, but the pyrogenic constituents continue to appear in much the same proportions. True crinanites, dyke rocks corresponding with the definition of Flett cited on p. 146 do occur, but they are rare. Examples include (S31417)
Some of the dykes in this subclass closely resemble the alkali-basalt lavas in that rounded, or in some cases automorphic olivine phenocrysts are present e.g. (S33956)
Other members carry only very small olivine crystals, though often in some abundance (e.g. (S31969)
At the margins of the crinanitic dykes, chilling has caused glass to form. This may be vesicular, with minerals such as thomsonite, analchne, chabazite and chlorite in the vesicles (e.g. (S31347)
Picritic dolerites-picrites
A few olivine-rich dykes of ultrabasic aspect have been found. Both in mineralogy and texture they are virtually identical to the picrite dolerite layers in the Trotternish sills. The olivines range up to 5 mm diameter; typically they are well rounded and a representative example from Breabost Burn, E.N.E. of Dun Flashader (S33981)
Mugearite
In appearance, the mugearite dykes, like the lavas of this composition, are recognizable to the experienced observer by their black colour, very fine grain, their platy fracture (in the dykes it is usually parallel to the walls) and their tendency to form a thin brown or reddish brown crust upon weathering. Under the microscope, they are hardly distinguishable from the lavas. The chief constituents are oligoclase (or more probably potash oligoclase and anorthoclase—see p. 164), tiny augite granules, microphenocrysts of olivine more fayalitic than in the other dyke rocks, and an abundance of tiny octahedra of titanomagnetite. The feldspars range from 0.04 mm (S37732)
None of our sliced specimens is a big-feldspar mugearite, comparable with the Roineval lavas (p. 120) and it is not certain that dykes of this remarkable rock type have been located. Small phenocrysts of composition respectively Ann (S31394)
Probably the best-known example of a mugearite dyke in North Skye is that of Am Bile, exposed 11 miles E.N.E. of Portree. J. W. Judd and G. A. J. Cole (1883) described the two-inch glassy selvedges of this dyke, and cited the following analysis by Hodgkinson: SiO2, 5029; Al2O3, 17.33; Fe2O3, 11.14; MnO, 0.66; CaO, 6.17; MgO, 2.62; Na2O, 4.24; K2O, 2.40; Loss on ignition, 327; Total, 100.72. Harker (1904, pp. 331–2) gave a petrographical description of the mugearite, which in the centre is coarser than that of Druim na Criche (S9373)
Variolite
A small but well defined group of dykes shows characteristics that may be regarded as consistent with the usage of the term variolite as adopted by Harker (1904, p. 347) and the authors of the Mull Memoir (Bailey and others 1924, pp. 150–1) though it should be noted that in Mull these rocks characteristically form the carapaces of pillow lavas. In the field, the dykes are pale grey or bluish-grey, fine-grained, often containing vesicles which may be empty, or filled with zeolites or a black mineraloid. Under the microscope they are found to be dominated by stellate groups or radiating sheaves of fine acicular or platy feldspars, the composition of which, according to their optical properties lies between Anis, and soda anorthoclase. Pyroxenes also occur in the form of thin prisms with an acicular tendency; they are, without exception, augites but their exact position with respect to the iron end of the series has not been determined. Acicular amphiboles also occur in some cases, pale-brown or green (S37724)
Leidleite
A single example of a rock comparable with the stony type of leidleite of the Mull Memoir (Bailey and others 1924, pp. 281–2) found during the field survey was identified by Mr. E. H. Francis. The rock has a pale bluish tint, is fine-grained and is riddled with vesicles most of which are empty, though a few have white mineral linings. In thin section it shows acicular yellow-brown amphiboles, 0.1–0.2 mm long set in a matrix of ill-defined feldspar of feathery rather than tabular form, though in places stellate groupings can be seen. The feldspar is an untwinned alkali type, perhaps anorthoclase. No glass is present. Some vesicles are rimmed with alkali feldspar. The single example (S31747)
Trachyte
Trachyte dykes are poorly represented in the collection from the present area, but as noted above, Harker (1904, p. 58) has already described the Drynoch group in Bracadale Burn. There is little to add; the rocks are very pale grey in the field, and carry sparse visible phenocrysts of augite and biotite. One example, collected 450 yd N.W. of the bridge in Glen Vidigill (S31388)
Feldspar-phyric dolerite and basalt
As
V | XII | Y | Z | |
SiO2 | 47.33 | 44.95 | 48.28 | 47.28 |
Al2O3 | 20.08 | 24.02 | 20.38 | 21.11 |
Fe2O3 | 0.55 | 0.93 | 1.78 | 3.52 |
FeO | 3.24 | 4.07 | 6.70 | 3.91 |
MgO | 12.53 | 9.43 | 7.93 | 8.06 |
CaO | 14.47 | 13.70 | 11.80 | 13.42 |
Na2O | 1.34 | 1.21 | 1.75 | 1.52 |
K2O | 0.07 | 0.11 | 014 | 0.29 |
H2O+ | 0.21 | 1.27 | 0.76 | 0.53 |
H2O− | 0.14 | 0.48 | 0.09 | 0.13 |
TiO2 | 015 | 013 | 0.23 | 0.28 |
P2O5 | tr | 0.02 | 0.02 | tr |
MnO | 0.08 | 0.08 | 0.28 | 0.15 |
CO2 | — | tr | 0.03 | — |
S | — | 0.01 | — | — |
Cr2O3 | 0.18 | 0.05 | — | — |
NiO | — | 0.01 | — | — |
BaO | — | 0.01 | — | — |
SrO | — | 0.02 | — | — |
Li2O | — | nt. fd. | — | — |
FeS2 | — | — | 0.04 | — |
100.37 | 100.50 | 100.21 | 100.20 |
Norms | V | XII | Y | Z | |||||
Or | 0.56 | 0.56 | 0.56 | 1.67 | |||||
ab | 1.32 | 9.96 | 14.67 | 12.58 | |||||
an | 48.93 | 59.77 | 47.54 | 50.04 | |||||
ne | — | — | — | — | |||||
di | wo | 9.55 | 18.09 | 3.48 | 6.64 | 4.52 | 18.77 | 6.96 | 13.32 |
en | 7.26 | 2.50 | 2.80 | 5.20 | |||||
fs | 1.28 | 0.66 | 1.45 | 1.06 | |||||
hy | en | — | 1.80 | 2.46 | 12.60 | 19.46 | 9.70 | 12.08 | |
fs | — | 0.66 | 6.86 | 2.38 | |||||
ol | fo | 16.70 | 19.96 | 13.44 | 17.52 | 3.08 | 5.12 | 3.64 | 4.66 |
fa | 3.26 | 4.08 | 2.04 | 1.02 | |||||
mt | 0.79 | 1.39 | 2.55 | 510 | |||||
it | — | 0.24 | 0.53 | 0.61 | |||||
ap | — | 0.04 | 0.04 | — | |||||
cr | — | 0.06 | — | — | |||||
ca | — | — | 0.07 | — | |||||
py | — | .002 | 0.04 | — | |||||
Plagioclase | OriAb18An81 | Or1Ab14An85 | Or1Ab23An76 | Or2Ab20An78 |
Key to table 13
V. Allivalite from Unit 10 of the Layered Series, Hallival, Rhum; Analyst, G. M. Brown 1957, p. 47.
XII. Allivalite, Broisgillmore Burn, ½-mile S.S.W. of summit of Am Bidean, Skye; Analysts W. F. Waters and K.L.H. Murray, Geological Survey Lab. No. 1576, 1950. Guppy and Sabine 1956, p. 24.
Y Gabbro-variant of Great Eucrite Ring-dyke, Centre 3. Ardnamurchan W. side of Creag an Airgid, 1¼ miles S. 40° E. of Achnaha; Analyst E. G. Radley, Geological Survey Lab. No. 736 in Richey and Thomas 1930, p. 85.
Z Olivine-gabbro (Eucrite). Major intrusion. Coir' a'Mhadaidh, Cuillins, Skye. Analyst, W. Pollard in Harker 1904, p. 103.
The phenocrysts tend towards a certain constancy of size, as if they had in some way been graded; few of the bytownite-anorthites are less than 2 mm or more than 5 mm long. Their calcic compositions are sufficiently evident from measurement of maximum extinction angles in the 'symmetrical' zones but they show complexity of twinning and parallel growth, where aggregated, so that the use of the more accurate Albite-Carlsbad method is fraught with uncertainty. Refractive index measurements of ten representative examples covering all possible varieties of matrix gave the following figures for maximum anorthitecontent : An70 (S30790)
Olivine is usually present in these dykes as phenocrysts or early crystals, but in size it is invariably inferior to the feldspars. In only one case does the olivine reach 1 mm diameter (S32717)
A variety of matrices are displayed. Of the 32 rocks sliced, half are classified as dolerites, half as basalts. In only one case (S33990)
Crinanitic types with up to 10 per cent zeolites are included in this class, 12 rocks falling into this group. Chabazite, analcime, thomsonite and stilbite were noticed; one rock (S31417)
Allivalite, olivine-eucrite, gabbro
Perhaps the most interesting dykes of North Skye are the coarse, phanerocrystalline intrusions which occupy a series of linear broad lenses or pods, trending N.N.W. (p. 136). In these the texture is not doleritic but gabbroid, made up of xenomorphic interlocked crystals of calcic plagioclase, olivine, clinopyroxene and titanomagnetite. The rocks are classified as allivalite when the anorthite-content of the plagioclase exceeds 80 per cent; olivine-eucrite when it is in the range An70–80 and gabbro when it is less than 70 per cent, in accordance (as far as allivalite is concerned) with the proposals of G. M. Brown (1957, p. 12), in his recent work on the type allivalites of Rhum, and as far as eucrite is concerned with those of W. J. Wadsworth (1961, p. 28).
Most of the dykes sampled belong to the allivalites and contain calcic bytownite or anorthite as their main constituent. As representative of them, a rock from the centre of the lens exposed in Broisgillmore Burn, ½ mile S.S.W. of the summit of Am Bidean (S37870)
The analysis of the rock from the centre of the lens shows that the rock is somewhat more feldspathic than allivalites from the type locality analysed by G. M. Brown (1957) but the feldspar composition leaves no doubt as to the correctness of the classification. Olivine greatly predominates over pyroxene; whereas in the eucrites cited in
A rock closely similar to the analysed specimen comes from 1560 yd N.N.W. of the Manse at Bracadale. The feldspar composition in An84; the plates, which range up to 4 mm across, enclose crystallographically oriented inclusions, apparently of glass. The olivine carries 26 per cent fayalite and zeolites are again present, especially thomsonite. In a rock from the dyke forming the waterfall in Voaker Burn (S31402)
From the S.E. point of Ardroag (S32945)
Summarizing, it appears that with small variations in the composition of the plagioclase which forms 60–70 per cent of these rocks, both allivalites and olivineeucrites are present. Olivine is normally twice as abundant as clinopyroxene. Some of the rocks are gabbroid and phanerocrystalline; others contain an admixed doleritic mesh.
Tholeiite
About one-third of the doleritic or basaltic dykes examined have proved to have two properties in common; a paucity or total absence of olivine, and the presence in the interstices of the labradorite mesh of patches of glass, or much more frequently, of chlorite or an ill-defined green mineraloid that may represent the devitrification products of glats. Although quartz is rare (in fact, only slice S33979, from 400 yd S.S.E. of Dun Flashader contains free quartz) and none of the patches show alkali feldspar, the rocks resemble closely many that have previously been classified as tholeiites in Scotland. This appears to be consistent with Rosenbusch's (1887) definition of tholeiite. As Holmes (1929) remarks, the essential features are the basaltic composition of the crystalline framework, the development of intersertal texture, and in the case of unqualified tholeiite, freedom or near freedom from olivine. Nevertheless, it must not be supposed that such rock necessarily derives from what is now accepted among petrologists as tholeiitic magma (vide Tilley 1952). As already noted, intrusions which manifestly belong to the alkali-basalt suite may be poor in olivine (p. 145) and may contain intersertal glass near their contacts with country rocks.
One feature of the rocks classified in North Skye as tholeiites which demands that a cautious view be taken of their origin, is the total absence from them of orthorhombic pyroxene or of pigeonite. A repeated search for these minerals has only served to reveal that all the pyroxenes investigated are, as in the "normal" basaltic rocks, diopsidic augites.
Dealing first with those dykes that carry a few per cent of olivine, it is possible to see in these comparisons with the Salen type of the Mull Memoir (Bailey and others 1924, p. 285). A good example comes from Gab na Hoe (S36213)
Probably of greater importance, both numerically and from a genetic point of view, are the olivine-free dykes that approximate to the Acklington type of Holmes (1929, p. 28). In an example from Allt Dearg (S33989)
Porphyritic tholeiites
Dykes containing calcic plagioclase phenocrysts up to 5 mm long set in a matrix similar to the tholeiites described above are known at a number of localities. The phenocrysts are similar in appearance, shape and composition to those described in the dykes related to the alkali basaltic suite (p. 160). Determinations gave An92 (S30784)
The matrix in some of these rocks corresponds with the Salen type (S30784)
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